Characterization and Luminescence Properties of Lanthanide-Based Polynuclear Complexes Nanoaggregates
For the first time, hexanuclear complexes with general chemical formula [Ln6O(OH)8(NO3)6(H2O) n ]2+ with n = 12 for Ln = Sm–Lu and Y and n = 14 for Ln = Pr and Nd were stabilized as nanoaggregates in ethylene glycol (EG). These unprecedented nanoaggregates were structurally characterized by 89Y an...
Gespeichert in:
Veröffentlicht in: | Inorganic chemistry 2015-06, Vol.54 (12), p.6043-6054 |
---|---|
Hauptverfasser: | , , , , , , , , , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
container_end_page | 6054 |
---|---|
container_issue | 12 |
container_start_page | 6043 |
container_title | Inorganic chemistry |
container_volume | 54 |
creator | Le Natur, François Calvez, Guillaume Guégan, Jean-Paul Le Pollès, Laurent Trivelli, Xavier Bernot, Kevin Daiguebonne, Carole Neaime, Chrystelle Costuas, Karine Grasset, Fabien Guillou, Olivier |
description | For the first time, hexanuclear complexes with general chemical formula [Ln6O(OH)8(NO3)6(H2O) n ]2+ with n = 12 for Ln = Sm–Lu and Y and n = 14 for Ln = Pr and Nd were stabilized as nanoaggregates in ethylene glycol (EG). These unprecedented nanoaggregates were structurally characterized by 89Y and 1H NMR spectroscopy, UV–vis absorption and luminescence spectroscopies, electrospray ionization mass spectrometry, diffusion ordered spectroscopy, transmission electron microscopy, and dynamic light scattering. These nanoaggregates present a 200 nm mean solvodynamic diameter. In these nanoaggregates, hexanuclear complexes are isolated and solvated by EG molecules. The replacement of ethylene glycol by 2-hydroxybenzyl alcohol provides new nanoaggregates that present an antenna effect toward lanthanide ions. This results in a significant enhancement of the luminescence properties of the aggregates and demonstrates the suitability of the strategy for obtaining highly tunable luminescent solutions. |
doi_str_mv | 10.1021/acs.inorgchem.5b00947 |
format | Article |
fullrecord | <record><control><sourceid>proquest_hal_p</sourceid><recordid>TN_cdi_hal_primary_oai_HAL_hal_01162339v1</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1689309989</sourcerecordid><originalsourceid>FETCH-LOGICAL-a451t-19404186d0ec1f55a42cb1cfcef02d52e6b51eeb187bf17f737394596d7c8943</originalsourceid><addsrcrecordid>eNqFkTFv2zAQhYmiReO4_QktNLaDXJ5EUuaYGm1SQEgyZMhGnKiTrUAiXVIKmv760LDrtQtJEN97h3uPsU_AV8AL-IY2rnrnw9buaFzJhnMtqjdsAbLguQT--JYtOE9vUEpfsMsYn3hiSqHes4tC8UKAhAWjzQ4D2olC_xen3rsMXZvV89g7ipacpew--D2FqaeY-S6r0U07dH1L-XeM1Gb3fnhxsx0IQ7bx436gP4m8Redxuw20xYniB_auwyHSx9O9ZA8_fzxsbvL67vrX5qrOUUiYctCCC1irlpOFTkoUhW3AdpY6XrSyINVIIGpgXTUdVF1VVqUWUqu2smstyiX7erTd4WD2oR8xvBiPvbm5qs3hjwOooiz1MyT2y5HdB_97pjiZsU8LDwM68nM0oNa65Fqnc8nkEbXBxxioO3sDN4cyTCrDnMswpzKS7vNpxNyM1J5V_9JPAByBg_7Jz8GlcP5j-gpyRJsf</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1689309989</pqid></control><display><type>article</type><title>Characterization and Luminescence Properties of Lanthanide-Based Polynuclear Complexes Nanoaggregates</title><source>American Chemical Society</source><creator>Le Natur, François ; Calvez, Guillaume ; Guégan, Jean-Paul ; Le Pollès, Laurent ; Trivelli, Xavier ; Bernot, Kevin ; Daiguebonne, Carole ; Neaime, Chrystelle ; Costuas, Karine ; Grasset, Fabien ; Guillou, Olivier</creator><creatorcontrib>Le Natur, François ; Calvez, Guillaume ; Guégan, Jean-Paul ; Le Pollès, Laurent ; Trivelli, Xavier ; Bernot, Kevin ; Daiguebonne, Carole ; Neaime, Chrystelle ; Costuas, Karine ; Grasset, Fabien ; Guillou, Olivier</creatorcontrib><description>For the first time, hexanuclear complexes with general chemical formula [Ln6O(OH)8(NO3)6(H2O) n ]2+ with n = 12 for Ln = Sm–Lu and Y and n = 14 for Ln = Pr and Nd were stabilized as nanoaggregates in ethylene glycol (EG). These unprecedented nanoaggregates were structurally characterized by 89Y and 1H NMR spectroscopy, UV–vis absorption and luminescence spectroscopies, electrospray ionization mass spectrometry, diffusion ordered spectroscopy, transmission electron microscopy, and dynamic light scattering. These nanoaggregates present a 200 nm mean solvodynamic diameter. In these nanoaggregates, hexanuclear complexes are isolated and solvated by EG molecules. The replacement of ethylene glycol by 2-hydroxybenzyl alcohol provides new nanoaggregates that present an antenna effect toward lanthanide ions. This results in a significant enhancement of the luminescence properties of the aggregates and demonstrates the suitability of the strategy for obtaining highly tunable luminescent solutions.</description><identifier>ISSN: 0020-1669</identifier><identifier>EISSN: 1520-510X</identifier><identifier>DOI: 10.1021/acs.inorgchem.5b00947</identifier><identifier>PMID: 26024151</identifier><language>eng</language><publisher>United States: American Chemical Society</publisher><subject>Chemical Sciences</subject><ispartof>Inorganic chemistry, 2015-06, Vol.54 (12), p.6043-6054</ispartof><rights>Copyright © American Chemical Society</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a451t-19404186d0ec1f55a42cb1cfcef02d52e6b51eeb187bf17f737394596d7c8943</citedby><cites>FETCH-LOGICAL-a451t-19404186d0ec1f55a42cb1cfcef02d52e6b51eeb187bf17f737394596d7c8943</cites><orcidid>0000-0003-0338-0494 ; 0000-0001-8337-6246 ; 0000-0002-4911-0214 ; 0000-0001-6775-9650 ; 0000-0002-2133-7214</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/acs.inorgchem.5b00947$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/acs.inorgchem.5b00947$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>230,315,782,786,887,2767,27083,27931,27932,56745,56795</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/26024151$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink><backlink>$$Uhttps://univ-rennes.hal.science/hal-01162339$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Le Natur, François</creatorcontrib><creatorcontrib>Calvez, Guillaume</creatorcontrib><creatorcontrib>Guégan, Jean-Paul</creatorcontrib><creatorcontrib>Le Pollès, Laurent</creatorcontrib><creatorcontrib>Trivelli, Xavier</creatorcontrib><creatorcontrib>Bernot, Kevin</creatorcontrib><creatorcontrib>Daiguebonne, Carole</creatorcontrib><creatorcontrib>Neaime, Chrystelle</creatorcontrib><creatorcontrib>Costuas, Karine</creatorcontrib><creatorcontrib>Grasset, Fabien</creatorcontrib><creatorcontrib>Guillou, Olivier</creatorcontrib><title>Characterization and Luminescence Properties of Lanthanide-Based Polynuclear Complexes Nanoaggregates</title><title>Inorganic chemistry</title><addtitle>Inorg. Chem</addtitle><description>For the first time, hexanuclear complexes with general chemical formula [Ln6O(OH)8(NO3)6(H2O) n ]2+ with n = 12 for Ln = Sm–Lu and Y and n = 14 for Ln = Pr and Nd were stabilized as nanoaggregates