Designing 'Totem' C2-Symmetrical Iron Porphyrin Catalysts for Stereoselective Cyclopropanations

The catalytic activity of the iron(III) C2 chiral porphyrin Fe(2)(OMe) in alkene cyclopropanation is herein reported. The catalyst promoted the reaction of differently substituted styrenes with diazo derivatives with trans‐diastereoselectivities and enantioselectivities up to 99:1 and 87 %, respecti...

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Veröffentlicht in:	Chemistry : a European journal 2016-09, Vol.22 (38), p.13599-13612
Hauptverfasser:	Carminati, Daniela Maria, Intrieri, Daniela, Caselli, Alessandro, Le Gac, Stéphane, Boitrel, Bernard, Toma, Lucio, Legnani, Laura, Gallo, Emma
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemical Sciences Chemistry cyclopropanation density functional calculations iron porphyrins stereoselective reactions
Online-Zugang:	Volltext
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