Effect of thermal annealing on electrical and optical properties of Ba-doped SrCu2O2 thin films on glass substrates
Ba‐doped SrCu2O2 (SCO) thin films were synthesized by annealing Ba‐doped SrCuO films deposited on glass substrates by metalorganic chemical vapour deposition (MOCVD) and composed of SrCO3 and CuO. In order to reduce cracks formed during conventional thermal annealing and therefore, to enhance opti...
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Veröffentlicht in: | Physica status solidi. A, Applications and materials science Applications and materials science, 2013-12, Vol.210 (12), p.2569-2574 |
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creator | Khan, Afzal Jiménez, Carmen Chaix-Pluchery, Odette Roussel, Hervé Deschanvres, Jean-Luc |
description | Ba‐doped SrCu2O2 (SCO) thin films were synthesized by annealing Ba‐doped SrCuO films deposited on glass substrates by metalorganic chemical vapour deposition (MOCVD) and composed of SrCO3 and CuO. In order to reduce cracks formed during conventional thermal annealing and therefore, to enhance optical and electrical properties of the films, annealing conditions were optimized in terms of heating rate, cooling rate and annealing time. The SCO phase was obtained after annealing at 650 °C for 5 min leading to a complete decomposition of the initial phases via an intermediate SrCuO2 phase. Optical characterizations of the SCO films indicate a transmittance of 75% in the visible range at 550 nm and a direct bandgap of 3.25 eV; their electrical conductivity was measured to be 4.3 × 10−2 S cm−1. |
doi_str_mv | 10.1002/pssa.201330011 |
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In order to reduce cracks formed during conventional thermal annealing and therefore, to enhance optical and electrical properties of the films, annealing conditions were optimized in terms of heating rate, cooling rate and annealing time. The SCO phase was obtained after annealing at 650 °C for 5 min leading to a complete decomposition of the initial phases via an intermediate SrCuO2 phase. Optical characterizations of the SCO films indicate a transmittance of 75% in the visible range at 550 nm and a direct bandgap of 3.25 eV; their electrical conductivity was measured to be 4.3 × 10−2 S cm−1.</description><identifier>ISSN: 1862-6300</identifier><identifier>EISSN: 1862-6319</identifier><identifier>DOI: 10.1002/pssa.201330011</identifier><language>eng</language><publisher>Weinheim: Blackwell Publishing Ltd</publisher><subject>Ba-doped SCO ; Chemical Sciences ; Material chemistry ; metalorganic chemical vapour deposition ; optical and electronical properties ; thin films ; transparent conductive oxides</subject><ispartof>Physica status solidi. A, Applications and materials science, 2013-12, Vol.210 (12), p.2569-2574</ispartof><rights>2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><orcidid>0000-0003-4668-8501 ; 0000-0001-9699-7084 ; 0000-0002-9601-1825 ; 0000-0001-6110-5760</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fpssa.201330011$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fpssa.201330011$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>230,314,776,780,881,1411,27901,27902,45550,45551</link.rule.ids><backlink>$$Uhttps://hal.science/hal-01067071$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Khan, Afzal</creatorcontrib><creatorcontrib>Jiménez, Carmen</creatorcontrib><creatorcontrib>Chaix-Pluchery, Odette</creatorcontrib><creatorcontrib>Roussel, Hervé</creatorcontrib><creatorcontrib>Deschanvres, Jean-Luc</creatorcontrib><title>Effect of thermal annealing on electrical and optical properties of Ba-doped SrCu2O2 thin films on glass substrates</title><title>Physica status solidi. A, Applications and materials science</title><addtitle>Phys. Status Solidi A</addtitle><description>Ba‐doped SrCu2O2 (SCO) thin films were synthesized by annealing Ba‐doped SrCuO films deposited on glass substrates by metalorganic chemical vapour deposition (MOCVD) and composed of SrCO3 and CuO. In order to reduce cracks formed during conventional thermal annealing and therefore, to enhance optical and electrical properties of the films, annealing conditions were optimized in terms of heating rate, cooling rate and annealing time. The SCO phase was obtained after annealing at 650 °C for 5 min leading to a complete decomposition of the initial phases via an intermediate SrCuO2 phase. Optical characterizations of the SCO films indicate a transmittance of 75% in the visible range at 550 nm and a direct bandgap of 3.25 eV; their electrical conductivity was measured to be 4.3 × 10−2 S cm−1.