Selective Metathesis of α‑Olefins from Bio-Sourced Fischer–Tropsch Feeds

Selective Metathesis of α‑Olefins from Bio-Sourced Fischer–Tropsch Feeds

The search for a low-cost process for the valorization of linear α-olefins combining high productivity and high selectivity is a longstanding goal for chemists. Herein, we report a soluble ruthenium olefin metathesis catalyst that performs the conversion of linear α-olefins to longer internal linear...

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Veröffentlicht in:ACS catalysis 2016-11, Vol.6 (11), p.7970-7976
Hauptverfasser: Rouen, Mathieu, Queval, Pierre, Borré, Etienne, Falivene, Laura, Poater, Albert, Berthod, Mikaël, Hugues, François, Cavallo, Luigi, Baslé, Olivier, Olivier-Bourbigou, Hélène, Mauduit, Marc
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container_end_page 7976
container_issue 11
container_start_page 7970
container_title ACS catalysis
container_volume 6
creator Rouen, Mathieu
Queval, Pierre
Borré, Etienne
Falivene, Laura
Poater, Albert
Berthod, Mikaël
Hugues, François
Cavallo, Luigi
Baslé, Olivier
Olivier-Bourbigou, Hélène
Mauduit, Marc
description The search for a low-cost process for the valorization of linear α-olefins combining high productivity and high selectivity is a longstanding goal for chemists. Herein, we report a soluble ruthenium olefin metathesis catalyst that performs the conversion of linear α-olefins to longer internal linear olefins with high selectivity (>99%) under neat conditions at low loadings (50 ppm) and without the need of expensive additives. This robust catalytic process allowed us to efficiently and selectively re-equilibrate the naphtha fraction (C5–C8) of a Fischer–Tropsch feed derived from non-petroleum resources to a higher-value product range (C9–C14), useful as detergent and plasticizer precursors.
doi_str_mv 10.1021/acscatal.6b01428
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title Selective Metathesis of α‑Olefins from Bio-Sourced Fischer–Tropsch Feeds
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