Switching off the single-molecule magnet properties of the [Co II (Me 6 tren)(OH 2 )] 2+ module by complexation with trans -[Ru III (salen)(CN) 2 ]
The trinuclear complex [{Co II (Me 6 tren)} 2 (μ-NC) 2 Ru III (salen)](NO 3 ) 3 ·3CH 3 CN·H 2 O ( 2 ) (salen = N , N ′-ethylenebis(salicylideneiminato); Me 6 tren = tris((dimethylamino)ethyl)amine) was synthesized by the reaction of trans -(PPh 4 )[Ru III (salen)(CN) 2 ] and two equivalents of [Co I...
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| Veröffentlicht in: | New journal of chemistry 2014, Vol.38 (8), p.3443-3448 |
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| container_issue | 8 |
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| container_title | New journal of chemistry |
| container_volume | 38 |
| creator | Piñero Cruz, Dalice M. Woodruff, Daniel N. Jeon, Ie-Rang Bhowmick, Indrani Secu, Mihail Hillard, Elizabeth A. Dechambenoit, Pierre Clérac, Rodolphe |
| description | The trinuclear complex [{Co
II
(Me
6
tren)}
2
(μ-NC)
2
Ru
III
(salen)](NO
3
)
3
·3CH
3
CN·H
2
O (
2
) (salen =
N
,
N
′-ethylenebis(salicylideneiminato); Me
6
tren = tris((dimethylamino)ethyl)amine) was synthesized by the reaction of
trans
-(PPh
4
)[Ru
III
(salen)(CN)
2
] and two equivalents of [Co
II
(Me
6
tren)(OH
2
)](NO
3
)
2
(
1
). Magnetic susceptibility measurements of
1
reveal its single-molecule magnet behaviour whilst
2
shows no appreciable slow dynamics of the magnetization even under an applied dc field. A comparison of the electrochemical properties of complex
2
with the
trans
-(PPh
4
)[Ru
III
(salen)(CN)
2
] precursor reveals anodic shifts of the reduction and oxidation waves. The absorption spectrum of
2
obtained from surface optical reflectivity methods is also reported and discussed. |
| doi_str_mv | 10.1039/C4NJ00452C |
| format | Article |
| fullrecord | <record><control><sourceid>hal_cross</sourceid><recordid>TN_cdi_hal_primary_oai_HAL_hal_01060695v1</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>oai_HAL_hal_01060695v1</sourcerecordid><originalsourceid>FETCH-LOGICAL-c146c-f22aa1e5fa43bcddae066c5261eec871986c8b052ed85cbf03570129bc6f7f013</originalsourceid><addsrcrecordid>eNpFkF1PgzAUhhujiXN64y_o5dCgbYECl4aom5lb4sfVspBSTgcGKKFM3e_wD1uc0avzked9T86L0DklV5R48XXiLx4I8QOWHKAR9XjsxozTQ9tT33dJ4PNjdGLMGyGUhpyO0NfzR9nLomw2WCuF-wKwsUMFbq0rkNsKcC02DfS47XQLXV-CseQPuEo0ns3w5BEwx30HjTNZTjHDzhqzS1zrfFBnOyx13VbwKfpSN9ieKywsGoPd1dPWGlgHI6pBnSwcK1-foiMlKgNnv3WMXu9uX5KpO1_ez5KbuSupz6WrGBOCQqCE72UyzwUQzmVg_wWQUUjjiMsoIwGDPApkpogXhISyOJNchYpQb4ycvW8hqrTtylp0u1SLMp3ezNNhRyjhhMfB-8Be7FnZaWM6UH8CStIh-vQ_eu8b1cdy_g</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Switching off the single-molecule magnet properties of the [Co II (Me 6 tren)(OH 2 )] 2+ module by complexation with trans -[Ru III (salen)(CN) 2 ]</title><source>Royal Society Of Chemistry Journals 2008-</source><source>Alma/SFX Local Collection</source><creator>Piñero Cruz, Dalice M. ; Woodruff, Daniel N. ; Jeon, Ie-Rang ; Bhowmick, Indrani ; Secu, Mihail ; Hillard, Elizabeth A. ; Dechambenoit, Pierre ; Clérac, Rodolphe</creator><creatorcontrib>Piñero Cruz, Dalice M. ; Woodruff, Daniel N. ; Jeon, Ie-Rang ; Bhowmick, Indrani ; Secu, Mihail ; Hillard, Elizabeth A. ; Dechambenoit, Pierre ; Clérac, Rodolphe</creatorcontrib><description>The trinuclear complex [{Co
II
(Me
6
tren)}
2
(μ-NC)
2
Ru
III
(salen)](NO
3
)
3
·3CH
3
CN·H
2
O (
2
) (salen =
N
,
N
′-ethylenebis(salicylideneiminato); Me
6
tren = tris((dimethylamino)ethyl)amine) was synthesized by the reaction of
trans
-(PPh
4
)[Ru
III
(salen)(CN)
2
] and two equivalents of [Co
II
(Me
6
tren)(OH
2
)](NO
3
)
2
(
1
). Magnetic susceptibility measurements of
1
