Surface film formation on a carbonaceous electrode: Influence of the binder chemistry
We have investigated the possible effect of carboxymethylcellulose (CMC) in the SEI film formation at the surface of a graphite composite electrode of LiCoO 2/graphite cells. The electrode/electrolyte interface was analyzed by XPS at different potentials of the first electrochemical cycle, and after...
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| Veröffentlicht in: | Journal of power sources 2009-04, Vol.189 (1), p.72-80 |
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| creator | El Ouatani, L. Dedryvère, R. Ledeuil, J.-B. Siret, C. Biensan, P. Desbrières, J. Gonbeau, D. |
| description | We have investigated the possible effect of carboxymethylcellulose (CMC) in the SEI film formation at the surface of a graphite composite electrode of LiCoO
2/graphite cells. The electrode/electrolyte interface was analyzed by XPS at different potentials of the first electrochemical cycle, and after simple contact of the electrode with the electrolyte. We could evidence a specific reactivity of CMC towards the electrolyte (LiPF
6 in a mixture of carbonate solvents), resulting in the formation of new species that contribute to the surface film composition. This result shows that the chemical reactivity of CMC towards the electrolyte takes part in the formation of the surface film, and contributes to the good properties of CMC as binder. |
| doi_str_mv | 10.1016/j.jpowsour.2008.11.031 |
| format | Article |
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2/graphite cells. The electrode/electrolyte interface was analyzed by XPS at different potentials of the first electrochemical cycle, and after simple contact of the electrode with the electrolyte. We could evidence a specific reactivity of CMC towards the electrolyte (LiPF
6 in a mixture of carbonate solvents), resulting in the formation of new species that contribute to the surface film composition. This result shows that the chemical reactivity of CMC towards the electrolyte takes part in the formation of the surface film, and contributes to the good properties of CMC as binder.</description><identifier>ISSN: 0378-7753</identifier><identifier>EISSN: 1873-2755</identifier><identifier>DOI: 10.1016/j.jpowsour.2008.11.031</identifier><identifier>CODEN: JPSODZ</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>Applied sciences ; Binders ; Carbonates ; Chemical Sciences ; CMC ; Contact ; Direct energy conversion and energy accumulation ; Electrical engineering. Electrical power engineering ; Electrical power engineering ; Electrochemical conversion: primary and secondary batteries, fuel cells ; Electrodes ; Electrolytes ; Exact sciences and technology ; Graphite ; Li-ion batteries ; Material chemistry ; or physical chemistry ; SBR ; SEI ; Solvents ; Theoretical and ; X-ray photoelectron spectroscopy ; XPS</subject><ispartof>Journal of power sources, 2009-04, Vol.189 (1), p.72-80</ispartof><rights>2008 Elsevier B.V.</rights><rights>2009 INIST-CNRS</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c507t-1f26511b3f3b57f4545a3fa320b1bc77e07d21275e136da96a11a03c26166d2e3</citedby><cites>FETCH-LOGICAL-c507t-1f26511b3f3b57f4545a3fa320b1bc77e07d21275e136da96a11a03c26166d2e3</cites><orcidid>0000-0001-5125-640X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.jpowsour.2008.11.031$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>230,309,310,314,780,784,789,790,885,3550,23930,23931,25140,27924,27925,45995</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=21693737$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://hal.science/hal-01560428$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>El Ouatani, L.</creatorcontrib><creatorcontrib>Dedryvère, R.</creatorcontrib><creatorcontrib>Ledeuil, J.-B.</creatorcontrib><creatorcontrib>Siret, C.</creatorcontrib><creatorcontrib>Biensan, P.</creatorcontrib><creatorcontrib>Desbrières, J.</creatorcontrib><creatorcontrib>Gonbeau, D.</creatorcontrib><title>Surface film formation on a carbonaceous electrode: Influence of the binder chemistry</title><title>Journal of power sources</title><description>We have investigated the possible effect of carboxymethylcellulose (CMC) in the SEI film formation at the surface of a graphite composite electrode of LiCoO
