New Method for Double-Resonance Spectroscopy in a Cold Quadrupole Ion Trap and Its Application to UV–UV Hole-Burning Spectroscopy of Protonated Adenine Dimer

New Method for Double-Resonance Spectroscopy in a Cold Quadrupole Ion Trap and Its Application to UV–UV Hole-Burning Spectroscopy of Protonated Adenine Dimer

A novel method for double-resonance spectroscopy in a cold quadrupole ion trap is presented, which utilizes dipolar resonant excitation of fragment ions in the quadrupole ion trap. Photofragments by a burn laser are removed by applying an auxiliary RF to the trap, and a probe laser detects the deple...

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Veröffentlicht in:The journal of physical chemistry letters 2014-08, Vol.5 (15), p.2760-2764
Hauptverfasser: Kang, Hyuk, Féraud, Géraldine, Dedonder-Lardeux, Claude, Jouvet, Christophe
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Sprache:eng
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Atomic and Molecular Clusters
Physics
Spectroscopy, Photochemistry, and Excited States
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container_issue 15
container_start_page 2760
container_title The journal of physical chemistry letters
container_volume 5
creator Kang, Hyuk
Féraud, Géraldine
Dedonder-Lardeux, Claude
Jouvet, Christophe
description A novel method for double-resonance spectroscopy in a cold quadrupole ion trap is presented, which utilizes dipolar resonant excitation of fragment ions in the quadrupole ion trap. Photofragments by a burn laser are removed by applying an auxiliary RF to the trap, and a probe laser detects the depletion of photofragments by the burn laser. By scanning the wavelength of the burn laser, conformation-specific UV spectrum of a cold ion is obtained. This simple and powerful method is applicable to any type of double-resonance spectroscopy in a cold quadrupole ion trap and was applied to UV–UV hole-burning spectroscopy of protonated adenine dimer. It was found that protonated adenine dimer has multiple conformers/tautomers, each with multiple excited states with drastically different excited state dynamics.
doi_str_mv 10.1021/jz5012466
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subjects Atomic and Molecular Clusters
Physics
Spectroscopy, Photochemistry, and Excited States
title New Method for Double-Resonance Spectroscopy in a Cold Quadrupole Ion Trap and Its Application to UV–UV Hole-Burning Spectroscopy of Protonated Adenine Dimer
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