Smart Detection of Toxic Metal Ions, Pb2+ and Cd2+, Using a 129Xe NMR-Based Sensor
An approach for sensitive magnetic resonance detection of metal cations is proposed. Combining the use of hyperpolarized 129Xe NMR and of a cage-molecule functionalized by a ligand able to chelate different cations, we show that simultaneous detection of lead, zinc, and cadmium ions at nanomolar con...
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| Veröffentlicht in: | Analytical and bioanalytical chemistry 2014-02, Vol.86 (3), p.1783-1788 |
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| container_end_page | 1788 |
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| container_issue | 3 |
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| container_title | Analytical and bioanalytical chemistry |
| container_volume | 86 |
| creator | Tassali, Nawal Kotera, Naoko Boutin, Céline Léonce, Estelle Boulard, Yves Rousseau, Bernard Dubost, Emmanuelle Taran, Frédéric Brotin, Thierry Dutasta, Jean-Pierre Berthault, Patrick |
| description | An approach for sensitive magnetic resonance detection of metal cations is proposed. Combining the use of hyperpolarized 129Xe NMR and of a cage-molecule functionalized by a ligand able to chelate different cations, we show that simultaneous detection of lead, zinc, and cadmium ions at nanomolar concentration is possible in short time, thanks to fast MRI sequences based on the HyperCEST scheme. |
| doi_str_mv | 10.1021/ac403669p |
| format | Article |
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Combining the use of hyperpolarized 129Xe NMR and of a cage-molecule functionalized by a ligand able to chelate different cations, we show that simultaneous detection of lead, zinc, and cadmium ions at nanomolar concentration is possible in short time, thanks to fast MRI sequences based on the HyperCEST scheme.</description><subject>Cadmium - analysis</subject><subject>Cadmium - chemistry</subject><subject>Chemical Sciences</subject><subject>Chemistry Techniques, Analytical - instrumentation</subject><subject>Environmental Pollutants - analysis</subject><subject>Environmental Pollutants - chemistry</subject><subject>Lead - analysis</subject><subject>Lead - chemistry</subject><subject>Magnetic Resonance Spectroscopy</subject><subject>or physical chemistry</subject><subject>Theoretical and</subject><issn>0003-2700</issn><issn>1618-2642</issn><issn>1520-6882</issn><issn>1618-2650</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNo9kE1Lw0AQQBdRbK0e_AOyFw_SRmd2N5vkWOtHC61KP8DbssluNKVNSjYV_fduqfY0MDyGeY-QS4RbBIZ3OhPApUw2R6SNIYNAxjE7Jm0A4AGLAFrkzLklACKgPCUtJgRncYRtMp2tdd3QB9vYrCmqklY5nVffRUYnttErOqpK16NvKetSXRo6MKzbowtXlB9UU2TJu6Uvk2lwr501dGZLV9Xn5CTXK2cv_maHLJ4e54NhMH59Hg3640BjLDFAweM0FgYMZwyFDlnIBQ_DhGvIdJJACgyQI_OUNJBZw_NUopCJiXL0wh1ys7_7qVdqUxde5EdVulDD_ljtdl4XIyHwCz17tWc323RtzQH_D-GB6z2gM6eW1bYu_esKQe0Cq0Ng_gsKgmPy</recordid><startdate>20140204</startdate><enddate>20140204</enddate><creator>Tassali, Nawal</creator><creator>Kotera, Naoko</creator><creator>Boutin, Céline</creator><creator>Léonce, Estelle</creator><creator>Boulard, Yves</creator><creator>Rousseau, Bernard</creator><creator>Dubost, Emmanuelle</creator><creator>Taran, Frédéric</creator><creator>Brotin, Thierry</creator><creator>Dutasta, Jean-Pierre</creator><creator>Berthault, Patrick</creator><general>American Chemical Society</general><general>Springer Verlag</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>1XC</scope><orcidid>https://orcid.org/0000-0002-0882-8297</orcidid><orcidid>https://orcid.org/0000-0001-5461-329X</orcidid><orcidid>https://orcid.org/0000-0003-0948-6097</orcidid><orcidid>https://orcid.org/0000-0001-9746-4706</orcidid><orcidid>https://orcid.org/0000-0003-4008-2912</orcidid></search><sort><creationdate>20140204</creationdate><title>Smart Detection of Toxic Metal Ions, Pb2+ and Cd2+, Using a 129Xe NMR-Based Sensor</title><author>Tassali, Nawal ; Kotera, Naoko ; Boutin, Céline ; Léonce, Estelle ; Boulard, Yves ; Rousseau, Bernard ; Dubost, Emmanuelle ; Taran, Frédéric ; Brotin, Thierry ; Dutasta, Jean-Pierre ; Berthault, Patrick</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a1861-1438b84d0d32214a5253435593a0ca990b02013128b86d0ced3fb61469d7f1403</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Cadmium - analysis</topic><topic>Cadmium - chemistry</topic><topic>Chemical Sciences</topic><topic>Chemistry Techniques, Analytical - instrumentation</topic><topic>Environmental Pollutants - analysis</topic><topic>Environmental Pollutants - chemistry</topic><topic>Lead - analysis</topic><topic>Lead - chemistry</topic><topic>Magnetic Resonance Spectroscopy</topic><topic>or physical chemistry</topic><topic>Theoretical and</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Tassali, Nawal</creatorcontrib><creatorcontrib>Kotera, Naoko</creatorcontrib><creatorcontrib>Boutin, Céline</creatorcontrib><creatorcontrib>Léonce, Estelle</creatorcontrib><creatorcontrib>Boulard, Yves</creatorcontrib><creatorcontrib>Rousseau, Bernard</creatorcontrib><creatorcontrib>Dubost, Emmanuelle</creatorcontrib><creatorcontrib>Taran, Frédéric</creatorcontrib><creatorcontrib>Brotin, Thierry</creatorcontrib><creatorcontrib>Dutasta, Jean-Pierre</creatorcontrib><creatorcontrib>Berthault, Patrick</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>Analytical and bioanalytical chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Tassali, Nawal</au><au>Kotera, Naoko</au><au>Boutin, Céline</au><au>Léonce, Estelle</au><au>Boulard, Yves</au><au>Rousseau, Bernard</au><au>Dubost, Emmanuelle</au><au>Taran, Frédéric</au><au>Brotin, Thierry</au><au>Dutasta, Jean-Pierre</au><au>Berthault, Patrick</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Smart Detection of Toxic Metal Ions, Pb2+ and Cd2+, Using a 129Xe NMR-Based Sensor</atitle><jtitle>Analytical and bioanalytical chemistry</jtitle><addtitle>Anal. 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| source | MEDLINE; ACS Publications; SpringerLink Journals - AutoHoldings |
| subjects | Cadmium - analysis Cadmium - chemistry Chemical Sciences Chemistry Techniques, Analytical - instrumentation Environmental Pollutants - analysis Environmental Pollutants - chemistry Lead - analysis Lead - chemistry Magnetic Resonance Spectroscopy or physical chemistry Theoretical and |
| title | Smart Detection of Toxic Metal Ions, Pb2+ and Cd2+, Using a 129Xe NMR-Based Sensor |
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