reveal its single-molecule magnet behaviour whilst
2
shows no appreciable slow dynamics of the magnetization even under an applied dc field. A comparison of the electrochemical properties of complex
2
with the
trans
-(PPh
4
)[Ru
III
(salen)(CN)
2
] precursor reveals anodic shifts of the reduction and oxidation waves. The absorption spectrum of
2
obtained from surface optical reflectivity methods is also reported and discussed.</description><identifier>ISSN: 1144-0546</identifier><identifier>EISSN: 1369-9261</identifier><identifier>DOI: 10.1039/C4NJ00452C</identifier><language>eng</language><publisher>Royal Society of Chemistry [1987-....]</publisher><subject>Chemical Sciences ; Material chemistry</subject><ispartof>New journal of chemistry, 2014, Vol.38 (8), p.3443-3448</ispartof><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c146c-f22aa1e5fa43bcddae066c5261eec871986c8b052ed85cbf03570129bc6f7f013</citedby><cites>FETCH-LOGICAL-c146c-f22aa1e5fa43bcddae066c5261eec871986c8b052ed85cbf03570129bc6f7f013</cites><orcidid>0000-0001-5509-169X ; 0000-0001-5429-7418 ; 0000-0002-5149-0324</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,314,776,780,881,4009,27902,27903,27904</link.rule.ids><backlink>$$Uhttps://hal.science/hal-01060695$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Piñero Cruz, Dalice M.</creatorcontrib><creatorcontrib>Woodruff, Daniel N.</creatorcontrib><creatorcontrib>Jeon, Ie-Rang</creatorcontrib><creatorcontrib>Bhowmick, Indrani</creatorcontrib><creatorcontrib>Secu, Mihail</creatorcontrib><creatorcontrib>Hillard, Elizabeth A.</creatorcontrib><creatorcontrib>Dechambenoit, Pierre</creatorcontrib><creatorcontrib>Clérac, Rodolphe</creatorcontrib><title>Switching off the single-molecule magnet properties of the [Co II (Me 6 tren)(OH 2 )] 2+ module by complexation with trans -[Ru III (salen)(CN) 2 ]</title><title>New journal of chemistry</title><description>The trinuclear complex [{Co
II
(Me
6
tren)}
2
(μ-NC)
2
Ru
III
(salen)](NO
3
)
3
·3CH
3
CN·H
2
O (
2
) (salen =
N
,
N
′-ethylenebis(salicylideneiminato); Me
6
tren = tris((dimethylamino)ethyl)amine) was synthesized by the reaction of
trans
-(PPh
4
)[Ru
III
(salen)(CN)
2
] and two equivalents of [Co
II
(Me
6
tren)(OH
2
)](NO
3
)
2
(
1
). Magnetic susceptibility measurements of
1
reveal its single-molecule magnet behaviour whilst
2
shows no appreciable slow dynamics of the magnetization even under an applied dc field. A comparison of the electrochemical properties of complex
2
with the
trans
-(PPh
4
)[Ru
III
(salen)(CN)
2
] precursor reveals anodic shifts of the reduction and oxidation waves. The absorption spectrum of
2
obtained from surface optical reflectivity methods is also reported and discussed.</description><subject>Chemical Sciences</subject><subject>Material chemistry</subject><issn>1144-0546</issn><issn>1369-9261</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNpFkF1PgzAUhhujiXN64y_o5dCgbYECl4aom5lb4sfVspBSTgcGKKFM3e_wD1uc0avzked9T86L0DklV5R48XXiLx4I8QOWHKAR9XjsxozTQ9tT33dJ4PNjdGLMGyGUhpyO0NfzR9nLomw2WCuF-wKwsUMFbq0rkNsKcC02DfS47XQLXV-CseQPuEo0ns3w5BEwx30HjTNZTjHDzhqzS1zrfFBnOyx13VbwKfpSN9ieKywsGoPd1dPWGlgHI6pBnSwcK1-foiMlKgNnv3WMXu9uX5KpO1_ez5KbuSupz6WrGBOCQqCE72UyzwUQzmVg_wWQUUjjiMsoIwGDPApkpogXhISyOJNchYpQb4ycvW8hqrTtylp0u1SLMp3ezNNhRyjhhMfB-8Be7FnZaWM6UH8CStIh-vQ_eu8b1cdy_g</recordid><startdate>2014</startdate><enddate>2014</enddate><creator>Piñero Cruz, Dalice M.</creator><creator>Woodruff, Daniel N.</creator><creator>Jeon, Ie-Rang</creator><creator>Bhowmick, Indrani</creator><creator>Secu, Mihail</creator><creator>Hillard, Elizabeth A.</creator><creator>Dechambenoit, Pierre</creator><creator>Clérac, Rodolphe</creator><general>Royal Society of Chemistry [1987-....]