Synthesis of aryliminoacetonitriles under FVT conditions or by dehydrogenation of arylaminoacetonitriles: an NMR and UV-photoelectron spectroscopy study

The synthesis of [( E)-arylimino]-acetonitriles 3 has been described. It was found that the title compounds can be obtained on the three ways, namely by: (i) dehydrogenation of arylaminoacetonitriles 1, (ii) thermal fragmentation of 1-aryl-4-cyano-β-lactams 4 and (iii) retro-ene reaction of (allyl-...

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Veröffentlicht in:	Tetrahedron 2009-12, Vol.65 (51), p.10581-10589
Hauptverfasser:	Leśniak, Stanisław, Chrostowska, Anna, Kuc, Dawid, Maciejczyk, Małgorzata, Khayar, Saïd, Nazarski, Ryszard B., Urbaniak, Łukasz
Format:	Artikel
Sprache:	eng
Schlagworte:	Aliphatic compounds Chemical Sciences Chemistry Exact sciences and technology Heterocyclic compounds Heterocyclic compounds with only one n hetero atom and condensed derivatives Inorganic chemistry Organic chemistry Preparations and properties
Online-Zugang:	Volltext
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