</description><subject>Ba-doped SCO</subject><subject>Chemical Sciences</subject><subject>Material chemistry</subject><subject>metalorganic chemical vapour deposition</subject><subject>optical and electronical properties</subject><subject>thin films</subject><subject>transparent conductive oxides</subject><issn>1862-6300</issn><issn>1862-6319</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNo9UctOwzAQjBBIlMKVsyVOHAK7dmPXx1Joi1TxUEEcLTdxWkOaBDvl8fc4Lcppd2dnRruaKDpHuEIAel17r68oIGMAiAdRD4ecxpyhPOx6gOPoxPt3gEEyENiL_F2em7QhVU6atXEbXRBdlkYXtlyRqiSmCFtn0x2ekapudn3tqtq4xhrfKm90nIU5Iws33tJHGqxsSXJbbHzrsSq098Rvl75xujH-NDrKdeHN2X_tR6-Tu5fxLJ4_Tu_Ho3m8ZpBgzKVOWaalgSEDqpmhcgk0lVwKNhSIMsdUGiapYYnUJlmG1RAoZMt0kKaZYP3ocu-71oWqnd1o96sqbdVsNFctBghcgMAvDNyLPTd89rk1vlHv1daV4TyFA84ZT2gCgSX3rG9bmN_OE0G1Cag2AdUloJ4Wi1E3BW2811rfmJ9Oq92H4oKJRL09TNXbZCwWt88T9cz-ABuIiv0</recordid><startdate>201312</startdate><enddate>201312</enddate><creator>Khan, Afzal</creator><creator>Jiménez, Carmen</creator><creator>Chaix-Pluchery, Odette</creator><creator>Roussel, Hervé</creator><creator>Deschanvres, Jean-Luc</creator><general>Blackwell Publishing Ltd</general><general>Wiley Subscription Services, Inc</general><general>Wiley</general><scope>BSCLL</scope><scope>7SP</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>1XC</scope><orcidid>https://orcid.org/0000-0003-4668-8501</orcidid><orcidid>https://orcid.org/0000-0001-9699-7084</orcidid><orcidid>https://orcid.org/0000-0002-9601-1825</orcidid><orcidid>https://orcid.org/0000-0001-6110-5760</orcidid></search><sort><creationdate>201312</creationdate><title>Effect of thermal annealing on electrical and optical properties of Ba-doped SrCu2O2 thin films on glass substrates</title><author>Khan, Afzal ; Jiménez, Carmen ; Chaix-Pluchery, Odette ; Roussel, Hervé ; Deschanvres, Jean-Luc</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-h3051-69ac3da9e08302a3e29b02c9697387119f1c9e392e359ae5bc968020dbc4ccd73</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Ba-doped SCO</topic><topic>Chemical Sciences</topic><topic>Material chemistry</topic><topic>metalorganic chemical vapour deposition</topic><topic>optical and electronical properties</topic><topic>thin films</topic><topic>transparent conductive oxides</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Khan, Afzal</creatorcontrib><creatorcontrib>Jiménez, Carmen</creatorcontrib><creatorcontrib>Chaix-Pluchery, Odette</creatorcontrib><creatorcontrib>Roussel, Hervé</creatorcontrib><creatorcontrib>Deschanvres, Jean-Luc</creatorcontrib><collection>Istex</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>Physica status solidi. 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Optical characterizations of the SCO films indicate a transmittance of 75% in the visible range at 550 nm and a direct bandgap of 3.25 eV; their electrical conductivity was measured to be 4.3 × 10−2 S cm−1.</abstract><cop>Weinheim</cop><pub>Blackwell Publishing Ltd</pub><doi>10.1002/pssa.201330011</doi><tpages>6</tpages><orcidid>https://orcid.org/0000-0003-4668-8501</orcidid><orcidid>https://orcid.org/0000-0001-9699-7084</orcidid><orcidid>https://orcid.org/0000-0002-9601-1825</orcidid><orcidid>https://orcid.org/0000-0001-6110-5760</orcidid></addata></record> |
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source | Wiley Online Library Journals Frontfile Complete |
subjects | Ba-doped SCO Chemical Sciences Material chemistry metalorganic chemical vapour deposition optical and electronical properties thin films transparent conductive oxides |
title | Effect of thermal annealing on electrical and optical properties of Ba-doped SrCu2O2 thin films on glass substrates |
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