in ethylene glycol (EG). These unprecedented nanoaggregates were structurally characterized by 89Y and 1H NMR spectroscopy, UV–vis absorption and luminescence spectroscopies, electrospray ionization mass spectrometry, diffusion ordered spectroscopy, transmission electron microscopy, and dynamic light scattering. These nanoaggregates present a 200 nm mean solvodynamic diameter. In these nanoaggregates, hexanuclear complexes are isolated and solvated by EG molecules. The replacement of ethylene glycol by 2-hydroxybenzyl alcohol provides new nanoaggregates that present an antenna effect toward lanthanide ions. This results in a significant enhancement of the luminescence properties of the aggregates and demonstrates the suitability of the strategy for obtaining highly tunable luminescent solutions.</description><subject>Chemical Sciences</subject><issn>0020-1669</issn><issn>1520-510X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNqFkTFv2zAQhYmiReO4_QktNLaDXJ5EUuaYGm1SQEgyZMhGnKiTrUAiXVIKmv760LDrtQtJEN97h3uPsU_AV8AL-IY2rnrnw9buaFzJhnMtqjdsAbLguQT--JYtOE9vUEpfsMsYn3hiSqHes4tC8UKAhAWjzQ4D2olC_xen3rsMXZvV89g7ipacpew--D2FqaeY-S6r0U07dH1L-XeM1Gb3fnhxsx0IQ7bx436gP4m8Redxuw20xYniB_auwyHSx9O9ZA8_fzxsbvL67vrX5qrOUUiYctCCC1irlpOFTkoUhW3AdpY6XrSyINVIIGpgXTUdVF1VVqUWUqu2smstyiX7erTd4WD2oR8xvBiPvbm5qs3hjwOooiz1MyT2y5HdB_97pjiZsU8LDwM68nM0oNa65Fqnc8nkEbXBxxioO3sDN4cyTCrDnMswpzKS7vNpxNyM1J5V_9JPAByBg_7Jz8GlcP5j-gpyRJsf</recordid><startdate>20150615</startdate><enddate>20150615</enddate><creator>Le Natur, François</creator><creator>Calvez, Guillaume</creator><creator>Guégan, Jean-Paul</creator><creator>Le Pollès, Laurent</creator><creator>Trivelli, Xavier</creator><creator>Bernot, Kevin</creator><creator>Daiguebonne, Carole</creator><creator>Neaime, Chrystelle</creator><creator>Costuas, Karine</creator><creator>Grasset, Fabien</creator><creator>Guillou, Olivier</creator><general>American Chemical Society</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>1XC</scope><orcidid>https://orcid.org/0000-0003-0338-0494</orcidid><orcidid>https://orcid.org/0000-0001-8337-6246</orcidid><orcidid>https://orcid.org/0000-0002-4911-0214</orcidid><orcidid>https://orcid.org/0000-0001-6775-9650</orcidid><orcidid>https://orcid.org/0000-0002-2133-7214</orcidid></search><sort><creationdate>20150615</creationdate><title>Characterization and Luminescence Properties of Lanthanide-Based Polynuclear Complexes Nanoaggregates</title><author>Le Natur, François ; Calvez, Guillaume ; Guégan, Jean-Paul ; Le Pollès, Laurent ; Trivelli, Xavier ; Bernot, Kevin ; Daiguebonne, Carole ; Neaime, Chrystelle ; Costuas, Karine ; Grasset, Fabien ; Guillou, Olivier</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a451t-19404186d0ec1f55a42cb1cfcef02d52e6b51eeb187bf17f737394596d7c8943</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Chemical Sciences</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Le Natur, François</creatorcontrib><creatorcontrib>Calvez, Guillaume</creatorcontrib><creatorcontrib>Guégan, Jean-Paul</creatorcontrib><creatorcontrib>Le Pollès, Laurent</creatorcontrib><creatorcontrib>Trivelli, Xavier</creatorcontrib><creatorcontrib>Bernot, Kevin</creatorcontrib><creatorcontrib>Daiguebonne, Carole</creatorcontrib><creatorcontrib>Neaime, Chrystelle</creatorcontrib><creatorcontrib>Costuas, Karine</creatorcontrib><creatorcontrib>Grasset, Fabien</creatorcontrib><creatorcontrib>Guillou, Olivier</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>Inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Le