Biopolymer-Supported Ionic-Liquid-Phase Ruthenium Catalysts for Olefin Metathesis
Original ruthenium supported ionic liquid phase (SILP) catalysts based on alginates as supports were developed for olefin metathesis reactions. The marine biopolymer, which fulfills most of the requisite properties for a support such as widespread abundance, insolubility in the majority of organic s...
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| Veröffentlicht in: | ChemSusChem 2014-04, Vol.7 (4), p.1040-1045 |
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| creator | Clousier, Nathalie Filippi, Alexandra Borré, Etienne Guibal, Eric Crévisy, Christophe Caijo, Fréderic Mauduit, Marc Dez, Isabelle Gaumont, Annie-Claude |
| description | Original ruthenium supported ionic liquid phase (SILP) catalysts based on alginates as supports were developed for olefin metathesis reactions. The marine biopolymer, which fulfills most of the requisite properties for a support such as widespread abundance, insolubility in the majority of organic solvents, a high affinity for ionic liquids, high chemical stability, biodegradability, low cost, and easy processing, was impregnated by [bmim][PF6] containing an ionically tagged ruthenium catalyst. These biosourced catalysts show promising performances in ring‐closing metathesis (RCM) and cross‐metathesis (CM) reactions, with a high level of recyclability and reusability combined with a good reactivity.
Powerful, reusable, and recyclable catalytic materials based on supported ionic liquid phase (SILP) technology for ruthenium ring‐closing metathesis (RCM) and cross metathesis (CM) reactions are reported. The materials use alginate, a cheap, renewable and easily conditioned biopolymer, as support. Their excellent recyclability (15 cycles) combined with their high reactivity in either monophasic or biphasic conditions (use of cyclohexane) makes them excellent choices for RCM and CM reactions. |
| doi_str_mv | 10.1002/cssc.201300804 |
| format | Article |
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Powerful, reusable, and recyclable catalytic materials based on supported ionic liquid phase (SILP) technology for ruthenium ring‐closing metathesis (RCM) and cross metathesis (CM) reactions are reported. The materials use alginate, a cheap, renewable and easily conditioned biopolymer, as support. Their excellent recyclability (15 cycles) combined with their high reactivity in either monophasic or biphasic conditions (use of cyclohexane) makes them excellent choices for RCM and CM reactions.</description><identifier>ISSN: 1864-5631</identifier><identifier>EISSN: 1864-564X</identifier><identifier>DOI: 10.1002/cssc.201300804</identifier><identifier>PMID: 24616203</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>biopolymers ; Biopolymers - chemistry ; Catalysis ; Chemical Sciences ; ionic liquids ; Ionic Liquids - chemistry ; Ions ; Malonates - chemistry ; metathesis ; ruthenium ; Ruthenium - chemistry ; Solvents ; supported catalysts</subject><ispartof>ChemSusChem, 2014-04, Vol.7 (4), p.1040-1045</ispartof><rights>2014 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.</rights><rights>2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4824-18c9b5dfb42601e81847dac24077565497cfffa1c07f7f886b50207fe3f5fbdb3</citedby><cites>FETCH-LOGICAL-c4824-18c9b5dfb42601e81847dac24077565497cfffa1c07f7f886b50207fe3f5fbdb3</cites><orcidid>0000-0002-7080-9708 ; 0000-0002-2767-6305</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fcssc.201300804$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fcssc.201300804$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>230,314,776,780,881,1411,27901,27902,45550,45551</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/24616203$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink><backlink>$$Uhttps://univ-rennes.hal.science/hal-01123674$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Clousier, Nathalie</creatorcontrib><creatorcontrib>Filippi, Alexandra</creatorcontrib><creatorcontrib>Borré, Etienne</creatorcontrib><creatorcontrib>Guibal, Eric</creatorcontrib><creatorcontrib>Crévisy, Christophe</creatorcontrib><creatorcontrib>Caijo, Fréderic</creatorcontrib><creatorcontrib>Mauduit, Marc</creatorcontrib><creatorcontrib>Dez, Isabelle</creatorcontrib><creatorcontrib>Gaumont, Annie-Claude</creatorcontrib><title>Biopolymer-Supported Ionic-Liquid-Phase Ruthenium Catalysts for Olefin Metathesis</title><title>ChemSusChem</title><addtitle>ChemSusChem</addtitle><description>Original ruthenium supported ionic liquid phase (SILP) catalysts based on alginates as supports were developed for olefin metathesis reactions. The marine biopolymer, which fulfills most of the requisite properties for a support such as widespread abundance, insolubility in the majority of organic solvents, a high affinity for ionic liquids, high chemical stability, biodegradability, low cost, and easy processing, was impregnated by [bmim][PF6] containing an ionically tagged ruthenium catalyst. These biosourced catalysts show promising performances in ring‐closing metathesis (RCM) and cross‐metathesis (CM) reactions, with a high level of recyclability and reusability combined with a good reactivity.
