ISIDORE, a probe for in situ trace metal speciation based on Donnan membrane technique with related electrochemical detection part 1: Equilibrium measurements
This work presents the development of a new probe (ISIDORE probe) based on the hyphenation of a Donnan Membrane Technique device (DMT) to a screen-printed electrode through a flow-cell to determine the free zinc, cadmium and lead ion concentration in natural samples, such as a freshwater river. The...
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| Veröffentlicht in: | Analytica chimica acta 2015-10, Vol.896, p.1-10 |
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| creator | Parat, Corinne Pinheiro, J.P. |
| description | This work presents the development of a new probe (ISIDORE probe) based on the hyphenation of a Donnan Membrane Technique device (DMT) to a screen-printed electrode through a flow-cell to determine the free zinc, cadmium and lead ion concentration in natural samples, such as a freshwater river. The probe displays many advantages namely: (i) the detection can be performed on-site, which avoids all problems inherent to sampling, transport and storage; (ii) the low volume of the acceptor solution implies shorter equilibration times; (ii) the electrochemical detection system allows monitoring the free ion concentration in the acceptor solution without sampling.
[Display omitted]
•A new probe has been developed for on-site analyses of free metal ion.•A screen-printed electrode has been hyphenated to a DMT device.•Analysis time has been reduced to 6H against 36H when using a classical DMT device.•This new probe has been successfully applied on a synthetic freshwater sample. |
| doi_str_mv | 10.1016/j.aca.2015.07.016 |
| format | Article |
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[Display omitted]
•A new probe has been developed for on-site analyses of free metal ion.•A screen-printed electrode has been hyphenated to a DMT device.•Analysis time has been reduced to 6H against 36H when using a classical DMT device.•This new probe has been successfully applied on a synthetic freshwater sample.</description><identifier>ISSN: 0003-2670</identifier><identifier>EISSN: 1873-4324</identifier><identifier>DOI: 10.1016/j.aca.2015.07.016</identifier><identifier>PMID: 26481984</identifier><language>eng</language><publisher>Netherlands: Elsevier B.V</publisher><subject>Analytical chemistry ; Cadmium ; Chemical Sciences ; Donnan membrane technique ; Lead ; On-site monitoring ; Screen-printed electrode ; Zinc</subject><ispartof>Analytica chimica acta, 2015-10, Vol.896, p.1-10</ispartof><rights>2015 Elsevier B.V.</rights><rights>Copyright © 2015 Elsevier B.V. All rights reserved.</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c387t-9a6d1570152a9358709a000be2e449f39eff567c49e2bf50f19fe1f03b46fc2c3</citedby><cites>FETCH-LOGICAL-c387t-9a6d1570152a9358709a000be2e449f39eff567c49e2bf50f19fe1f03b46fc2c3</cites><orcidid>0000-0001-7925-9733 ; 0000-0003-4601-8188</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0003267015008624$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>230,314,776,780,881,3537,27901,27902,65306</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/26481984$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink><backlink>$$Uhttps://hal.science/hal-01248660$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Parat, Corinne</creatorcontrib><creatorcontrib>Pinheiro, J.P.</creatorcontrib><title>ISIDORE, a probe for in situ trace metal speciation based on Donnan membrane technique with related electrochemical detection part 1: Equilibrium measurements</title><title>Analytica chimica acta</title><addtitle>Anal Chim Acta</addtitle><description>This work presents the development of a new probe (ISIDORE probe) based on the hyphenation of a Donnan Membrane Technique device (DMT) to a screen-printed electrode through a flow-cell to determine the free zinc, cadmium and lead ion concentration in natural samples, such as a freshwater river. The probe displays many advantages namely: (i) the detection can be performed on-site, which avoids all problems inherent to sampling, transport and storage; (ii) the low volume of the acceptor solution implies shorter equilibration times; (ii) the electrochemical detection system allows monitoring the free ion concentration in the acceptor solution without sampling.
