Improved and General Manganese‐Catalyzed N‐Methylation of Aromatic Amines Using Methanol
A novel lutidine‐based manganese PNP‐pincer complex has been synthesized for the selective N‐methylation of aromatic amines with methanol. Using borrowing hydrogen methodology, a selection of differently functionalized aniline derivatives is selectively methylated in good yields. Mn lends a hydrogen...
Gespeichert in:
| Veröffentlicht in: | Chemistry : a European journal 2017-04, Vol.23 (23), p.5410-5413 |
|---|---|
| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 5413 |
|---|---|
| container_issue | 23 |
| container_start_page | 5410 |
| container_title | Chemistry : a European journal |
| container_volume | 23 |
| creator | Neumann, Jacob Elangovan, Saravanakumar Spannenberg, Anke Junge, Kathrin Beller, Matthias |
| description | A novel lutidine‐based manganese PNP‐pincer complex has been synthesized for the selective N‐methylation of aromatic amines with methanol. Using borrowing hydrogen methodology, a selection of differently functionalized aniline derivatives is selectively methylated in good yields.
Mn lends a hydrogen: A manganese pincer complex has been employed for the selective N‐methylation of aromatic amines using methanol and borrowing hydrogen methodology. A selection of differently functionalized aniline derivatives is selectively mono‐methylated in good yields. |
| doi_str_mv | 10.1002/chem.201605218 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_hal_p</sourceid><recordid>TN_cdi_hal_primary_oai_HAL_hal_01518033v1</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1861583349</sourcerecordid><originalsourceid>FETCH-LOGICAL-c5438-7d3239a99fa6be9bfb9ad8c5a8cded1c97a171f5044ad7aeabcb30891076e7e43</originalsourceid><addsrcrecordid>eNqF0cFuEzEQBmALgWgIXDmilbjAYcN4vV7bxygqTaUELvSGZM16Z5utvOuyTorCiUfgGfskdZQSJC49jcb6PPL4Z-wthxkHKD65DfWzAngFsuD6GZvwVHOhKvmcTcCUKq-kMGfsVYw3AGAqIV6ys0JzqApjJuz7ZX87hjtqMhya7IIGGtFnaxyucaBI97__LHCLfv8riS-pW9N2s_e47cKQhTabj6FPjcvmfZd8dhW74To7IByCf81etOgjvXmsU3b1-fzbYpmvvl5cLuar3MlS6Fw1ohAGjWmxqsnUbW2w0U6idg013BmFXPFWQllio5CwdrUAbTioihSVYso-Hudu0Nvbsetx3NuAnV3OV_ZwBlxyDULc8WQ_HG1a-8eO4tb2XXTkfdo37KLlBsoCCqHF01RXXCZXmkTf_0dvwm4c0tJJGTBKyvT1UzY7KjeGGEdqT4_lYA9x2kOc9hRnuvDuceyu7qk58b_5JWCO4Gfnaf_EOLtYnq__DX8ACvqsow</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1890975596</pqid></control><display><type>article</type><title>Improved and General Manganese‐Catalyzed N‐Methylation of Aromatic Amines Using Methanol</title><source>Wiley Journals</source><creator>Neumann, Jacob ; Elangovan, Saravanakumar ; Spannenberg, Anke ; Junge, Kathrin ; Beller, Matthias</creator><creatorcontrib>Neumann, Jacob ; Elangovan, Saravanakumar ; Spannenberg, Anke ; Junge, Kathrin ; Beller, Matthias</creatorcontrib><description>A novel lutidine‐based manganese PNP‐pincer complex has been synthesized for the selective N‐methylation of aromatic amines with methanol. Using borrowing hydrogen methodology, a selection of differently functionalized aniline derivatives is selectively methylated in good yields.