Powerful, reusable, and recyclable catalytic materials based on supported ionic liquid phase (SILP) technology for ruthenium ring‐closing metathesis (RCM) and cross metathesis (CM) reactions are reported. The materials use alginate, a cheap, renewable and easily conditioned biopolymer, as support. Their excellent recyclability (15 cycles) combined with their high reactivity in either monophasic or biphasic conditions (use of cyclohexane) makes them excellent choices for RCM and CM reactions.</description><subject>biopolymers</subject><subject>Biopolymers - chemistry</subject><subject>Catalysis</subject><subject>Chemical Sciences</subject><subject>ionic liquids</subject><subject>Ionic Liquids - chemistry</subject><subject>Ions</subject><subject>Malonates - chemistry</subject><subject>metathesis</subject><subject>ruthenium</subject><subject>Ruthenium - chemistry</subject><subject>Solvents</subject><subject>supported catalysts</subject><issn>1864-5631</issn><issn>1864-564X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqF0T9v1DAcBmALgWgprIwoEgsMOWzH_zKWCNqiu7ZwRWWzHMfWuSRxaifAfXt8SokQC5Mt6_m9sv0C8BLBFYIQv9Mx6hWGqIBQQPIIHCPBSE4Z-fZ42RfoCDyL8Q5CBkvGnoIjTBhiGBbH4PN75wff7jsT8u00DD6MpskufO90vnb3k2vy652KJvsyjTvTu6nLKjWqdh_HmFkfsqvWWNdnGzOqBKKLz8ETq9poXjysJ-Drxw831Xm-vjq7qE7XuSYCkxwJXda0sTXBDCIjkCC8URoTyDlllJRcW2sV0pBbboVgNYU47U1hqa2bujgBb-fcnWrlEFynwl565eT56VoeziBCuGCc_EDJvpntEPz9ZOIoOxe1aVvVGz9FiWj6QArLskj09T_0zk-hTy85KIyEQEgktZqVDj7GYOxyAwTloRh5KEYuxaSBVw-xU92ZZuF_mkignMFP15r9f-Jktd1Wf4fn86yLo_m1zKrwXTJecCpvL88kvrndbK4_UXlZ_Aa-AqgJ</recordid><startdate>201404</startdate><enddate>201404</enddate><creator>Clousier, Nathalie</creator><creator>Filippi, Alexandra</creator><creator>Borré, Etienne</creator><creator>Guibal, Eric</creator><creator>Crévisy, Christophe</creator><creator>Caijo, Fréderic</creator><creator>Mauduit, Marc</creator><creator>Dez, Isabelle</creator><creator>Gaumont, Annie-Claude</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><general>Wiley Subscription Services, Inc</general><general>ChemPubSoc Europe/Wiley</general><scope>BSCLL</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>K9.</scope><scope>7X8</scope><scope>1XC</scope><scope>VOOES</scope><orcidid>https://orcid.org/0000-0002-7080-9708</orcidid><orcidid>https://orcid.org/0000-0002-2767-6305</orcidid></search><sort><creationdate>201404</creationdate><title>Biopolymer-Supported Ionic-Liquid-Phase Ruthenium Catalysts for Olefin Metathesis</title><author>Clousier, Nathalie ; Filippi, Alexandra ; Borré, Etienne ; Guibal, Eric ; Crévisy, Christophe ; Caijo, Fréderic ; Mauduit, Marc ; Dez, Isabelle ; Gaumont, Annie-Claude</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4824-18c9b5dfb42601e81847dac24077565497cfffa1c07f7f886b50207fe3f5fbdb3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>biopolymers</topic><topic>Biopolymers - chemistry</topic><topic>Catalysis</topic><topic>Chemical Sciences</topic><topic>ionic liquids</topic><topic>Ionic Liquids - chemistry</topic><topic>Ions</topic><topic>Malonates - chemistry</topic><topic>metathesis</topic><topic>ruthenium</topic><topic>Ruthenium - chemistry</topic><topic>Solvents</topic><topic>supported