Qualitative and quantitative assessment of water sorption in natural fibres using ATR-FTIR spectroscopy
•Effect of moisture sorption on plant fibres was investigated by FTIR spectroscopy.•Hydroxyl and carboxyl moieties are specific sites for water sorption.•Partial least squares regression quantified the water content of natural fibres.•Models fitted the sorption isotherms and diffusion kinetics. In t...
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| Veröffentlicht in: | Carbohydrate polymers 2014-01, Vol.101, p.163-170 |
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| creator | Célino, Amandine Gonçalves, Olivier Jacquemin, Frédéric Fréour, Sylvain |
| description | •Effect of moisture sorption on plant fibres was investigated by FTIR spectroscopy.•Hydroxyl and carboxyl moieties are specific sites for water sorption.•Partial least squares regression quantified the water content of natural fibres.•Models fitted the sorption isotherms and diffusion kinetics.
In the field of composite materials, natural fibres appear to be a viable replacement for glass fibres. However, in humid conditions, strong hydrophilic behaviour of such materials can lead to their structural modification. Then, understanding moisture sorption mechanisms in these materials is an important issue for their efficient use. In this work, the water sorption on three natural fibres (flax, hemp and sisal) was studied using Fourier transformed infrared spectroscopy. The spectral information allowed both qualitative and quantitative analyses of the moisture absorption mechanisms. The main chemical functions involved in the water sorption phenomenon were identified. The absolute water content of the fibres was also determined by using a partial least square regression (PLS-R) approach. Moreover, typical sorption isotherm curves described by Park model were fitted as well as water diffusion kinetics. These last applications confirmed the validity of the FTIR spectra based predictive models. |
| doi_str_mv | 10.1016/j.carbpol.2013.09.023 |
| format | Article |
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In the field of composite materials, natural fibres appear to be a viable replacement for glass fibres. However, in humid conditions, strong hydrophilic behaviour of such materials can lead to their structural modification. Then, understanding moisture sorption mechanisms in these materials is an important issue for their efficient use. In this work, the water sorption on three natural fibres (flax, hemp and sisal) was studied using Fourier transformed infrared spectroscopy. The spectral information allowed both qualitative and quantitative analyses of the moisture absorption mechanisms. The main chemical functions involved in the water sorption phenomenon were identified. The absolute water content of the fibres was also determined by using a partial least square regression (PLS-R) approach. Moreover, typical sorption isotherm curves described by Park model were fitted as well as water diffusion kinetics. These last applications confirmed the validity of the FTIR spectra based predictive models.</description><identifier>ISSN: 0144-8617</identifier><identifier>EISSN: 1879-1344</identifier><identifier>DOI: 10.1016/j.carbpol.2013.09.023</identifier><identifier>PMID: 24299761</identifier><identifier>CODEN: CAPOD8</identifier><language>eng</language><publisher>Kidlington: Elsevier Ltd</publisher><subject>Absorption ; Analytical chemistry ; Applied sciences ; Biological Products - chemistry ; Chemical and Process Engineering ; Chemical Sciences ; Compounding ingredients ; Diffusion ; Diffusion kinetics ; Engineering Sciences ; Exact sciences and technology ; Fibers and threads ; Fillers and reinforcing agents ; Forms of application and semi-finished materials ; Fourier transformed infrared spectroscopy ; Kinetics ; Least-Squares Analysis ; Materials ; Mechanics ; Natural fibres ; Partial least square regression ; Plants - chemistry ; Polymer industry, paints, wood ; Spectroscopy, Fourier Transform Infrared ; Technology of polymers ; Water - chemistry ; Water sorption</subject><ispartof>Carbohydrate polymers, 2014-01, Vol.101, p.163-170</ispartof><rights>2013 Elsevier Ltd</rights><rights>2015 INIST-CNRS</rights><rights>Copyright © 2013 Elsevier Ltd. All rights reserved.</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c476t-48c396d17fa7964aba617575f7cac9ceb4c2db7f759445a7c1f0125a544cffa13</citedby><cites>FETCH-LOGICAL-c476t-48c396d17fa7964aba617575f7cac9ceb4c2db7f759445a7c1f0125a544cffa13</cites><orcidid>0000-0002-9498-6194 ; 0000-0002-3815-9178 ; 0000-0002-7361-3444 ; 0000-0003-4041-1253</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.carbpol.2013.09.023$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>230,314,777,781,882,3537,27905,27906,45976</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=28344794$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/24299761$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink><backlink>$$Uhttps://hal.science/hal-01007227$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Célino, Amandine</creatorcontrib><creatorcontrib>Gonçalves, Olivier</creatorcontrib><creatorcontrib>Jacquemin, Frédéric</creatorcontrib><creatorcontrib>Fréour, Sylvain</creatorcontrib><title>Qualitative and quantitative assessment of water sorption in natural fibres using ATR-FTIR spectroscopy</title><title>Carbohydrate polymers</title><addtitle>Carbohydr Polym</addtitle><description>•Effect of moisture sorption on plant fibres was investigated by FTIR spectroscopy.•Hydroxyl and carboxyl moieties are specific sites for water sorption.•Partial least squares regression quantified the water content of natural fibres.•Models fitted the sorption isotherms and diffusion kinetics.