Mn lends a hydrogen: A manganese pincer complex has been employed for the selective N‐methylation of aromatic amines using methanol and borrowing hydrogen methodology. A selection of differently functionalized aniline derivatives is selectively mono‐methylated in good yields.</description><identifier>ISSN: 0947-6539</identifier><identifier>EISSN: 1521-3765</identifier><identifier>DOI: 10.1002/chem.201605218</identifier><identifier>PMID: 28106299</identifier><identifier>CODEN: CEUJED</identifier><language>eng</language><publisher>Germany: Wiley Subscription Services, Inc</publisher><subject>Amines ; Aniline ; borrowing hydrogen ; Chemical Sciences ; Chemistry ; Derivatives ; Hydrogen ; Manganese ; Methodology ; Methyl alcohol ; methylation ; pincer complex ; Synthesis</subject><ispartof>Chemistry : a European journal, 2017-04, Vol.23 (23), p.5410-5413</ispartof><rights>2017 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.</rights><rights>2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c5438-7d3239a99fa6be9bfb9ad8c5a8cded1c97a171f5044ad7aeabcb30891076e7e43</citedby><cites>FETCH-LOGICAL-c5438-7d3239a99fa6be9bfb9ad8c5a8cded1c97a171f5044ad7aeabcb30891076e7e43</cites><orcidid>0000-0001-5709-0965</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fchem.201605218$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fchem.201605218$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>230,314,780,784,885,1417,27924,27925,45574,45575</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/28106299$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink><backlink>$$Uhttps://univ-rennes.hal.science/hal-01518033$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Neumann, Jacob</creatorcontrib><creatorcontrib>Elangovan, Saravanakumar</creatorcontrib><creatorcontrib>Spannenberg, Anke</creatorcontrib><creatorcontrib>Junge, Kathrin</creatorcontrib><creatorcontrib>Beller, Matthias</creatorcontrib><title>Improved and General Manganese‐Catalyzed N‐Methylation of Aromatic Amines Using Methanol</title><title>Chemistry : a European journal</title><addtitle>Chemistry</addtitle><description>A novel lutidine‐based manganese PNP‐pincer complex has been synthesized for the selective N‐methylation of aromatic amines with methanol. Using borrowing hydrogen methodology, a selection of differently functionalized aniline derivatives is selectively methylated in good yields.
Mn lends a hydrogen: A manganese pincer complex has been employed for the selective N‐methylation of aromatic amines using methanol and borrowing hydrogen methodology. A selection of differently functionalized aniline derivatives is selectively mono‐methylated in good yields.</description><subject>Amines</subject><subject>Aniline</subject><subject>borrowing hydrogen</subject><subject>Chemical Sciences</subject><subject>Chemistry</subject><subject>Derivatives</subject><subject>Hydrogen</subject><subject>Manganese</subject><subject>Methodology</subject><subject>Methyl alcohol</subject><subject>methylation</subject><subject>pincer complex</subject><subject>Synthesis</subject><issn>0947-6539</issn><issn>1521-3765</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNqF0cFuEzEQBmALgWgIXDmilbjAYcN4vV7bxygqTaUELvSGZM16Z5utvOuyTorCiUfgGfskdZQSJC49jcb6PPL4Z-wthxkHKD65DfWzAngFsuD6GZvwVHOhKvmcTcCUKq-kMGfsVYw3AGAqIV6ys0JzqApjJuz7ZX87hjtqMhya7IIGGtFnaxyucaBI97__LHCLfv8riS-pW9N2s_e47cKQhTabj6FPjcvmfZd8dhW74To7IByCf81etOgjvXmsU3b1-fzbYpmvvl5cLuar3MlS6Fw1ohAGjWmxqsnUbW2w0U6idg013BmFXPFWQllio5CwdrUAbTioihSVYso-Hudu0Nvbsetx3NuAnV3OV_ZwBlxyDULc8WQ_HG1a-8eO4tb2XXTkfdo37KLlBsoCCqHF01RXXCZXmkTf_0dvwm4c0tJJGTBKyvT1UzY7KjeGGEdqT4_lYA9x2kOc9hRnuvDuceyu7qk58b_5JWCO4Gfnaf_EOLtYnq__DX8ACvqsow</recordid><startdate>20170424</startdate><enddate>20170424</enddate><creator>Neumann, Jacob</creator><creator>Elangovan, Saravanakumar</creator><creator>Spannenberg, Anke</creator><creator>Junge, Kathrin</creator><creator>Beller, Matthias</creator><general>Wiley Subscription Services, Inc</general><general>Wiley-VCH Verlag</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>K9.