Probing the local structure of Prussian blue electrodes by 113Cd NMR spectroscopy

We demonstrate that 113Cd NMR is a potent technique to monitor the local electronic and structural states of the Prussian blue electrode during Li+ intercalation, providing an atomic-scale insight into the reaction mechanism.

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2017-05, Vol.46 (19), p.6159-6162
Hauptverfasser: Flambard, A, Sugahara, A, De, S, Okubo, M, Yamada, A, Lescouëzec, R
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container_end_page 6162
container_issue 19
container_start_page 6159
container_title Dalton transactions : an international journal of inorganic chemistry
container_volume 46
creator Flambard, A
Sugahara, A
De, S
Okubo, M
Yamada, A
Lescouëzec, R
description We demonstrate that 113Cd NMR is a potent technique to monitor the local electronic and structural states of the Prussian blue electrode during Li+ intercalation, providing an atomic-scale insight into the reaction mechanism.
doi_str_mv 10.1039/c7dt00728k
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identifier ISSN: 1477-9226
ispartof Dalton transactions : an international journal of inorganic chemistry, 2017-05, Vol.46 (19), p.6159-6162
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language eng
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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Chemical Sciences
Electrodes
Electronics
Intercalation
Material chemistry
Monitors
NMR spectroscopy
Nuclear magnetic resonance
Reaction mechanisms
title Probing the local structure of Prussian blue electrodes by 113Cd NMR spectroscopy
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