</general><scope>AAYXX</scope><scope>CITATION</scope><scope>1XC</scope><orcidid>https://orcid.org/0000-0001-5509-169X</orcidid><orcidid>https://orcid.org/0000-0001-5429-7418</orcidid><orcidid>https://orcid.org/0000-0002-5149-0324</orcidid></search><sort><creationdate>2014</creationdate><title>Switching off the single-molecule magnet properties of the [Co II (Me 6 tren)(OH 2 )] 2+ module by complexation with trans -[Ru III (salen)(CN) 2 ]</title><author>Piñero Cruz, Dalice M. ; Woodruff, Daniel N. ; Jeon, Ie-Rang ; Bhowmick, Indrani ; Secu, Mihail ; Hillard, Elizabeth A. ; Dechambenoit, Pierre ; Clérac, Rodolphe</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c146c-f22aa1e5fa43bcddae066c5261eec871986c8b052ed85cbf03570129bc6f7f013</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Chemical Sciences</topic><topic>Material chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Piñero Cruz, Dalice M.</creatorcontrib><creatorcontrib>Woodruff, Daniel N.</creatorcontrib><creatorcontrib>Jeon, Ie-Rang</creatorcontrib><creatorcontrib>Bhowmick, Indrani</creatorcontrib><creatorcontrib>Secu, Mihail</creatorcontrib><creatorcontrib>Hillard, Elizabeth A.</creatorcontrib><creatorcontrib>Dechambenoit, Pierre</creatorcontrib><creatorcontrib>Clérac, Rodolphe</creatorcontrib><collection>CrossRef</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>New journal of chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Piñero Cruz, Dalice M.</au><au>Woodruff, Daniel N.</au><au>Jeon, Ie-Rang</au><au>Bhowmick, Indrani</au><au>Secu, Mihail</au><au>Hillard, Elizabeth A.</au><au>Dechambenoit, Pierre</au><au>Clérac, Rodolphe</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Switching off the single-molecule magnet properties of the [Co II (Me 6 tren)(OH 2 )] 2+ module by complexation with trans -[Ru III (salen)(CN) 2 ]</atitle><jtitle>New journal of chemistry</jtitle><date>2014</date><risdate>2014</risdate><volume>38</volume><issue>8</issue><spage>3443</spage><epage>3448</epage><pages>3443-3448</pages><issn>1144-0546</issn><eissn>1369-9261</eissn><abstract>The trinuclear complex [{Co
II
(Me
6
tren)}
2
(μ-NC)
2
Ru
III
(salen)](NO
3
)
3
·3CH
3
CN·H
2
O (
2
) (salen =
N
,
N
′-ethylenebis(salicylideneiminato); Me
6
tren = tris((dimethylamino)ethyl)amine) was synthesized by the reaction of
trans
-(PPh
4
)[Ru
III
(salen)(CN)
2
] and two equivalents of [Co
II
(Me
6
tren)(OH
2
)](NO
3
)
2
(
1
). Magnetic susceptibility measurements of
1
reveal its single-molecule magnet behaviour whilst
2
shows no appreciable slow dynamics of the magnetization even under an applied dc field. A comparison of the electrochemical properties of complex
2
with the
trans
-(PPh
4
)[Ru
III
(salen)(CN)
2
] precursor reveals anodic shifts of the reduction and oxidation waves. The absorption spectrum of
2
obtained from surface optical reflectivity methods is also reported and discussed.</abstract><pub>Royal Society of Chemistry [1987-....]</pub><doi>10.1039/C4NJ00452C</doi><tpages>6</tpages><orcidid>https://orcid.org/0000-0001-5509-169X</orcidid><orcidid>https://orcid.org/0000-0001-5429-7418</orcidid><orcidid>https://orcid.org/0000-0002-5149-0324</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1144-0546 |
| ispartof | New journal of chemistry, 2014, Vol.38 (8), p.3443-3448 |
| issn | 1144-0546 1369-9261 |
| language | eng |
| recordid | cdi_hal_primary_oai_HAL_hal_01060695v1 |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Chemical Sciences Material chemistry |
| title | Switching off the single-molecule magnet properties of the [Co II (Me 6 tren)(OH 2 )] 2+ module by complexation with trans -[Ru III (salen)(CN) 2 ] |
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