</scope><scope>7X8</scope><scope>1XC</scope><orcidid>https://orcid.org/0000-0001-5709-0965</orcidid></search><sort><creationdate>20170424</creationdate><title>Improved and General Manganese‐Catalyzed N‐Methylation of Aromatic Amines Using Methanol</title><author>Neumann, Jacob ; Elangovan, Saravanakumar ; Spannenberg, Anke ; Junge, Kathrin ; Beller, Matthias</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c5438-7d3239a99fa6be9bfb9ad8c5a8cded1c97a171f5044ad7aeabcb30891076e7e43</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Amines</topic><topic>Aniline</topic><topic>borrowing hydrogen</topic><topic>Chemical Sciences</topic><topic>Chemistry</topic><topic>Derivatives</topic><topic>Hydrogen</topic><topic>Manganese</topic><topic>Methodology</topic><topic>Methyl alcohol</topic><topic>methylation</topic><topic>pincer complex</topic><topic>Synthesis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Neumann, Jacob</creatorcontrib><creatorcontrib>Elangovan, Saravanakumar</creatorcontrib><creatorcontrib>Spannenberg, Anke</creatorcontrib><creatorcontrib>Junge, Kathrin</creatorcontrib><creatorcontrib>Beller, Matthias</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>Chemistry : a European journal</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Neumann, Jacob</au><au>Elangovan, Saravanakumar</au><au>Spannenberg, Anke</au><au>Junge, Kathrin</au><au>Beller, Matthias</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Improved and General Manganese‐Catalyzed N‐Methylation of Aromatic Amines Using Methanol</atitle><jtitle>Chemistry : a European journal</jtitle><addtitle>Chemistry</addtitle><date>2017-04-24</date><risdate>2017</risdate><volume>23</volume><issue>23</issue><spage>5410</spage><epage>5413</epage><pages>5410-5413</pages><issn>0947-6539</issn><eissn>1521-3765</eissn><coden>CEUJED</coden><abstract>A novel lutidine‐based manganese PNP‐pincer complex has been synthesized for the selective N‐methylation of aromatic amines with methanol. Using borrowing hydrogen methodology, a selection of differently functionalized aniline derivatives is selectively methylated in good yields.
Mn lends a hydrogen: A manganese pincer complex has been employed for the selective N‐methylation of aromatic amines using methanol and borrowing hydrogen methodology. A selection of differently functionalized aniline derivatives is selectively mono‐methylated in good yields.</abstract><cop>Germany</cop><pub>Wiley Subscription Services, Inc</pub><pmid>28106299</pmid><doi>10.1002/chem.201605218</doi><tpages>4</tpages><orcidid>https://orcid.org/0000-0001-5709-0965</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0947-6539 |
| ispartof | Chemistry : a European journal, 2017-04, Vol.23 (23), p.5410-5413 |
| issn | 0947-6539 1521-3765 |
| language | eng |
| recordid | cdi_hal_primary_oai_HAL_hal_01518033v1 |
| source | Wiley Journals |
| subjects | Amines Aniline borrowing hydrogen Chemical Sciences Chemistry Derivatives Hydrogen Manganese Methodology Methyl alcohol methylation pincer complex Synthesis |
| title | Improved and General Manganese‐Catalyzed N‐Methylation of Aromatic Amines Using Methanol |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-04T22%3A20%3A50IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_hal_p&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Improved%20and%20General%20Manganese%E2%80%90Catalyzed%20N%E2%80%90Methylation%20of%20Aromatic%20Amines%20Using%20Methanol&rft.jtitle=Chemistry%20:%20a%20European%20journal&rft.au=Neumann,%20Jacob&rft.date=2017-04-24&rft.volume=23&rft.issue=23&rft.spage=5410&rft.epage=5413&rft.pages=5410-5413&rft.issn=0947-6539&rft.eissn=1521-3765&rft.coden=CEUJED&rft_id=info:doi/10.1002/chem.201605218&rft_dat=%3Cproquest_hal_p%3E1861583349%3C/proquest_hal_p%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1890975596&rft_id=info:pmid/28106299&rfr_iscdi=true |