An Unusual 3D Zinc-Organic Framework Constructed from Paddle-Wheel-Based Carboxylate Sheets Bridged by Acetate Ions
A zinc‐2,6‐naphthalenedicarboxylate metal‐organic framework, (H2NEt2)[Zn2(AcO)(NDC)2]·nDEF (1) (DEF = N,N‐diethylformamide, AcO = acetate), was solvothermally synthesized in the presence of small amounts of acetic acid and characterized by single‐crystal and powder X‐ray diffraction and thermogravim...
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| Veröffentlicht in: | Zeitschrift für anorganische und allgemeine Chemie (1950) 2016-06, Vol.642 (11-12), p.709-713 |
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| container_title | Zeitschrift für anorganische und allgemeine Chemie (1950) |
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| creator | Saffon-Merceron, Nathalie Barthélémy, Marie-Claire Laurent, Christophe Fabing, Isabelle Hoffmann, Pascal Vigroux, Alain |
| description | A zinc‐2,6‐naphthalenedicarboxylate metal‐organic framework, (H2NEt2)[Zn2(AcO)(NDC)2]·nDEF (1) (DEF = N,N‐diethylformamide, AcO = acetate), was solvothermally synthesized in the presence of small amounts of acetic acid and characterized by single‐crystal and powder X‐ray diffraction and thermogravimetric analysis. Compound 1 is an anionic 3D paddle‐wheel MOF, in which the zinc‐naphthalenedicarboxylate sheets are linked together by bridging acetate ions. Compound 1 exhibits large square channels (13 × 13 Å), which contain DEF molecules and, alternatively, charge‐balancing diethylammonium cations in situ generated by the hydrolysis of DEF under the solvothermal conditions used. The anionic host framework of 1 is unstable upon removal of guest DEF molecules suggesting that host‐guest hydrogen bond interactions are crucial for maintaining the structural integrity of this compound. |
| doi_str_mv | 10.1002/zaac.201600133 |
| format | Article |
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Compound 1 is an anionic 3D paddle‐wheel MOF, in which the zinc‐naphthalenedicarboxylate sheets are linked together by bridging acetate ions. Compound 1 exhibits large square channels (13 × 13 Å), which contain DEF molecules and, alternatively, charge‐balancing diethylammonium cations in situ generated by the hydrolysis of DEF under the solvothermal conditions used. The anionic host framework of 1 is unstable upon removal of guest DEF molecules suggesting that host‐guest hydrogen bond interactions are crucial for maintaining the structural integrity of this compound.</description><identifier>ISSN: 0044-2313</identifier><identifier>EISSN: 1521-3749</identifier><identifier>DOI: 10.1002/zaac.201600133</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>2,6‐Naphthalenedicarboxylate ; 6-Naphthalenedicarboxylate ; Bridging acetate ligand ; Engineering Sciences ; Materials ; Metal-organic frameworks ; Paddle-wheel MOF ; Supercritical CO2 activation ; Zinc</subject><ispartof>Zeitschrift für anorganische und allgemeine Chemie (1950), 2016-06, Vol.642 (11-12), p.709-713</ispartof><rights>Copyright © 2016 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>Copyright © 2016 WILEY-VCH Verlag GmbH & Co. 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Chem</addtitle><description>A zinc‐2,6‐naphthalenedicarboxylate metal‐organic framework, (H2NEt2)[Zn2(AcO)(NDC)2]·nDEF (1) (DEF = N,N‐diethylformamide, AcO = acetate), was solvothermally synthesized in the presence of small amounts of acetic acid and characterized by single‐crystal and powder X‐ray diffraction and thermogravimetric analysis. Compound 1 is an anionic 3D paddle‐wheel MOF, in which the zinc‐naphthalenedicarboxylate sheets are linked together by bridging acetate ions. Compound 1 exhibits large square channels (13 × 13 Å), which contain DEF molecules and, alternatively, charge‐balancing diethylammonium cations in situ generated by the hydrolysis of DEF under the solvothermal conditions used. The anionic host framework of 1 is unstable upon removal of guest DEF molecules suggesting that host‐guest hydrogen bond interactions are crucial for maintaining the structural integrity of this compound.