Natur, François</au><au>Calvez, Guillaume</au><au>Guégan, Jean-Paul</au><au>Le Pollès, Laurent</au><au>Trivelli, Xavier</au><au>Bernot, Kevin</au><au>Daiguebonne, Carole</au><au>Neaime, Chrystelle</au><au>Costuas, Karine</au><au>Grasset, Fabien</au><au>Guillou, Olivier</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Characterization and Luminescence Properties of Lanthanide-Based Polynuclear Complexes Nanoaggregates</atitle><jtitle>Inorganic chemistry</jtitle><addtitle>Inorg. Chem</addtitle><date>2015-06-15</date><risdate>2015</risdate><volume>54</volume><issue>12</issue><spage>6043</spage><epage>6054</epage><pages>6043-6054</pages><issn>0020-1669</issn><eissn>1520-510X</eissn><abstract>For the first time, hexanuclear complexes with general chemical formula [Ln6O(OH)8(NO3)6(H2O) n ]2+ with n = 12 for Ln = Sm–Lu and Y and n = 14 for Ln = Pr and Nd were stabilized as nanoaggregates in ethylene glycol (EG). These unprecedented nanoaggregates were structurally characterized by 89Y and 1H NMR spectroscopy, UV–vis absorption and luminescence spectroscopies, electrospray ionization mass spectrometry, diffusion ordered spectroscopy, transmission electron microscopy, and dynamic light scattering. These nanoaggregates present a 200 nm mean solvodynamic diameter. In these nanoaggregates, hexanuclear complexes are isolated and solvated by EG molecules. The replacement of ethylene glycol by 2-hydroxybenzyl alcohol provides new nanoaggregates that present an antenna effect toward lanthanide ions. This results in a significant enhancement of the luminescence properties of the aggregates and demonstrates the suitability of the strategy for obtaining highly tunable luminescent solutions.</abstract><cop>United States</cop><pub>American Chemical Society</pub><pmid>26024151</pmid><doi>10.1021/acs.inorgchem.5b00947</doi><tpages>12</tpages><orcidid>https://orcid.org/0000-0003-0338-0494</orcidid><orcidid>https://orcid.org/0000-0001-8337-6246</orcidid><orcidid>https://orcid.org/0000-0002-4911-0214</orcidid><orcidid>https://orcid.org/0000-0001-6775-9650</orcidid><orcidid>https://orcid.org/0000-0002-2133-7214</orcidid></addata></record> |
fulltext | fulltext |
identifier | ISSN: 0020-1669 |
ispartof | Inorganic chemistry, 2015-06, Vol.54 (12), p.6043-6054 |
issn | 0020-1669 1520-510X |
language | eng |
recordid | cdi_hal_primary_oai_HAL_hal_01162339v1 |
source | American Chemical Society |
subjects | Chemical Sciences |
title | Characterization and Luminescence Properties of Lanthanide-Based Polynuclear Complexes Nanoaggregates |
url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-06T16%3A24%3A09IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_hal_p&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Characterization%20and%20Luminescence%20Properties%20of%20Lanthanide-Based%20Polynuclear%20Complexes%20Nanoaggregates&rft.jtitle=Inorganic%20chemistry&rft.au=Le%20Natur,%20Franc%CC%A7ois&rft.date=2015-06-15&rft.volume=54&rft.issue=12&rft.spage=6043&rft.epage=6054&rft.pages=6043-6054&rft.issn=0020-1669&rft.eissn=1520-510X&rft_id=info:doi/10.1021/acs.inorgchem.5b00947&rft_dat=%3Cproquest_hal_p%3E1689309989%3C/proquest_hal_p%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1689309989&rft_id=info:pmid/26024151&rfr_iscdi=true |