Transparent ZnS Ceramics by Sintering of High Purity Monodisperse Nanopowders
We report an efficient way of preparing transparent ZnS ceramics using the hot‐pressing technique. It has been found that the transparency is highly dependent on the purity and the grain size distribution of the starting ZnS powders. Highly pure and monodisperse ZnS powders have been obtained by pos...
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| Veröffentlicht in: | Journal of the American Ceramic Society 2013-10, Vol.96 (10), p.3070-3074 |
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| container_title | Journal of the American Ceramic Society |
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| creator | Chlique, Christophe Merdrignac-Conanec, Odile Hakmeh, Noha Zhang, Xianghua Adam, Jean-Luc |
| description | We report an efficient way of preparing transparent ZnS ceramics using the hot‐pressing technique. It has been found that the transparency is highly dependent on the purity and the grain size distribution of the starting ZnS powders. Highly pure and monodisperse ZnS powders have been obtained by posttreatment of the precipitated powders in a H2S/N2 flow for 2 h at 600°C. The obtained ZnS ceramics show fully dense and homogeneous microstructure with average grain size of ~1 μm and smooth grain boundaries, leading to an excellent transmission of around 70% in the mid‐ and far‐ IR regions. The preparation technique described in this study is highly reproducible. |
| doi_str_mv | 10.1111/jace.12570 |
| format | Article |
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It has been found that the transparency is highly dependent on the purity and the grain size distribution of the starting ZnS powders. Highly pure and monodisperse ZnS powders have been obtained by posttreatment of the precipitated powders in a H2S/N2 flow for 2 h at 600°C. The obtained ZnS ceramics show fully dense and homogeneous microstructure with average grain size of ~1 μm and smooth grain boundaries, leading to an excellent transmission of around 70% in the mid‐ and far‐ IR regions. The preparation technique described in this study is highly reproducible.</description><identifier>ISSN: 0002-7820</identifier><identifier>EISSN: 1551-2916</identifier><identifier>DOI: 10.1111/jace.12570</identifier><identifier>CODEN: JACTAW</identifier><language>eng</language><publisher>Columbus: Blackwell Publishing Ltd</publisher><subject>Ceramic sintering ; Ceramics ; Chemical Sciences ; Grain boundaries ; Grain size ; Hot pressing ; Material chemistry ; Microstructure ; Nanocomposites ; Nanomaterials ; Nanostructure ; Purity ; Zinc sulfides</subject><ispartof>Journal of the American Ceramic Society, 2013-10, Vol.96 (10), p.3070-3074</ispartof><rights>2013 The American Ceramic Society</rights><rights>Copyright Wiley Subscription Services, Inc. Oct 2013</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c5740-1de5865a3b5571f135d8afb3901d3dfab9a31a338f22352840041b220624d4ec3</citedby><cites>FETCH-LOGICAL-c5740-1de5865a3b5571f135d8afb3901d3dfab9a31a338f22352840041b220624d4ec3</cites><orcidid>0000-0002-1242-6776 ; 0000-0002-2180-6543 ; 0000-0002-9293-5844</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1111%2Fjace.12570$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1111%2Fjace.12570$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>230,314,780,784,885,1417,27924,27925,45574,45575</link.rule.ids><backlink>$$Uhttps://hal.science/hal-00946222$$DView record in HAL$$Hfree_for_read</backlink></links><search><contributor>Bhandarkar, S.</contributor><contributor>Bhandarkar, S.