Properties of a Tunable Multinuclear Nickel Polyoxotungstate Platform

A series of hybrid nickel bisphosphonate (BP) polyoxometalates (POMs) has been isolated. The complexes NaK‐Ni7‐Ale2 (Ale=[H2O3PC(C3H6NH2)(OH)PO3H2]) and NaNH4‐Ni7‐Ale2 are both made of two {PW9O34} fragments enclosing a heptanuclear NiII core connected to two alendronate ligands. By pre‐functionalis...

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Veröffentlicht in:	Chemistry : a European journal 2013-05, Vol.19 (21), p.6753-6765
Hauptverfasser:	El Moll, Hani, Rousseau, Guillaume, Dolbecq, Anne, Oms, Olivier, Marrot, Jérôme, Haouas, Mohamed, Taulelle, Francis, Rivière, Eric, Wernsdorfer, Wolfgang, Lachkar, David, Lacôte, Emmanuel, Keita, Bineta, Mialane, Pierre
Format:	Artikel
Sprache:	eng
Schlagworte:	Acetal resins Alcohols Amines - chemistry Catalysis Catalysts Chemistry Cobalt - chemistry Crystallography, X-Ray Electrochemistry hybrid materials Hydrogen Peroxide Ligands Magnetic Resonance Spectroscopy Magnetics Models, Molecular molecular magnetism Nickel Nickel - chemistry Nitrates nitrogen oxide reduction NMR spectroscopy oxidation Oxidation-Reduction Physics Platforms polyoxometalates Reduction Studies Tungsten Compounds - chemistry
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