Synthesis and conformational analysis of redox-active ferrocenyl-calixarenes
A novel synthetic approach toward redox-active calixarene-based receptors is described wherein ferrocene fragments have been introduced at the lower rim through anion-binding urea or amide connections. A thorough 1H NMR investigation on a series of calixarene-ferrocene receptors was performed in ord...
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| Veröffentlicht in: | Tetrahedron 2009-01, Vol.65 (3), p.672-676 |
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| container_end_page | 676 |
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| container_issue | 3 |
| container_start_page | 672 |
| container_title | Tetrahedron |
| container_volume | 65 |
| creator | Métay, Estelle Duclos, Marie Christine Pellet-Rostaing, Stéphane Lemaire, Marc Kannappan, Ramu Bucher, Christophe Saint-Aman, Eric Chaix, Carole |
| description | A novel synthetic approach toward redox-active calixarene-based receptors is described wherein ferrocene fragments have been introduced at the lower rim through anion-binding urea or amide connections. A thorough
1H NMR investigation on a series of calixarene-ferrocene receptors was performed in order to estimate their hydrogen bonding-driven self-association properties and improve our understanding of the correlation between molecular structures and redox properties.
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| doi_str_mv | 10.1016/j.tet.2008.11.032 |
| format | Article |
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1H NMR investigation on a series of calixarene-ferrocene receptors was performed in order to estimate their hydrogen bonding-driven self-association properties and improve our understanding of the correlation between molecular structures and redox properties.
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| ispartof | Tetrahedron, 2009-01, Vol.65 (3), p.672-676 |
| issn | 0040-4020 1464-5416 |
| language | eng |
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| source | Access via ScienceDirect (Elsevier) |
| subjects | Alicyclic compounds Alicyclic compounds, terpenoids, prostaglandins, steroids Chemical Sciences Chemistry Exact sciences and technology Organic chemistry Preparations and properties |
| title | Synthesis and conformational analysis of redox-active ferrocenyl-calixarenes |
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