Pyridyl-Functionalised 3H-1,2,3,4-Triazaphospholes: Synthesis, Coordination Chemistry and Photophysical Properties of Low-Coordinate Phosphorus Compounds

Novel conjugated, pyridyl‐functionalised triazaphospholes with either tBu or SiMe3 substituents at the 5‐position of the N3PC heterocycle have been prepared by a [3+2] cycloaddition reaction and compared with structurally related, triazole‐based systems. Photoexcitation of the 2‐pyridyl‐substituted...

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Veröffentlicht in:	Chemistry : a European journal 2015-07, Vol.21 (31), p.11096-11109
Hauptverfasser:	Sklorz, Julian A. W., Hoof, Santina, Rades, Nadine, De Rycke, Nicolas, Könczöl, László, Szieberth, Dénes, Weber, Manuela, Wiecko, Jelena, Nyulászi, László, Hissler, Muriel, Müller, Christian
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemical Sciences Coordination compounds coordination modes Cycloaddition density functional calculations Derivatives Emission heterocycles luminescence Mathematical analysis Nitrogen Nitrogen atoms Organic chemistry Phosphorus Synthesis (chemistry) Triazoles
Online-Zugang:	Volltext
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