Optimized methods for obtaining cellulose and cellulose sulfates from birch wood
The methods of obtaining cellulose and cellulose sulfates from birch wood based on the use of one-step catalytic delignification of wood by hydrogen peroxide in acetic acid–water medium were studied. The conditions of birch wood oxidative delignification by acetic acid/hydrogen peroxide mixtures in...
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| Veröffentlicht in: | Wood science and technology 2015-07, Vol.49 (4), p.825-843 |
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| creator | Kuznetsov, Boris N. Kuznetsova, Svetlana A. Levdansky, Vladimir A. Levdansky, Alexandr V. Vasil’eva, Natalia Yu Chesnokov, Nikolay V. Ivanchenko, Natalia M. Djakovitch, Laurent Pinel, Catherine |
| description | The methods of obtaining cellulose and cellulose sulfates from birch wood based on the use of one-step catalytic delignification of wood by hydrogen peroxide in acetic acid–water medium were studied. The conditions of birch wood oxidative delignification by acetic acid/hydrogen peroxide mixtures in the presence of sulfuric acid catalyst were optimized in order to obtain an acceptable yield of cellulose product with low content of residual lignin. Cellulose extracted from birch wood by green method was used for preparation of cellulose sulfates in dioxane solution. The homogeneous sulfation of obtained cellulose by chlorosulfonic acid in dioxane allows to reduce the fragmentation of polymer and to synthesize cellulose sulfates with a finer and more homogeneous structure as compared to cellulose sulfates prepared by heterogeneous sulfation in harmful pyridine. Obtained samples of cellulose and cellulose sulfates were characterized by XRD, SEM, AFM, NMR, FTIR, Raman, XPS and chemical methods. |
| doi_str_mv | 10.1007/s00226-015-0723-y |
| format | Article |
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The conditions of birch wood oxidative delignification by acetic acid/hydrogen peroxide mixtures in the presence of sulfuric acid catalyst were optimized in order to obtain an acceptable yield of cellulose product with low content of residual lignin. Cellulose extracted from birch wood by green method was used for preparation of cellulose sulfates in dioxane solution. The homogeneous sulfation of obtained cellulose by chlorosulfonic acid in dioxane allows to reduce the fragmentation of polymer and to synthesize cellulose sulfates with a finer and more homogeneous structure as compared to cellulose sulfates prepared by heterogeneous sulfation in harmful pyridine. Obtained samples of cellulose and cellulose sulfates were characterized by XRD, SEM, AFM, NMR, FTIR, Raman, XPS and chemical methods.</description><identifier>ISSN: 0043-7719</identifier><identifier>EISSN: 1432-5225</identifier><identifier>DOI: 10.1007/s00226-015-0723-y</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Acetic acid ; Biomedical and Life Sciences ; Catalysis ; Cellulose ; Ceramics ; Chemical industry ; Chemical Sciences ; Composites ; Environment and Society ; Environmental Sciences ; Glass ; Homogeneous structure ; Hydrogen peroxide ; Life Sciences ; Lignin ; Machines ; Manufacturing ; Natural Materials ; NMR ; Nuclear magnetic resonance ; Organic chemistry ; Original ; Polymers ; Processes ; Pyridines ; Sulfates ; Sulfation ; Sulfuric acid ; Wood Science & Technology ; X ray photoelectron spectroscopy</subject><ispartof>Wood science and technology, 2015-07, Vol.49 (4), p.825-843</ispartof><rights>Springer-Verlag Berlin Heidelberg 2015</rights><rights>Wood Science and Technology is a copyright of Springer, (2015). All Rights Reserved.</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c457t-21c3cf7b3afd5261a5ef5652349151de3fc0da778c3ae3d6b0462a00b46d25dd3</citedby><cites>FETCH-LOGICAL-c457t-21c3cf7b3afd5261a5ef5652349151de3fc0da778c3ae3d6b0462a00b46d25dd3</cites><orcidid>0000-0002-6340-3208 ; 0000-0001-5084-5608</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s00226-015-0723-y$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s00226-015-0723-y$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>230,314,780,784,885,27924,27925,41488,42557,51319</link.rule.ids><backlink>$$Uhttps://hal.science/hal-01179885$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Kuznetsov, Boris N.</creatorcontrib><creatorcontrib>Kuznetsova, Svetlana A.</creatorcontrib><creatorcontrib>Levdansky, Vladimir A.</creatorcontrib><creatorcontrib>Levdansky, Alexandr V.