Turn-On Luminescence Sensing and Real-Time Detection of Traces of Water in Organic Solvents by a Flexible Metal-Organic Framework
The development of efficient sensors for the determination of the water content in organic solvents is highly desirable for a number of chemical industries. Presented herein is a Mg2+ metal–organic framework (MOF), which exhibits the remarkable capability to rapidly detect traces of water (0.05–5 %...
Gespeichert in:
| Veröffentlicht in: | Angewandte Chemie International Edition 2015-01, Vol.54 (5), p.1651-1656 |
|---|---|
| Hauptverfasser: | , , , , , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 1656 |
|---|---|
| container_issue | 5 |
| container_start_page | 1651 |
| container_title | Angewandte Chemie International Edition |
| container_volume | 54 |
| creator | Douvali, Antigoni Tsipis, Athanassios C. Eliseeva, Svetlana V. Petoud, Stéphane Papaefstathiou, Giannis S. Malliakas, Christos D. Papadas, Ioannis Armatas, Gerasimos S. Margiolaki, Irene Kanatzidis, Mercouri G. Lazarides, Theodore Manos, Manolis J. |
| description | The development of efficient sensors for the determination of the water content in organic solvents is highly desirable for a number of chemical industries. Presented herein is a Mg2+ metal–organic framework (MOF), which exhibits the remarkable capability to rapidly detect traces of water (0.05–5 % v/v) in various organic solvents through an unusual turn‐on luminescence sensing mechanism. The extraordinary sensitivity and fast response of this MOF for water, and its reusability make it one of the most powerful water sensors known.
Testing the water: A Mg2+ metal–organic framework (MOF) is reported. It has the extraordinary capability to detect, in real time, trace water concentrations (0.05–5 %) in various organic solvents through an unusual turn‐on luminescence sensing mechanism. The sensitivity and fast response of this MOF for water, and its reusability, make it one of the most powerful water sensors known. |
| doi_str_mv | 10.1002/anie.201410612 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_hal_p</sourceid><recordid>TN_cdi_hal_primary_oai_HAL_hal_01171231v1</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1652415154</sourcerecordid><originalsourceid>FETCH-LOGICAL-c6512-52ccbd6f16d6e732a2c46ac7f8d071f9a0dca1cb3e08c8d4a0d41d7ed1f4be783</originalsourceid><addsrcrecordid>eNqFkUFPGzEQhVdVq0Jprz1WlnppD5t6bK-9HEMggJQSqaTK0fJ6Z6lh10vtDZAj_xxHgajqBfngsfW9p5l5WfYZ6AgoZT-MdzhiFARQCexNtg8Fg5wrxd-mWnCeq7KAvexDjNeJL0sq32d7rBClopLtZ4-LVfD53JPZqnMeo0VvkVyij85fEeNr8gtNmy9ch-QYB7SD6z3pG7IIxmLcVEszYCDOk3m4Su1Yctm3d-iHSKo1MWTa4oOrWiQ_cUhOL9A0mA7v-3DzMXvXmDbip-f7IPs9PVlMzvLZ_PR8Mp7lVhbA8oJZW9WyAVlLVJwZZoU0VjVlTRU0h4bW1oCtONLSlrVIbwG1whoaUaEq-UH2fev7x7T6NrjOhLXujdNn45ne_FEABYzDHST225a9Df3fFcZBdy6tpm2Nx34VNSgK6XBOX0dlwQQUUIiEfv0Pve7T9tPQiRJpJi5gQ422lA19jAGbXbNA9SZzvclc7zJPgi_Ptquqw3qHv4ScgMMtcO9aXL9ip8cX5yf_mudbrYsDPuy0Jtxoqbgq9PLiVNPFsZwe0aWe8CcHvcXx</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1647323414</pqid></control><display><type>article</type><title>Turn-On Luminescence Sensing and Real-Time Detection of Traces of Water in Organic Solvents by a Flexible Metal-Organic Framework</title><source>MEDLINE</source><source>Access via Wiley Online Library</source><creator>Douvali, Antigoni ; Tsipis, Athanassios C. ; Eliseeva, Svetlana V. ; Petoud, Stéphane ; Papaefstathiou, Giannis S. ; Malliakas, Christos D. ; Papadas, Ioannis ; Armatas, Gerasimos S. ; Margiolaki, Irene ; Kanatzidis, Mercouri G. ; Lazarides, Theodore ; Manos, Manolis J.</creator><creatorcontrib>Douvali, Antigoni ; Tsipis, Athanassios C. ; Eliseeva, Svetlana V. ; Petoud, Stéphane ; Papaefstathiou, Giannis S. ; Malliakas, Christos D. ; Papadas, Ioannis ; Armatas, Gerasimos S. ; Margiolaki, Irene ; Kanatzidis, Mercouri G. ; Lazarides, Theodore ; Manos, Manolis J.</creatorcontrib><description>The development of efficient sensors for the determination of the water content in organic solvents is highly desirable for a number of chemical industries. Presented herein is a Mg2+ metal–organic framework (MOF), which exhibits the remarkable capability to rapidly detect traces of water (0.05–5 % v/v) in various organic solvents through an unusual turn‐on luminescence sensing mechanism. The extraordinary sensitivity and fast response of this MOF for water, and its reusability make it one of the most powerful water sensors known.