catalysts</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Clousier, Nathalie</creatorcontrib><creatorcontrib>Filippi, Alexandra</creatorcontrib><creatorcontrib>Borré, Etienne</creatorcontrib><creatorcontrib>Guibal, Eric</creatorcontrib><creatorcontrib>Crévisy, Christophe</creatorcontrib><creatorcontrib>Caijo, Fréderic</creatorcontrib><creatorcontrib>Mauduit, Marc</creatorcontrib><creatorcontrib>Dez, Isabelle</creatorcontrib><creatorcontrib>Gaumont, Annie-Claude</creatorcontrib><collection>Istex</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><collection>Hyper Article en Ligne (HAL)</collection><collection>Hyper Article en Ligne (HAL) (Open Access)</collection><jtitle>ChemSusChem</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Clousier, Nathalie</au><au>Filippi, Alexandra</au><au>Borré, Etienne</au><au>Guibal, Eric</au><au>Crévisy, Christophe</au><au>Caijo, Fréderic</au><au>Mauduit, Marc</au><au>Dez, Isabelle</au><au>Gaumont, Annie-Claude</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Biopolymer-Supported Ionic-Liquid-Phase Ruthenium Catalysts for Olefin Metathesis</atitle><jtitle>ChemSusChem</jtitle><addtitle>ChemSusChem</addtitle><date>2014-04</date><risdate>2014</risdate><volume>7</volume><issue>4</issue><spage>1040</spage><epage>1045</epage><pages>1040-1045</pages><issn>1864-5631</issn><eissn>1864-564X</eissn><abstract>Original ruthenium supported ionic liquid phase (SILP) catalysts based on alginates as supports were developed for olefin metathesis reactions. The marine biopolymer, which fulfills most of the requisite properties for a support such as widespread abundance, insolubility in the majority of organic solvents, a high affinity for ionic liquids, high chemical stability, biodegradability, low cost, and easy processing, was impregnated by [bmim][PF6] containing an ionically tagged ruthenium catalyst. These biosourced catalysts show promising performances in ring‐closing metathesis (RCM) and cross‐metathesis (CM) reactions, with a high level of recyclability and reusability combined with a good reactivity.
Powerful, reusable, and recyclable catalytic materials based on supported ionic liquid phase (SILP) technology for ruthenium ring‐closing metathesis (RCM) and cross metathesis (CM) reactions are reported. The materials use alginate, a cheap, renewable and easily conditioned biopolymer, as support. Their excellent recyclability (15 cycles) combined with their high reactivity in either monophasic or biphasic conditions (use of cyclohexane) makes them excellent choices for RCM and CM reactions.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><pmid>24616203</pmid><doi>10.1002/cssc.201300804</doi><tpages>6</tpages><orcidid>https://orcid.org/0000-0002-7080-9708</orcidid><orcidid>https://orcid.org/0000-0002-2767-6305</orcidid><oa>free_for_read</oa></addata></record> |
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| source | MEDLINE; Wiley Online Library Journals Frontfile Complete |
| subjects | biopolymers Biopolymers - chemistry Catalysis Chemical Sciences ionic liquids Ionic Liquids - chemistry Ions Malonates - chemistry metathesis ruthenium Ruthenium - chemistry Solvents supported catalysts |
| title | Biopolymer-Supported Ionic-Liquid-Phase Ruthenium Catalysts for Olefin Metathesis |
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