</creatorcontrib><creatorcontrib>Vasil’eva, Natalia Yu</creatorcontrib><creatorcontrib>Chesnokov, Nikolay V.</creatorcontrib><creatorcontrib>Ivanchenko, Natalia M.</creatorcontrib><creatorcontrib>Djakovitch, Laurent</creatorcontrib><creatorcontrib>Pinel, Catherine</creatorcontrib><title>Optimized methods for obtaining cellulose and cellulose sulfates from birch wood</title><title>Wood science and technology</title><addtitle>Wood Sci Technol</addtitle><description>The methods of obtaining cellulose and cellulose sulfates from birch wood based on the use of one-step catalytic delignification of wood by hydrogen peroxide in acetic acid–water medium were studied. The conditions of birch wood oxidative delignification by acetic acid/hydrogen peroxide mixtures in the presence of sulfuric acid catalyst were optimized in order to obtain an acceptable yield of cellulose product with low content of residual lignin. Cellulose extracted from birch wood by green method was used for preparation of cellulose sulfates in dioxane solution. The homogeneous sulfation of obtained cellulose by chlorosulfonic acid in dioxane allows to reduce the fragmentation of polymer and to synthesize cellulose sulfates with a finer and more homogeneous structure as compared to cellulose sulfates prepared by heterogeneous sulfation in harmful pyridine. Obtained samples of cellulose and cellulose sulfates were characterized by XRD, SEM, AFM, NMR, FTIR, Raman, XPS and chemical methods.</description><subject>Acetic acid</subject><subject>Biomedical and Life Sciences</subject><subject>Catalysis</subject><subject>Cellulose</subject><subject>Ceramics</subject><subject>Chemical industry</subject><subject>Chemical Sciences</subject><subject>Composites</subject><subject>Environment and Society</subject><subject>Environmental Sciences</subject><subject>Glass</subject><subject>Homogeneous structure</subject><subject>Hydrogen peroxide</subject><subject>Life Sciences</subject><subject>Lignin</subject><subject>Machines</subject><subject>Manufacturing</subject><subject>Natural Materials</subject><subject>NMR</subject><subject>Nuclear magnetic resonance</subject><subject>Organic chemistry</subject><subject>Original</subject><subject>Polymers</subject><subject>Processes</subject><subject>Pyridines</subject><subject>Sulfates</subject><subject>Sulfation</subject><subject>Sulfuric acid</subject><subject>Wood Science & Technology</subject><subject>X ray photoelectron spectroscopy</subject><issn>0043-7719</issn><issn>1432-5225</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><recordid>eNp1kE1Lw0AQhhdRsH78AG8BTx6iM7vZbHosRa1QqAc9L5v9aFOSbN1NlPrrTYmoF0_DDM_7MjyEXCHcIoC4iwCU5ikgT0FQlu6PyAQzRlNOKT8mE4CMpULg9JScxbgFQCGyYkKeV7uuaqpPa5LGdhtvYuJ8SHzZqaqt2nWibV33tY82Ua35s8W-dqqzAx58k5RV0Jvkw3tzQU6cqqO9_J7n5PXh_mW-SJerx6f5bJnqjIsupaiZdqJkyhlOc1TcOp5zyrIpcjSWOQ1GCVFopiwzeQlZThVAmeWGcmPYObkZezeqlrtQNSrspVeVXMyW8nADRDEtCv6OA3s9srvg33obO7n1fWiH9-QgjSIFgWygcKR08DEG635qEeRBshwlD81cHiTL_ZChYyYObLu24bf5_9AXDrx_Zw</recordid><startdate>20150701</startdate><enddate>20150701</enddate><creator>Kuznetsov, Boris N.</creator><creator>Kuznetsova, Svetlana A.</creator><creator>Levdansky, Vladimir A.</creator><creator>Levdansky, Alexandr V.</creator><creator>Vasil’eva, Natalia Yu</creator><creator>Chesnokov, Nikolay V.</creator><creator>Ivanchenko, Natalia M.</creator><creator>Djakovitch, Laurent</creator><creator>Pinel, Catherine</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><general>Springer Verlag</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>ATCPS</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>BHPHI</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>GNUQQ</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PATMY</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PYCSY</scope><scope>1XC</scope><orcidid>https://orcid.org/0000-0002-6340-3208</orcidid><orcidid>https://orcid.org/0000-0001-5084-5608</orcidid></search><sort><creationdate>20150701</creationdate><title>Optimized methods for obtaining cellulose and cellulose sulfates from birch wood</title><author>Kuznetsov, Boris N. ; Kuznetsova, Svetlana A. ; Levdansky, Vladimir A. ; Levdansky, Alexandr V. ; Vasil’eva, Natalia Yu ; Chesnokov, Nikolay V. ; Ivanchenko, Natalia M. ; Djakovitch, Laurent ; Pinel, Catherine</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c457t-21c3cf7b3afd5261a5ef5652349151de3fc0da778c3ae3d6b0462a00b46d25dd3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Acetic acid</topic><topic>Biomedical and Life Sciences</topic><topic>Catalysis</topic><topic>Cellulose</topic><topic>Ceramics</topic><topic>Chemical