Testing the water: A Mg2+ metal–organic framework (MOF) is reported. It has the extraordinary capability to detect, in real time, trace water concentrations (0.05–5 %) in various organic solvents through an unusual turn‐on luminescence sensing mechanism. The sensitivity and fast response of this MOF for water, and its reusability, make it one of the most powerful water sensors known.</description><edition>International ed. in English</edition><identifier>ISSN: 1433-7851</identifier><identifier>EISSN: 1521-3773</identifier><identifier>DOI: 10.1002/anie.201410612</identifier><identifier>PMID: 25487062</identifier><identifier>CODEN: ACIEAY</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>Chemical industries ; Chemical Sciences ; Coordination Complexes - chemistry ; crystal engineering ; Detection ; Luminescence ; Metal-organic frameworks ; Metals, Alkaline Earth - chemistry ; microporous materials ; Moisture content ; Organometallic Compounds - chemistry ; Real time ; Sensors ; Solvents ; Solvents - chemistry ; Spectrometry, Fluorescence ; Thermodynamics ; Water - analysis</subject><ispartof>Angewandte Chemie International Edition, 2015-01, Vol.54 (5), p.1651-1656</ispartof><rights>2015 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.</rights><rights>2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c6512-52ccbd6f16d6e732a2c46ac7f8d071f9a0dca1cb3e08c8d4a0d41d7ed1f4be783</citedby><cites>FETCH-LOGICAL-c6512-52ccbd6f16d6e732a2c46ac7f8d071f9a0dca1cb3e08c8d4a0d41d7ed1f4be783</cites><orcidid>0000-0002-1768-8513</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fanie.201410612$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fanie.201410612$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>230,314,780,784,885,1417,27924,27925,45574,45575</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/25487062$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink><backlink>$$Uhttps://hal.science/hal-01171231$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Douvali, Antigoni</creatorcontrib><creatorcontrib>Tsipis, Athanassios C.</creatorcontrib><creatorcontrib>Eliseeva, Svetlana V.</creatorcontrib><creatorcontrib>Petoud, Stéphane</creatorcontrib><creatorcontrib>Papaefstathiou, Giannis S.</creatorcontrib><creatorcontrib>Malliakas, Christos D.</creatorcontrib><creatorcontrib>Papadas, Ioannis</creatorcontrib><creatorcontrib>Armatas, Gerasimos S.</creatorcontrib><creatorcontrib>Margiolaki, Irene</creatorcontrib><creatorcontrib>Kanatzidis, Mercouri G.</creatorcontrib><creatorcontrib>Lazarides, Theodore</creatorcontrib><creatorcontrib>Manos, Manolis J.</creatorcontrib><title>Turn-On Luminescence Sensing and Real-Time Detection of Traces of Water in Organic Solvents by a Flexible Metal-Organic Framework</title><title>Angewandte Chemie International Edition</title><addtitle>Angew. Chem. Int. Ed</addtitle><description>The development of efficient sensors for the determination of the water content in organic solvents is highly desirable for a number of chemical industries. Presented herein is a Mg2+ metal–organic framework (MOF), which exhibits the remarkable capability to rapidly detect traces of water (0.05–5 % v/v) in various organic solvents through an unusual turn‐on luminescence sensing mechanism. The extraordinary sensitivity and fast response of this MOF for water, and its reusability make it one of the most powerful water sensors known.
