Radical Additions of Xanthates to Vinyl Epoxides and Related Derivatives: A Powerful Tool for the Modular Creation of Quaternary Centers

An open relationship: The triethylborane/O2‐mediated addition of xanthates to vinyl epoxides and derivatives represents an efficient process to form carbon–carbon bonds. Complex structures can be rapidly assembled in a modular, convergent manner, under mild conditions, using readily available reagen...

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Veröffentlicht in:	Angewandte Chemie International Edition 2006-10, Vol.45 (39), p.6520-6523
Hauptverfasser:	Charrier, Nicolas, Gravestock, David, Zard, Samir Z.
Format:	Artikel
Sprache:	eng
Schlagworte:	allylation allylic alcohols Chemical Sciences Organic chemistry radical reactions vinyl epoxides xanthates
Online-Zugang:	Volltext
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