Electrosynthesis and characterization of oligophenylene deriving from 4-(methoxyphenyl)acetonitrile

► The anodic oxidation of p-methoxyphenylacetonitrile led to a conjugated oligophenylene. ► The chemical structure was elucidated by different spectroscopic techniques. ► A mechanism for the electro-oxidative oligomerization was evoked in the light of a DFT theoretical calculation. ► A photoluminesc...

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Veröffentlicht in:	Journal of molecular structure 2013-01, Vol.1031 (16), p.186-193
Hauptverfasser:	Amor, Sarra Ben, Said, Ayoub Haj, Chemek, Mourad, Ayachi, Sahbi, Massuyeau, Florian, Wéry, Jany, Alimi, Kamel, Roudesli, Sadok
Format:	Artikel
Sprache:	eng
Schlagworte:	4-(Methoxyphenyl)acetonitrile acetonitrile Anodizing Cations chemical structure Condensed Matter Conjugated polymers DFT calculation differential scanning calorimetry Electrodes Electrosynthesis Emission spectroscopy Fourier transform infrared spectroscopy gel permeation chromatography Materials Science Molecular structure nuclear magnetic resonance spectroscopy Oligomers oxidation Photoluminescence Physics solubility solvents Thermogravimetric analysis thermogravimetry ultraviolet-visible spectroscopy
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