Ferromagnetic ordering of -[Sm(iii)-radical]n- coordination polymers
[Sm(hfac)3(boaDTDA)]n is the first coordination compound of a thiazyl-based neutral radical ligand to exhibit ferromagnetic ordering; TC = 3 K. The [Sm(iii)-radical]n species is soluble in common organic solvents and can be sublimed quantitatively. A McConnell I mechanism is implicated in local exch...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2016-04, Vol.52 (31), p.5414-5417 |
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| container_title | Chemical communications (Cambridge, England) |
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| creator | Fatila, Elisabeth M Maahs, Adam C Mills, Michelle B Rouzières, Mathieu Soldatov, Dmitriy V Clérac, Rodolphe Preuss, Kathryn E |
| description | [Sm(hfac)3(boaDTDA)]n is the first coordination compound of a thiazyl-based neutral radical ligand to exhibit ferromagnetic ordering; TC = 3 K. The [Sm(iii)-radical]n species is soluble in common organic solvents and can be sublimed quantitatively. A McConnell I mechanism is implicated in local exchange pathways that contribute to cooperative magnetic properties. |
| doi_str_mv | 10.1039/c6cc01548d |
| format | Article |
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| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Chemical Sciences Material chemistry |
| title | Ferromagnetic ordering of -[Sm(iii)-radical]n- coordination polymers |
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