Testing the water: A Mg2+ metal–organic framework (MOF) is reported. It has the extraordinary capability to detect, in real time, trace water concentrations (0.05–5 %) in various organic solvents through an unusual turn‐on luminescence sensing mechanism. The sensitivity and fast response of this MOF for water, and its reusability, make it one of the most powerful water sensors known.</description><subject>Chemical industries</subject><subject>Chemical Sciences</subject><subject>Coordination Complexes - chemistry</subject><subject>crystal engineering</subject><subject>Detection</subject><subject>Luminescence</subject><subject>Metal-organic frameworks</subject><subject>Metals, Alkaline Earth - chemistry</subject><subject>microporous materials</subject><subject>Moisture content</subject><subject>Organometallic Compounds - chemistry</subject><subject>Real time</subject><subject>Sensors</subject><subject>Solvents</subject><subject>Solvents - chemistry</subject><subject>Spectrometry, Fluorescence</subject><subject>Thermodynamics</subject><subject>Water - analysis</subject><issn>1433-7851</issn><issn>1521-3773</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkUFPGzEQhVdVq0Jprz1WlnppD5t6bK-9HEMggJQSqaTK0fJ6Z6lh10vtDZAj_xxHgajqBfngsfW9p5l5WfYZ6AgoZT-MdzhiFARQCexNtg8Fg5wrxd-mWnCeq7KAvexDjNeJL0sq32d7rBClopLtZ4-LVfD53JPZqnMeo0VvkVyij85fEeNr8gtNmy9ch-QYB7SD6z3pG7IIxmLcVEszYCDOk3m4Su1Yctm3d-iHSKo1MWTa4oOrWiQ_cUhOL9A0mA7v-3DzMXvXmDbip-f7IPs9PVlMzvLZ_PR8Mp7lVhbA8oJZW9WyAVlLVJwZZoU0VjVlTRU0h4bW1oCtONLSlrVIbwG1whoaUaEq-UH2fev7x7T6NrjOhLXujdNn45ne_FEABYzDHST225a9Df3fFcZBdy6tpm2Nx34VNSgK6XBOX0dlwQQUUIiEfv0Pve7T9tPQiRJpJi5gQ422lA19jAGbXbNA9SZzvclc7zJPgi_Ptquqw3qHv4ScgMMtcO9aXL9ip8cX5yf_mudbrYsDPuy0Jtxoqbgq9PLiVNPFsZwe0aWe8CcHvcXx</recordid><startdate>20150126</startdate><enddate>20150126</enddate><creator>Douvali, Antigoni</creator><creator>Tsipis, Athanassios C.</creator><creator>Eliseeva, Svetlana V.</creator><creator>Petoud, Stéphane</creator><creator>Papaefstathiou, Giannis S.</creator><creator>Malliakas, Christos D.</creator><creator>Papadas, Ioannis</creator><creator>Armatas, Gerasimos S.</creator><creator>Margiolaki, Irene</creator><creator>Kanatzidis, Mercouri G.</creator><creator>Lazarides, Theodore</creator><creator>Manos, Manolis J.</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><general>Wiley Subscription Services, Inc</general><general>Wiley-VCH Verlag</general><scope>BSCLL</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7TM</scope><scope>K9.</scope><scope>7X8</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>1XC</scope><orcidid>https://orcid.org/0000-0002-1768-8513</orcidid></search><sort><creationdate>20150126</creationdate><title>Turn-On Luminescence Sensing and Real-Time Detection of Traces of Water in Organic Solvents by a Flexible Metal-Organic Framework</title><author>Douvali, Antigoni ; Tsipis, Athanassios C. ; Eliseeva, Svetlana V. ; Petoud, Stéphane ; Papaefstathiou, Giannis S. ; Malliakas, Christos D. ; Papadas, Ioannis ; Armatas, Gerasimos S. ; Margiolaki, Irene ; Kanatzidis, Mercouri G. ; Lazarides, Theodore ; Manos, Manolis J.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c6512-52ccbd6f16d6e732a2c46ac7f8d071f9a0dca1cb3e08c8d4a0d41d7ed1f4be783</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Chemical industries</topic><topic>Chemical Sciences</topic><topic>Coordination Complexes - chemistry</topic><topic>crystal engineering</topic><topic>Detection</topic><topic>Luminescence</topic><topic>Metal-organic frameworks</topic><topic>Metals, Alkaline Earth - chemistry</topic><topic>microporous materials</topic><topic>Moisture content</topic><topic>Organometallic Compounds - chemistry</topic><topic>Real time</topic><topic>Sensors</topic><topic>Solvents</topic><topic>Solvents - chemistry</topic><topic>Spectrometry, Fluorescence</topic><topic>Thermodynamics</topic><topic>Water - analysis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Douvali, Antigoni</creatorcontrib><creatorcontrib>Tsipis, Athanassios C.</creatorcontrib><creatorcontrib>Eliseeva, Svetlana V.</creatorcontrib><creatorcontrib>Petoud, Stéphane</creatorcontrib><creatorcontrib>Papaefstathiou, Giannis S.