</description><subject>2,6‐Naphthalenedicarboxylate</subject><subject>6-Naphthalenedicarboxylate</subject><subject>Bridging acetate ligand</subject><subject>Engineering Sciences</subject><subject>Materials</subject><subject>Metal-organic frameworks</subject><subject>Paddle-wheel MOF</subject><subject>Supercritical CO2 activation</subject><subject>Zinc</subject><issn>0044-2313</issn><issn>1521-3749</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNqFkU1v1DAQhiMEUpfCtWdLnDh4sT12vDlmA_1AK4paqkp7sSaO06bNJsVOaJdfj6OgFTcutvTO84xGepPkhLMlZ0x8-o1ol4LxlDEO8CpZcCU4BS2z18mCMSmpAA5HydsQHlhkmFKLJOQduenGMGJL4DPZNp2ll_4Ou8aSU48799z7R1L0XRj8aAdXkdr3O_Idq6p19PbeuZauMcS8QF_2L_sWB0euYz4EsvZNdRdH5Z7k1g3T5CJuepe8qbEN7v3f_zi5Of3yozinm8uziyLfUCtFBlSwsq41YLpaYSZRpRlnvBTx0aVjgOAqsZJY6lTZSkkNQopK2NJCClJxDsfJx3nvPbbmyTc79HvTY2PO842ZMsajxUH_mtgPM_vk-5-jC4N56EffxfMM11kqtVxlKlLLmbK-D8G7-rCWMzOVYKYSzKGEKGSz8Ny0bv8f2mzzvPjXpbPbhMG9HFz0jybVoJW5_XZmvmrJ1_pqawD-AC68l9U</recordid><startdate>201606</startdate><enddate>201606</enddate><creator>Saffon-Merceron, Nathalie</creator><creator>Barthélémy, Marie-Claire</creator><creator>Laurent, Christophe</creator><creator>Fabing, Isabelle</creator><creator>Hoffmann, Pascal</creator><creator>Vigroux, Alain</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><general>Wiley Subscription Services, Inc</general><general>Wiley-VCH Verlag</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>1XC</scope><scope>VOOES</scope><orcidid>https://orcid.org/0000-0002-7542-0320</orcidid><orcidid>https://orcid.org/0000-0002-8707-3928</orcidid><orcidid>https://orcid.org/0000-0002-0301-4163</orcidid><orcidid>https://orcid.org/0000-0002-8502-3986</orcidid></search><sort><creationdate>201606</creationdate><title>An Unusual 3D Zinc-Organic Framework Constructed from Paddle-Wheel-Based Carboxylate Sheets Bridged by Acetate Ions</title><author>Saffon-Merceron, Nathalie ; Barthélémy, Marie-Claire ; Laurent, Christophe ; Fabing, Isabelle ; Hoffmann, Pascal ; Vigroux, Alain</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4293-20bff73a688a94a569101b21017be03a3ed284ab765cd5473242d2cbc36345113</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>2,6‐Naphthalenedicarboxylate</topic><topic>6-Naphthalenedicarboxylate</topic><topic>Bridging acetate ligand</topic><topic>Engineering Sciences</topic><topic>Materials</topic><topic>Metal-organic frameworks</topic><topic>Paddle-wheel MOF</topic><topic>Supercritical CO2 activation</topic><topic>Zinc</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Saffon-Merceron, Nathalie</creatorcontrib><creatorcontrib>Barthélémy, Marie-Claire</creatorcontrib><creatorcontrib>Laurent, Christophe</creatorcontrib><creatorcontrib>Fabing, Isabelle</creatorcontrib><creatorcontrib>Hoffmann, Pascal</creatorcontrib><creatorcontrib>Vigroux, Alain</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><collection>Hyper Article en Ligne (HAL)</collection><collection>Hyper Article en Ligne (HAL) (Open Access)</collection><jtitle>Zeitschrift für anorganische und allgemeine Chemie (1950)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Saffon-Merceron, Nathalie</au><au>Barthélémy, Marie-Claire</au><au>Laurent, Christophe</au><au>Fabing, Isabelle</au><au>Hoffmann, Pascal</au><au>Vigroux, Alain</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>An Unusual 3D Zinc-Organic Framework Constructed from Paddle-Wheel-Based Carboxylate Sheets Bridged by Acetate Ions</atitle><jtitle>Zeitschrift für anorganische und allgemeine Chemie (1950)</jtitle><addtitle>Z. anorg. allg. 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| subjects | 2,6‐Naphthalenedicarboxylate 6-Naphthalenedicarboxylate Bridging acetate ligand Engineering Sciences Materials Metal-organic frameworks Paddle-wheel MOF Supercritical CO2 activation Zinc |
| title | An Unusual 3D Zinc-Organic Framework Constructed from Paddle-Wheel-Based Carboxylate Sheets Bridged by Acetate Ions |
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