Dual luminescence in solid CuI(piperazine): hypothesis of an emissive 1-D delocalized excited state
Solid [CuI(piperazine)0.5]∞, characterized by a structure with an infinite double chain of CuI, presents an unexpected dual luminescence. The short copper-copper distances allow the existence of both cluster-centered and 1-D delocalized electronic transitions, as emerged from theoretical calculation...
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| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2015-01, Vol.44 (29), p.13003-13006 |
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| container_end_page | 13006 |
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| container_issue | 29 |
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| container_title | Dalton transactions : an international journal of inorganic chemistry |
| container_volume | 44 |
| creator | Maini, L Braga, D Mazzeo, P P Maschio, L Rérat, M Manet, I Ventura, B |
| description | Solid [CuI(piperazine)0.5]∞, characterized by a structure with an infinite double chain of CuI, presents an unexpected dual luminescence. The short copper-copper distances allow the existence of both cluster-centered and 1-D delocalized electronic transitions, as emerged from theoretical calculations. Beyond the more common cluster-centered emission a higher energy band, which differs in lifetime and in temperature dependence, is observed. |
| doi_str_mv | 10.1039/c5dt02204e |
| format | Article |
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| identifier | ISSN: 1477-9226 |
| ispartof | Dalton transactions : an international journal of inorganic chemistry, 2015-01, Vol.44 (29), p.13003-13006 |
| issn | 1477-9226 1477-9234 |
| language | eng |
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| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Chains Chemical Sciences Emission Emissivity Energy bands Excitation Luminescence Mathematical analysis or physical chemistry Temperature dependence Theoretical and |
| title | Dual luminescence in solid CuI(piperazine): hypothesis of an emissive 1-D delocalized excited state |
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