Thermally driven low-spin∕high-spin phase transitions in solids

A microscopic model of low-spin/high-spin transitions in solids containing transition metal ions with d(6) configuration is described. The underlying physics of the transition is related to the large totally symmetric relaxation of ligands accompanying the two electron promotion from the t(2) to e o...

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Veröffentlicht in:	Physical review. B, Condensed matter and materials physics Condensed matter and materials physics, 2005-07, Vol.72 (2), Article 024406
Hauptverfasser:	Biernacki, S. W., Clerjaud, B.
Format:	Artikel
Sprache:	eng
Schlagworte:	Condensed Matter Physics
Online-Zugang:	Volltext
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