Lithium-Ion Batteries Working at 85°C: Aging Phenomena and Electrode/Electrolyte Interfaces Studied by XPS

Lithium-Ion Batteries Working at 85°C: Aging Phenomena and Electrode/Electrolyte Interfaces Studied by XPS

Li(Ni,Mn,Co)O2/graphite lithium-ion batteries designed to work at high temperature were tested upon cycling at 85°C in various voltage ranges. Aging processes in relation with changes in the electrode/electrolyte interfaces at both electrodes were investigated by X-ray Photoelectron Spectroscopy (XP...

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Veröffentlicht in:Journal of the Electrochemical Society 2012, Vol.159 (10), p.A1739-A1746
Hauptverfasser: Bodenes, Lucille, Dedryvère, Rémi, Martinez, Hervé, Fischer, Florent, Tessier, Cécile, Pérès, Jean-Paul
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Material chemistry
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container_end_page A1746
container_issue 10
container_start_page A1739
container_title Journal of the Electrochemical Society
container_volume 159
creator Bodenes, Lucille
Dedryvère, Rémi
Martinez, Hervé
Fischer, Florent
Tessier, Cécile
Pérès, Jean-Paul
description Li(Ni,Mn,Co)O2/graphite lithium-ion batteries designed to work at high temperature were tested upon cycling at 85°C in various voltage ranges. Aging processes in relation with changes in the electrode/electrolyte interfaces at both electrodes were investigated by X-ray Photoelectron Spectroscopy (XPS). Changes were observed in the composition of the solid electrolyte interphase (SEI) at the surface of graphite electrode due to the high cycling temperature: disappearance of carbonates and increase of inorganic compounds coming from degradation of the salt. A slight dissolution process of the PVdF positive electrode binder was evidenced. It was also observed that the formation and thickness of the passivation layer at the positive electrode surface at 85°C depends on the cycling voltage range.
doi_str_mv 10.1149/2.061210jes
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Material chemistry
title Lithium-Ion Batteries Working at 85°C: Aging Phenomena and Electrode/Electrolyte Interfaces Studied by XPS
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