[Display omitted]
•A new probe has been developed for on-site analyses of free metal ion.•A screen-printed electrode has been hyphenated to a DMT device.•Analysis time has been reduced to 6H against 36H when using a classical DMT device.•This new probe has been successfully applied on a synthetic freshwater sample.</description><subject>Analytical chemistry</subject><subject>Cadmium</subject><subject>Chemical Sciences</subject><subject>Donnan membrane technique</subject><subject>Lead</subject><subject>On-site monitoring</subject><subject>Screen-printed electrode</subject><subject>Zinc</subject><issn>0003-2670</issn><issn>1873-4324</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNp9kU1v1DAQhi0EokvhB3BBPoJEgu04cQynqt3SlVaqxMfZcpyx1qt8bG2niD_Db2W2W3rkZHv0zGPNO4S85azkjDef9qV1thSM1yVTJVaekRVvVVXISsjnZMUYqwrRKHZGXqW0x6fgTL4kZ6KRLdetXJE_m--bq9tv64_U0kOcO6B-jjRMNIW80BytAzpCtgNNB3DB5jBPtLMJeoqXq3ma7ITA2EU7Ac3gdlO4W4D-CnlHIww2IwkDuBxnt4MxOFT1gOCD6WBjpvwzXd8tYQhdDMuINpuWCCNMOb0mL7wdErx5PM_Jz-v1j8ubYnv7dXN5sS1c1apcaNv0vFYYhLC6qlvFtMVpOxAgpfaVBu_rRjmpQXS-Zp5rD9yzqpONd8JV5-TDybuzgznEMNr428w2mJuLrTnWGBeybRp2z5F9f2IxLxw1ZTOG5GAYMIF5SYYrUTMhlGaI8hPq4pxSBP_k5swcV2j2Bldojis0TOEvDfa8e9Qv3Qj9U8e_nSHw5QQABnIfIJrkAkwO-hAxVtPP4T_6v4o1rOw</recordid><startdate>20151008</startdate><enddate>20151008</enddate><creator>Parat, Corinne</creator><creator>Pinheiro, J.P.</creator><general>Elsevier B.V</general><general>Elsevier Masson</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>1XC</scope><orcidid>https://orcid.org/0000-0001-7925-9733</orcidid><orcidid>https://orcid.org/0000-0003-4601-8188</orcidid></search><sort><creationdate>20151008</creationdate><title>ISIDORE, a probe for in situ trace metal speciation based on Donnan membrane technique with related electrochemical detection part 1: Equilibrium measurements</title><author>Parat, Corinne ; Pinheiro, J.P.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c387t-9a6d1570152a9358709a000be2e449f39eff567c49e2bf50f19fe1f03b46fc2c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Analytical chemistry</topic><topic>Cadmium</topic><topic>Chemical Sciences</topic><topic>Donnan membrane technique</topic><topic>Lead</topic><topic>On-site monitoring</topic><topic>Screen-printed electrode</topic><topic>Zinc</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Parat, Corinne</creatorcontrib><creatorcontrib>Pinheiro, J.P.</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>Analytica chimica acta</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Parat, Corinne</au><au>Pinheiro, J.P.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>ISIDORE, a probe for in situ trace metal speciation based on Donnan membrane technique with related electrochemical detection part 1: Equilibrium measurements</atitle><jtitle>Analytica chimica acta</jtitle><addtitle>Anal Chim Acta</addtitle><date>2015-10-08</date><risdate>2015</risdate><volume>896</volume><spage>1</spage><epage>10</epage><pages>1-10</pages><issn>0003-2670</issn><eissn>1873-4324</eissn><abstract>This work presents the development of a new probe (ISIDORE probe) based on the hyphenation of a Donnan Membrane Technique device (DMT) to a screen-printed electrode through a flow-cell to determine the free zinc, cadmium and lead ion concentration in natural samples, such as a freshwater river. The probe displays many advantages namely: (i) the detection can be performed on-site, which avoids all problems inherent to sampling, transport and storage; (ii) the low volume of the acceptor solution implies shorter equilibration times; (ii) the electrochemical detection system allows monitoring the free ion concentration in the acceptor solution without sampling.
[Display omitted]
•A new probe has been developed for on-site analyses of free metal ion.•A screen-printed electrode has been hyphenated to a DMT device.•Analysis time has been reduced to 6H against 36H when using a classical DMT device.•This new probe has been successfully applied on a synthetic freshwater sample.</abstract><cop>Netherlands</cop><pub>Elsevier B.V</pub><pmid>26481984</pmid><doi>10.1016/j.aca.2015.07.016</doi><tpages>10</tpages><orcidid>https://orcid.org/0000-0001-7925-9733</orcidid><orcidid>https://orcid.org/0000-0003-4601-8188</orcidid></addata></record> |
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| language | eng |
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| source | Elsevier ScienceDirect Journals |
| subjects | Analytical chemistry Cadmium Chemical Sciences Donnan membrane technique Lead On-site monitoring Screen-printed electrode Zinc |
| title | ISIDORE, a probe for in situ trace metal speciation based on Donnan membrane technique with related electrochemical detection part 1: Equilibrium measurements |
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