Electrical, optical and morphological properties of a new chromogenic calix[4]arene derivative

•We have studied the electrical and optical properties of a new chromogenic calix[4]arene derivative.•We have investigated the effect of solvent used for the film fabrication on the optical properties.•The impedance spectra have been discussed in terms of an equivalent circuit model designed as a pa...

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Veröffentlicht in:Synthetic metals 2014-11, Vol.197, p.112-118
Hauptverfasser: Ebdelli, R., Ben Dkhil, S., Azib, T., Ben Chaabane, R., Dumazet-Bonnamour, I., Ben Ouada, H., Davenas, J.
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container_end_page 118
container_issue
container_start_page 112
container_title Synthetic metals
container_volume 197
creator Ebdelli, R.
Ben Dkhil, S.
Azib, T.
Ben Chaabane, R.
Dumazet-Bonnamour, I.
Ben Ouada, H.
Davenas, J.
description •We have studied the electrical and optical properties of a new chromogenic calix[4]arene derivative.•We have investigated the effect of solvent used for the film fabrication on the optical properties.•The impedance spectra have been discussed in terms of an equivalent circuit model designed as a parallel resistor Rp and capacitor Cp network in series with resistor Rs. We have studied electrical properties of ITO/azo-calix[4]arene/Al diodes by means of current–voltage measurement and impedance spectroscopy in a wide frequency range. The devices with an ITO/azo-calix[4]arene/Al structure could be modeled as a simple combination of resistors and capacitors. The impedance spectra can be discussed in terms of an equivalent circuit model designed as a parallel resistor Rp and capacitor Cp network in series with resistor Rs. We extract numerical values of these parameters by fitting experimental data. Relaxation processes have been identified too from the impedance spectroscopy. Their values deduced from fitting experimental data to the model have given a dielectric relaxation time in the ms range and an exponential trap distribution.
doi_str_mv 10.1016/j.synthmet.2014.09.007
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We have studied electrical properties of ITO/azo-calix[4]arene/Al diodes by means of current–voltage measurement and impedance spectroscopy in a wide frequency range. The devices with an ITO/azo-calix[4]arene/Al structure could be modeled as a simple combination of resistors and capacitors. The impedance spectra can be discussed in terms of an equivalent circuit model designed as a parallel resistor Rp and capacitor Cp network in series with resistor Rs. We extract numerical values of these parameters by fitting experimental data. Relaxation processes have been identified too from the impedance spectroscopy. 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source Elsevier ScienceDirect Journals
subjects Aluminum
Applied sciences
Capacitors
Chemical Sciences
Chromogenic calixarene
Derivatives
Devices
Diodes
Electrical properties
Electronics
Exact sciences and technology
Fittings
Impedance spectroscopy
Material chemistry
Mathematical models
Morphological properties
Optical properties
Polymers
Resistors
Semiconductor electronics. Microelectronics. Optoelectronics. Solid state devices
Thin films
title Electrical, optical and morphological properties of a new chromogenic calix[4]arene derivative
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