2/graphite cells. The electrode/electrolyte interface was analyzed by XPS at different potentials of the first electrochemical cycle, and after simple contact of the electrode with the electrolyte. We could evidence a specific reactivity of CMC towards the electrolyte (LiPF
6 in a mixture of carbonate solvents), resulting in the formation of new species that contribute to the surface film composition. This result shows that the chemical reactivity of CMC towards the electrolyte takes part in the formation of the surface film, and contributes to the good properties of CMC as binder.</description><subject>Applied sciences</subject><subject>Binders</subject><subject>Carbonates</subject><subject>Chemical Sciences</subject><subject>CMC</subject><subject>Contact</subject><subject>Direct energy conversion and energy accumulation</subject><subject>Electrical engineering. Electrical power engineering</subject><subject>Electrical power engineering</subject><subject>Electrochemical conversion: primary and secondary batteries, fuel cells</subject><subject>Electrodes</subject><subject>Electrolytes</subject><subject>Exact sciences and technology</subject><subject>Graphite</subject><subject>Li-ion batteries</subject><subject>Material chemistry</subject><subject>or physical chemistry</subject><subject>SBR</subject><subject>SEI</subject><subject>Solvents</subject><subject>Theoretical and</subject><subject>X-ray photoelectron spectroscopy</subject><subject>XPS</subject><issn>0378-7753</issn><issn>1873-2755</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><recordid>eNqFkU1r3DAQhkVoIdtt_0LQJbQ92J2RLMnbU0Nok8BCD23OQpYlVovX2kp2Qv59ZTbNMUUDAs3zaj5eQi4QagSUX_b1_hgfc5xTzQDaGrEGjmdkha3iFVNCvCEr4KqtlBL8nLzLeQ8AiApW5P7XnLyxjvowHKiP6WCmEEdawlBrUhfHko1zpm5wdkqxd1_p3eiH2Y1FFT2ddo52YexdonbnDiFP6ek9eevNkN2H53tN7n98_319W21_3txdX20rK0BNFXomBWLHPe-E8o1ohOHecAYddlYpB6pnWCZwyGVvNtIgGuCWSZSyZ46vyefTvzsz6GMKB5OedDRB315t9fIGKCQ0rH3Awn48sccU_8wuT7r0at0wmHGZT7cbiaqFZlPIT6-SqJRCgQ0TBZUn1KaYc3L-pQsEvbij9_qfO3pxRyPq4k4RXj7XMNmawScz2pBf1Azlhqty1uTbiXNljQ_BJZ1tWFbfh1T80H0M_yv1F-Byp8Q</recordid><startdate>20090401</startdate><enddate>20090401</enddate><creator>El Ouatani, L.</creator><creator>Dedryvère, R.</creator><creator>Ledeuil, J.-B.</creator><creator>Siret, C.</creator><creator>Biensan, P.</creator><creator>Desbrières, J.</creator><creator>Gonbeau, D.</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7SU</scope><scope>7TB</scope><scope>8FD</scope><scope>C1K</scope><scope>FR3</scope><scope>KR7</scope><scope>L7M</scope><scope>7ST</scope><scope>SOI</scope><scope>1XC</scope><orcidid>https://orcid.org/0000-0001-5125-640X</orcidid></search><sort><creationdate>20090401</creationdate><title>Surface film formation on a carbonaceous electrode: Influence of the binder chemistry</title><author>El Ouatani, L. ; Dedryvère, R. ; Ledeuil, J.-B. ; Siret, C. ; Biensan, P. ; Desbrières, J. ; Gonbeau, D.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c507t-1f26511b3f3b57f4545a3fa320b1bc77e07d21275e136da96a11a03c26166d2e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2009</creationdate><topic>Applied sciences</topic><topic>Binders</topic><topic>Carbonates</topic><topic>Chemical Sciences</topic><topic>CMC</topic><topic>Contact</topic><topic>Direct energy conversion and energy accumulation</topic><topic>Electrical engineering. 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2/graphite cells. The electrode/electrolyte interface was analyzed by XPS at different potentials of the first electrochemical cycle, and after simple contact of the electrode with the electrolyte. We could evidence a specific reactivity of CMC towards the electrolyte (LiPF
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| source | Elsevier ScienceDirect Journals Complete |
| subjects | Applied sciences Binders Carbonates Chemical Sciences CMC Contact Direct energy conversion and energy accumulation Electrical engineering. Electrical power engineering Electrical power engineering Electrochemical conversion: primary and secondary batteries, fuel cells Electrodes Electrolytes Exact sciences and technology Graphite Li-ion batteries Material chemistry or physical chemistry SBR SEI Solvents Theoretical and X-ray photoelectron spectroscopy XPS |
| title | Surface film formation on a carbonaceous electrode: Influence of the binder chemistry |
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