Magneto-Luminescence Correlation in the Textbook Dysprosium(III) Nitrate Single-Ion Magnet
Multifunctional Single-Molecule Magnets (SMMs) or Single-Ion Magnets (SIMs) are intriguing molecule-based materials presenting an association of the slow magnetic relaxation with other physical properties. In this article, we present an example of a very simple molecule based on Dy3+ ion exhibiting...
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| Veröffentlicht in: | Magnetochemistry 2016-12, Vol.2 (4), p.41 |
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| container_title | Magnetochemistry |
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| creator | Mamontova, Ekaterina Long, Jérôme Ferreira, Rute Botas, Alexandre Luneau, Dominique Guari, Yannick Carlos, Luis Larionova, Joulia |
| description | Multifunctional Single-Molecule Magnets (SMMs) or Single-Ion Magnets (SIMs) are intriguing molecule-based materials presenting an association of the slow magnetic relaxation with other physical properties. In this article, we present an example of a very simple molecule based on Dy3+ ion exhibiting a field induced SIM property and a characteristic Dy3+ based emission. The [Dy(NO3)3(H2O)4]·2H2O (1) complex is characterized by the means of single crystal X-Ray diffraction and their magnetic and photo-luminescent properties are investigated. We demonstrate here that it is possible to correlate the magnetic and luminescent properties and to obtain the Orbach barrier from the low temperature emission spectra, which is often difficult to properly extract from the magnetic measurements, especially in the case of field induced SIMs. |
| doi_str_mv | 10.3390/magnetochemistry2040041 |
| format | Article |
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In this article, we present an example of a very simple molecule based on Dy3+ ion exhibiting a field induced SIM property and a characteristic Dy3+ based emission. The [Dy(NO3)3(H2O)4]·2H2O (1) complex is characterized by the means of single crystal X-Ray diffraction and their magnetic and photo-luminescent properties are investigated. We demonstrate here that it is possible to correlate the magnetic and luminescent properties and to obtain the Orbach barrier from the low temperature emission spectra, which is often difficult to properly extract from the magnetic measurements, especially in the case of field induced SIMs.</description><identifier>ISSN: 2312-7481</identifier><identifier>EISSN: 2312-7481</identifier><identifier>DOI: 10.3390/magnetochemistry2040041</identifier><language>eng</language><publisher>Basel: MDPI AG</publisher><subject>Chemical Sciences ; Coordination chemistry ; Dysprosium ; Emission spectra ; Investigations ; Ligands ; Luminescence ; Magnetic induction ; Magnetic measurement ; Magnetic properties ; Magnetic relaxation ; Magnets ; Nitrates ; Optical properties ; Photoluminescence ; Physical properties ; Single crystals ; X ray spectra ; X-ray diffraction</subject><ispartof>Magnetochemistry, 2016-12, Vol.2 (4), p.41</ispartof><rights>2016. 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| source | MDPI - Multidisciplinary Digital Publishing Institute; DOAJ Directory of Open Access Journals; Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals |
| subjects | Chemical Sciences Coordination chemistry Dysprosium Emission spectra Investigations Ligands Luminescence Magnetic induction Magnetic measurement Magnetic properties Magnetic relaxation Magnets Nitrates Optical properties Photoluminescence Physical properties Single crystals X ray spectra X-ray diffraction |
| title | Magneto-Luminescence Correlation in the Textbook Dysprosium(III) Nitrate Single-Ion Magnet |
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