In the field of composite materials, natural fibres appear to be a viable replacement for glass fibres. However, in humid conditions, strong hydrophilic behaviour of such materials can lead to their structural modification. Then, understanding moisture sorption mechanisms in these materials is an important issue for their efficient use. In this work, the water sorption on three natural fibres (flax, hemp and sisal) was studied using Fourier transformed infrared spectroscopy. The spectral information allowed both qualitative and quantitative analyses of the moisture absorption mechanisms. The main chemical functions involved in the water sorption phenomenon were identified. The absolute water content of the fibres was also determined by using a partial least square regression (PLS-R) approach. Moreover, typical sorption isotherm curves described by Park model were fitted as well as water diffusion kinetics. These last applications confirmed the validity of the FTIR spectra based predictive models.</description><subject>Absorption</subject><subject>Analytical chemistry</subject><subject>Applied sciences</subject><subject>Biological Products - chemistry</subject><subject>Chemical and Process Engineering</subject><subject>Chemical Sciences</subject><subject>Compounding ingredients</subject><subject>Diffusion</subject><subject>Diffusion kinetics</subject><subject>Engineering Sciences</subject><subject>Exact sciences and technology</subject><subject>Fibers and threads</subject><subject>Fillers and reinforcing agents</subject><subject>Forms of application and semi-finished materials</subject><subject>Fourier transformed infrared spectroscopy</subject><subject>Kinetics</subject><subject>Least-Squares Analysis</subject><subject>Materials</subject><subject>Mechanics</subject><subject>Natural fibres</subject><subject>Partial least square regression</subject><subject>Plants - chemistry</subject><subject>Polymer industry, paints, wood</subject><subject>Spectroscopy, Fourier Transform Infrared</subject><subject>Technology of polymers</subject><subject>Water - chemistry</subject><subject>Water sorption</subject><issn>0144-8617</issn><issn>1879-1344</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkUuL2zAQgEVp6abb_oQWXQrtwa5ky1Z0KmHpPiBQuqRnMZalrYIjezVylv33VUg2PXYuguGbh-Yj5CNnJWe8_bYtDcRuGoeyYrwumSpZVb8iC76UquC1EK_JgnEhimXL5QV5h7hlOVrO3pKLSlRKyZYvyMOvGQafIPm9pRB6-jhDSOcEokXc2ZDo6OgTJBspjnFKfgzUBxogzREG6nwXLdIZfXigq819cb25u6c4WZPiiGacnt-TNw4GtB9O7yX5ff1jc3VbrH_e3F2t1oURsk2FWJpatT2XDqRqBXSQt29k46QBo4zthKn6TjrZKCEakIY7xqsGGiGMc8DrS_L12PcPDHqKfgfxWY_g9e1qrQ85xhmTVSX3B_bLkZ3i-DhbTHrn0dhhgGDHGTUXbcOlrBXLaHNETf4PRuvOvTnTBx96q08-9MGHZkpnH7nu02nE3O1sf656EZCBzycA0MDgIgTj8R-3zCalEpn7fuRsPt7e26jReBuM7X3MV9b96P-zyl-9p6xA</recordid><startdate>20140130</startdate><enddate>20140130</enddate><creator>Célino, Amandine</creator><creator>Gonçalves, Olivier</creator><creator>Jacquemin, Frédéric</creator><creator>Fréour, Sylvain</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>1XC</scope><scope>VOOES</scope><orcidid>https://orcid.org/0000-0002-9498-6194</orcidid><orcidid>https://orcid.org/0000-0002-3815-9178</orcidid><orcidid>https://orcid.org/0000-0002-7361-3444</orcidid><orcidid>https://orcid.org/0000-0003-4041-1253</orcidid></search><sort><creationdate>20140130</creationdate><title>Qualitative and quantitative assessment of water sorption in natural fibres using ATR-FTIR spectroscopy</title><author>Célino, Amandine ; Gonçalves, Olivier ; Jacquemin, Frédéric ; Fréour, Sylvain</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c476t-48c396d17fa7964aba617575f7cac9ceb4c2db7f759445a7c1f0125a544cffa13</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Absorption</topic><topic>Analytical chemistry</topic><topic>Applied sciences</topic><topic>Biological Products - chemistry</topic><topic>Chemical and Process Engineering</topic><topic>Chemical Sciences</topic><topic>Compounding ingredients</topic><topic>Diffusion</topic><topic>Diffusion kinetics</topic><topic>Engineering Sciences</topic><topic>Exact sciences and technology</topic><topic>Fibers and threads</topic><topic>Fillers and reinforcing agents</topic><topic>Forms of application and