Secondary Phosphine Oxide–Gold(I) Complexes and Their First Application in Catalysis

Secondary Phosphine Oxide–Gold(I) Complexes and Their First Application in Catalysis

A series of new secondary phosphine oxide (SPO)–gold(I) complexes have been synthesized and characterized by X-ray crystallography. Complexes exhibited dimeric structures interconnected by O–H···Cl hydrogen bonds. Their first use in homogeneous catalysis is reported and suggests a broad field of app...

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Veröffentlicht in:Organometallics 2014-08, Vol.33 (15), p.4051-4056
Hauptverfasser: Schröder, Felix, Tugny, Coralie, Salanouve, Elise, Clavier, Hervé, Giordano, Laurent, Moraleda, Delphine, Gimbert, Yves, Mouriès-Mansuy, Virginie, Goddard, Jean-Philippe, Fensterbank, Louis
Format: Artikel
Sprache:eng
Schlagworte:
Chemical Sciences
Organic chemistry
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Zusammenfassung:A series of new secondary phosphine oxide (SPO)–gold(I) complexes have been synthesized and characterized by X-ray crystallography. Complexes exhibited dimeric structures interconnected by O–H···Cl hydrogen bonds. Their first use in homogeneous catalysis is reported and suggests a broad field of application in prototypical enyne cycloisomerization and hydroxy- and methoxycyclization reactions.
ISSN:0276-7333
1520-6041
DOI:10.1021/om500568q