Probing the local structure of Prussian blue electrodes by 113Cd NMR spectroscopy

Probing the local structure of Prussian blue electrodes by 113Cd NMR spectroscopy

We demonstrate that 113Cd NMR is a potent technique to monitor the local electronic and structural states of the Prussian blue electrode during Li+ intercalation, providing an atomic-scale insight into the reaction mechanism.

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2017-05, Vol.46 (19), p.6159-6162
Hauptverfasser: Flambard, A, Sugahara, A, De, S, Okubo, M, Yamada, A, Lescouëzec, R
Format: Artikel
Sprache:eng
Schlagworte:
Chemical Sciences
Electrodes
Electronics
Intercalation
Material chemistry
Monitors
NMR spectroscopy
Nuclear magnetic resonance
Reaction mechanisms
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Beschreibung
Zusammenfassung:We demonstrate that 113Cd NMR is a potent technique to monitor the local electronic and structural states of the Prussian blue electrode during Li+ intercalation, providing an atomic-scale insight into the reaction mechanism.
ISSN:1477-9226
1477-9234
DOI:10.1039/c7dt00728k