semi-finished materials</topic><topic>Fourier transformed infrared spectroscopy</topic><topic>Kinetics</topic><topic>Least-Squares Analysis</topic><topic>Materials</topic><topic>Mechanics</topic><topic>Natural fibres</topic><topic>Partial least square regression</topic><topic>Plants - chemistry</topic><topic>Polymer industry, paints, wood</topic><topic>Spectroscopy, Fourier Transform Infrared</topic><topic>Technology of polymers</topic><topic>Water - chemistry</topic><topic>Water sorption</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Célino, Amandine</creatorcontrib><creatorcontrib>Gonçalves, Olivier</creatorcontrib><creatorcontrib>Jacquemin, Frédéric</creatorcontrib><creatorcontrib>Fréour, Sylvain</creatorcontrib><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>Hyper Article en Ligne (HAL)</collection><collection>Hyper Article en Ligne (HAL) (Open Access)</collection><jtitle>Carbohydrate polymers</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Célino, Amandine</au><au>Gonçalves, Olivier</au><au>Jacquemin, Frédéric</au><au>Fréour, Sylvain</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Qualitative and quantitative assessment of water sorption in natural fibres using ATR-FTIR spectroscopy</atitle><jtitle>Carbohydrate polymers</jtitle><addtitle>Carbohydr Polym</addtitle><date>2014-01-30</date><risdate>2014</risdate><volume>101</volume><spage>163</spage><epage>170</epage><pages>163-170</pages><issn>0144-8617</issn><eissn>1879-1344</eissn><coden>CAPOD8</coden><abstract>•Effect of moisture sorption on plant fibres was investigated by FTIR spectroscopy.•Hydroxyl and carboxyl moieties are specific sites for water sorption.•Partial least squares regression quantified the water content of natural fibres.•Models fitted the sorption isotherms and diffusion kinetics.
In the field of composite materials, natural fibres appear to be a viable replacement for glass fibres. However, in humid conditions, strong hydrophilic behaviour of such materials can lead to their structural modification. Then, understanding moisture sorption mechanisms in these materials is an important issue for their efficient use. In this work, the water sorption on three natural fibres (flax, hemp and sisal) was studied using Fourier transformed infrared spectroscopy. The spectral information allowed both qualitative and quantitative analyses of the moisture absorption mechanisms. The main chemical functions involved in the water sorption phenomenon were identified. The absolute water content of the fibres was also determined by using a partial least square regression (PLS-R) approach. Moreover, typical sorption isotherm curves described by Park model were fitted as well as water diffusion kinetics. These last applications confirmed the validity of the FTIR spectra based predictive models.</abstract><cop>Kidlington</cop><pub>Elsevier Ltd</pub><pmid>24299761</pmid><doi>10.1016/j.carbpol.2013.09.023</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0002-9498-6194</orcidid><orcidid>https://orcid.org/0000-0002-3815-9178</orcidid><orcidid>https://orcid.org/0000-0002-7361-3444</orcidid><orcidid>https://orcid.org/0000-0003-4041-1253</orcidid><oa>free_for_read</oa></addata></record> |
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| ispartof | Carbohydrate polymers, 2014-01, Vol.101, p.163-170 |
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| subjects | Absorption Analytical chemistry Applied sciences Biological Products - chemistry Chemical and Process Engineering Chemical Sciences Compounding ingredients Diffusion Diffusion kinetics Engineering Sciences Exact sciences and technology Fibers and threads Fillers and reinforcing agents Forms of application and semi-finished materials Fourier transformed infrared spectroscopy Kinetics Least-Squares Analysis Materials Mechanics Natural fibres Partial least square regression Plants - chemistry Polymer industry, paints, wood Spectroscopy, Fourier Transform Infrared Technology of polymers Water - chemistry Water sorption |
| title | Qualitative and quantitative assessment of water sorption in natural fibres using ATR-FTIR spectroscopy |
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