High temperature sublimation of α-amino acids: a realistic prebiotic process leading to large enantiomeric excess

The reiterative high temperature co-sublimation of an enantiopure or an enantioenriched α-amino acid mixed with racemic α-amino acids leads to deracemization of the latter. A synergistic effect is observed for complex mixtures, and the sense of the handedness is, for all compounds, identical to that...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2015-04, Vol.51 (32), p.7054-7057
Hauptverfasser:	Tarasevych, Arkadii V, Sorochinsky, Alexander E, Kukhar, Valery P, Guillemin, Jean-Claude
Format:	Artikel
Sprache:	eng
Schlagworte:	Amino Acids - chemistry Handedness Life Sciences Phase Transition Stereoisomerism Sublimation Synergistic effect Temperature
Online-Zugang:	Volltext
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