industry</topic><topic>Chemical Sciences</topic><topic>Composites</topic><topic>Environment and Society</topic><topic>Environmental Sciences</topic><topic>Glass</topic><topic>Homogeneous structure</topic><topic>Hydrogen peroxide</topic><topic>Life Sciences</topic><topic>Lignin</topic><topic>Machines</topic><topic>Manufacturing</topic><topic>Natural Materials</topic><topic>NMR</topic><topic>Nuclear magnetic resonance</topic><topic>Organic chemistry</topic><topic>Original</topic><topic>Polymers</topic><topic>Processes</topic><topic>Pyridines</topic><topic>Sulfates</topic><topic>Sulfation</topic><topic>Sulfuric acid</topic><topic>Wood Science & Technology</topic><topic>X ray photoelectron spectroscopy</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kuznetsov, Boris N.</creatorcontrib><creatorcontrib>Kuznetsova, Svetlana A.</creatorcontrib><creatorcontrib>Levdansky, Vladimir A.</creatorcontrib><creatorcontrib>Levdansky, Alexandr V.</creatorcontrib><creatorcontrib>Vasil’eva, Natalia Yu</creatorcontrib><creatorcontrib>Chesnokov, Nikolay V.</creatorcontrib><creatorcontrib>Ivanchenko, Natalia M.</creatorcontrib><creatorcontrib>Djakovitch, Laurent</creatorcontrib><creatorcontrib>Pinel, Catherine</creatorcontrib><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>Agricultural & Environmental Science Collection</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest Natural Science Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>ProQuest Central Student</collection><collection>SciTech Premium Collection</collection><collection>https://resources.nclive.org/materials</collection><collection>Environmental Science Database</collection><collection>Materials science collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>Environmental Science Collection</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>Wood science and technology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kuznetsov, Boris N.</au><au>Kuznetsova, Svetlana A.</au><au>Levdansky, Vladimir A.</au><au>Levdansky, Alexandr V.</au><au>Vasil’eva, Natalia Yu</au><au>Chesnokov, Nikolay V.</au><au>Ivanchenko, Natalia M.</au><au>Djakovitch, Laurent</au><au>Pinel, Catherine</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Optimized methods for obtaining cellulose and cellulose sulfates from birch wood</atitle><jtitle>Wood science and technology</jtitle><stitle>Wood Sci Technol</stitle><date>2015-07-01</date><risdate>2015</risdate><volume>49</volume><issue>4</issue><spage>825</spage><epage>843</epage><pages>825-843</pages><issn>0043-7719</issn><eissn>1432-5225</eissn><abstract>The methods of obtaining cellulose and cellulose sulfates from birch wood based on the use of one-step catalytic delignification of wood by hydrogen peroxide in acetic acid–water medium were studied. The conditions of birch wood oxidative delignification by acetic acid/hydrogen peroxide mixtures in the presence of sulfuric acid catalyst were optimized in order to obtain an acceptable yield of cellulose product with low content of residual lignin. Cellulose extracted from birch wood by green method was used for preparation of cellulose sulfates in dioxane solution. The homogeneous sulfation of obtained cellulose by chlorosulfonic acid in dioxane allows to reduce the fragmentation of polymer and to synthesize cellulose sulfates with a finer and more homogeneous structure as compared to cellulose sulfates prepared by heterogeneous sulfation in harmful pyridine. Obtained samples of cellulose and cellulose sulfates were characterized by XRD, SEM, AFM, NMR, FTIR, Raman, XPS and chemical methods.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s00226-015-0723-y</doi><tpages>19</tpages><orcidid>https://orcid.org/0000-0002-6340-3208</orcidid><orcidid>https://orcid.org/0000-0001-5084-5608</orcidid></addata></record> |
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| subjects | Acetic acid Biomedical and Life Sciences Catalysis Cellulose Ceramics Chemical industry Chemical Sciences Composites Environment and Society Environmental Sciences Glass Homogeneous structure Hydrogen peroxide Life Sciences Lignin Machines Manufacturing Natural Materials NMR Nuclear magnetic resonance Organic chemistry Original Polymers Processes Pyridines Sulfates Sulfation Sulfuric acid Wood Science & Technology X ray photoelectron spectroscopy |
| title | Optimized methods for obtaining cellulose and cellulose sulfates from birch wood |
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