Beyond the anisotropy barrier: slow relaxation of the magnetization in both easy-axis and easy-plane Ln(trensal) complexes

We present a spectroscopic and magnetic (both static and dynamic) characterization of two isostructural Dy and Er complexes evidencing that, despite the different types of magnetic anisotropy, the two molecules show similar slow relaxation of the magnetization in a static magnetic field.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2014-01, Vol.50 (14), p.1648-1651
Hauptverfasser: Lucaccini, Eva, Sorace, Lorenzo, Perfetti, Mauro, Costes, Jean-Pierre, Sessoli, Roberta
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container_issue 14
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container_title Chemical communications (Cambridge, England)
container_volume 50
creator Lucaccini, Eva
Sorace, Lorenzo
Perfetti, Mauro
Costes, Jean-Pierre
Sessoli, Roberta
description We present a spectroscopic and magnetic (both static and dynamic) characterization of two isostructural Dy and Er complexes evidencing that, despite the different types of magnetic anisotropy, the two molecules show similar slow relaxation of the magnetization in a static magnetic field.
doi_str_mv 10.1039/c3cc48866g
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source Royal Society Of Chemistry Journals; Alma/SFX Local Collection
subjects Barriers
Chemical Sciences
Coordination chemistry
title Beyond the anisotropy barrier: slow relaxation of the magnetization in both easy-axis and easy-plane Ln(trensal) complexes
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