Synthesis and first applications of a new family of chiral monophosphine ligand: 2,5-diphenylphosphospholanes

The cyclic phosphinic acid 1-hydroxy-1- r-oxo-2 c,5- t-diphenylphospholane was synthesized and resolved into enantiomers through fractional crystallization of the quinine salts. The P-phenyl, P-methyl and P-benzyl tertiary phosphine oxides were obtained from the secondary phosphine oxide, reduction...

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Veröffentlicht in:	Tetrahedron 2002-07, Vol.58 (29), p.5895-5904
Hauptverfasser:	Guillen, Frédéric, Rivard, Michael, Toffano, Martial, Legros, Jean-Yves, Daran, Jean-Claude, Fiaud, Jean-Claude
Format:	Artikel
Sprache:	eng
Schlagworte:	catalysis Chemical Sciences enantioselection Organic chemistry phosphine phosphinic acid
Online-Zugang:	Volltext
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