Facile Synthesis of Innocuous Comb-Shaped Polymethacrylates with PEG Side Chains by Nitroxide-Mediated Radical Polymerization in Hydroalcoholic Solutions

The nitroxide-mediated copolymerization of poly(ethylene glycol) methyl ether methacrylate (MePEGMA) with a small amount of acrylonitrile using an SG1-based alkoxyamine initiator was shown to be a very simple and efficient technique to synthesize graft copolymers with poly(ethylene glycol) side chai...

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Veröffentlicht in:	Macromolecules 2010-11, Vol.43 (22), p.9291-9303
Hauptverfasser:	Chenal, Marion, Mura, Simona, Marchal, Cathie, Gigmes, Didier, Charleux, Bernadette, Fattal, Elias, Couvreur, Patrick, Nicolas, Julien
Format:	Artikel
Sprache:	eng
Schlagworte:	Applied sciences Chemical Sciences Copolymerization Exact sciences and technology Organic polymers Physicochemistry of polymers Preparation, kinetics, thermodynamics, mechanism and catalysts
Online-Zugang:	Volltext
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