</creatorcontrib><creatorcontrib>Malliakas, Christos D.</creatorcontrib><creatorcontrib>Papadas, Ioannis</creatorcontrib><creatorcontrib>Armatas, Gerasimos S.</creatorcontrib><creatorcontrib>Margiolaki, Irene</creatorcontrib><creatorcontrib>Kanatzidis, Mercouri G.</creatorcontrib><creatorcontrib>Lazarides, Theodore</creatorcontrib><creatorcontrib>Manos, Manolis J.</creatorcontrib><collection>Istex</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Nucleic Acids Abstracts</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>Angewandte Chemie International Edition</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Douvali, Antigoni</au><au>Tsipis, Athanassios C.</au><au>Eliseeva, Svetlana V.</au><au>Petoud, Stéphane</au><au>Papaefstathiou, Giannis S.</au><au>Malliakas, Christos D.</au><au>Papadas, Ioannis</au><au>Armatas, Gerasimos S.</au><au>Margiolaki, Irene</au><au>Kanatzidis, Mercouri G.</au><au>Lazarides, Theodore</au><au>Manos, Manolis J.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Turn-On Luminescence Sensing and Real-Time Detection of Traces of Water in Organic Solvents by a Flexible Metal-Organic Framework</atitle><jtitle>Angewandte Chemie International Edition</jtitle><addtitle>Angew. Chem. Int. Ed</addtitle><date>2015-01-26</date><risdate>2015</risdate><volume>54</volume><issue>5</issue><spage>1651</spage><epage>1656</epage><pages>1651-1656</pages><issn>1433-7851</issn><eissn>1521-3773</eissn><coden>ACIEAY</coden><abstract>The development of efficient sensors for the determination of the water content in organic solvents is highly desirable for a number of chemical industries. Presented herein is a Mg2+ metal–organic framework (MOF), which exhibits the remarkable capability to rapidly detect traces of water (0.05–5 % v/v) in various organic solvents through an unusual turn‐on luminescence sensing mechanism. The extraordinary sensitivity and fast response of this MOF for water, and its reusability make it one of the most powerful water sensors known.
Testing the water: A Mg2+ metal–organic framework (MOF) is reported. It has the extraordinary capability to detect, in real time, trace water concentrations (0.05–5 %) in various organic solvents through an unusual turn‐on luminescence sensing mechanism. The sensitivity and fast response of this MOF for water, and its reusability, make it one of the most powerful water sensors known.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><pmid>25487062</pmid><doi>10.1002/anie.201410612</doi><tpages>6</tpages><edition>International ed. in English</edition><orcidid>https://orcid.org/0000-0002-1768-8513</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1433-7851 |
| ispartof | Angewandte Chemie International Edition, 2015-01, Vol.54 (5), p.1651-1656 |
| issn | 1433-7851 1521-3773 |
| language | eng |
| recordid | cdi_hal_primary_oai_HAL_hal_01171231v1 |
| source | MEDLINE; Access via Wiley Online Library |
| subjects | Chemical industries Chemical Sciences Coordination Complexes - chemistry crystal engineering Detection Luminescence Metal-organic frameworks Metals, Alkaline Earth - chemistry microporous materials Moisture content Organometallic Compounds - chemistry Real time Sensors Solvents Solvents - chemistry Spectrometry, Fluorescence Thermodynamics Water - analysis |
| title | Turn-On Luminescence Sensing and Real-Time Detection of Traces of Water in Organic Solvents by a Flexible Metal-Organic Framework |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-18T20%3A17%3A55IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_hal_p&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Turn-On%20Luminescence%20Sensing%20and%20Real-Time%20Detection%20of%20Traces%20of%20Water%20in%20Organic%20Solvents%20by%20a%20Flexible%20Metal-Organic%20Framework&rft.jtitle=Angewandte%20Chemie%20International%20Edition&rft.au=Douvali,%20Antigoni&rft.date=2015-01-26&rft.volume=54&rft.issue=5&rft.spage=1651&rft.epage=1656&rft.pages=1651-1656&rft.issn=1433-7851&rft.eissn=1521-3773&rft.coden=ACIEAY&rft_id=info:doi/10.1002/anie.201410612&rft_dat=%3Cproquest_hal_p%3E1652415154%3C/proquest_hal_p%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1647323414&rft_id=info:pmid/25487062&rfr_iscdi=true |