Electron and proton transfers at diiron dithiolate sites relevant to the catalysis of proton reduction by the [FeFe]-hydrogenases

This review focuses on electron and proton transfers involving hexacarbonyl and substituted {2Fe2S} complexes inspired from the active site of the [FeFe]-hydrogenases ([FeFe]H 2ases), and on different mechanisms by which the synthetic models catalyze the reduction of protons. Selected aspects of the...

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Veröffentlicht in:	Coordination chemistry reviews 2009-05, Vol.253 (9), p.1476-1494
Hauptverfasser:	Capon, Jean-François, Gloaguen, Frédéric, Pétillon, François Y., Schollhammer, Philippe, Talarmin, Jean
Format:	Artikel
Sprache:	eng
Schlagworte:	Bioorganometallic chemistry Chemical Sciences Coordination chemistry DFT calculations Diiron complexes Electron transfer Hydrogenase Inorganic chemistry Proton reduction Protonation
Online-Zugang:	Volltext
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