</contributor><creatorcontrib>Chlique, Christophe</creatorcontrib><creatorcontrib>Merdrignac-Conanec, Odile</creatorcontrib><creatorcontrib>Hakmeh, Noha</creatorcontrib><creatorcontrib>Zhang, Xianghua</creatorcontrib><creatorcontrib>Adam, Jean-Luc</creatorcontrib><title>Transparent ZnS Ceramics by Sintering of High Purity Monodisperse Nanopowders</title><title>Journal of the American Ceramic Society</title><addtitle>J. Am. Ceram. Soc</addtitle><description>We report an efficient way of preparing transparent ZnS ceramics using the hot‐pressing technique. It has been found that the transparency is highly dependent on the purity and the grain size distribution of the starting ZnS powders. Highly pure and monodisperse ZnS powders have been obtained by posttreatment of the precipitated powders in a H2S/N2 flow for 2 h at 600°C. The obtained ZnS ceramics show fully dense and homogeneous microstructure with average grain size of ~1 μm and smooth grain boundaries, leading to an excellent transmission of around 70% in the mid‐ and far‐ IR regions. The preparation technique described in this study is highly reproducible.</description><subject>Ceramic sintering</subject><subject>Ceramics</subject><subject>Chemical Sciences</subject><subject>Grain boundaries</subject><subject>Grain size</subject><subject>Hot pressing</subject><subject>Material chemistry</subject><subject>Microstructure</subject><subject>Nanocomposites</subject><subject>Nanomaterials</subject><subject>Nanostructure</subject><subject>Purity</subject><subject>Zinc sulfides</subject><issn>0002-7820</issn><issn>1551-2916</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNqN0c9v0zAUB3ALMYmy7cJfEIkLIGX4-VecY9WNdtCVSStC4mI5ibO5pHawU7b-97gEduAA-GI96_P8ZH8RegH4DNJ6u9G1OQPCC_wETYBzyEkJ4imaYIxJXkiCn6HnMW5SCaVkE3S1DtrFXgfjhuyLu8lmJuitrWNW7bMb6wYTrLvNfJst7O1ddr0LdthnV975xsbehGiylXa-9_dNKk7QUau7aE5_7cfo07uL9WyRLz_OL2fTZV7zguEcGsOl4JpWnBfQAuWN1G1FSwwNbVpdlZqCplS2hFBOJMOYQUUIFoQ1zNT0GL0e773TneqD3eqwV15btZgu1eEM45IJQsh3SPbVaPvgv-1MHNTWxtp0nXbG76ICUaYhsuD035SVjHIhgf8HFYxzyqlI9OUfdON3waX_SYoRCVIUJKk3o6qDjzGY9vFdgNUhW3XIVv3MNmEY8b3tzP4vUr2fzi5-9-Rjj42DeXjs0eGrEgUtuPq8miuyWM3P8Ye1ovQHheqxcQ</recordid><startdate>201310</startdate><enddate>201310</enddate><creator>Chlique, Christophe</creator><creator>Merdrignac-Conanec, Odile</creator><creator>Hakmeh, Noha</creator><creator>Zhang, Xianghua</creator><creator>Adam, Jean-Luc</creator><general>Blackwell Publishing Ltd</general><general>Wiley Subscription Services, Inc</general><general>Wiley</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QQ</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><scope>7U5</scope><scope>8BQ</scope><scope>L7M</scope><scope>1XC</scope><orcidid>https://orcid.org/0000-0002-1242-6776</orcidid><orcidid>https://orcid.org/0000-0002-2180-6543</orcidid><orcidid>https://orcid.org/0000-0002-9293-5844</orcidid></search><sort><creationdate>201310</creationdate><title>Transparent ZnS Ceramics by Sintering of High Purity Monodisperse Nanopowders</title><author>Chlique, Christophe ; Merdrignac-Conanec, Odile ; Hakmeh, Noha ; Zhang, Xianghua ; Adam, Jean-Luc</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c5740-1de5865a3b5571f135d8afb3901d3dfab9a31a338f22352840041b220624d4ec3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Ceramic sintering</topic><topic>Ceramics</topic><topic>Chemical Sciences</topic><topic>Grain boundaries</topic><topic>Grain size</topic><topic>Hot pressing</topic><topic>Material chemistry</topic><topic>Microstructure</topic><topic>Nanocomposites</topic><topic>Nanomaterials</topic><topic>Nanostructure</topic><topic>Purity</topic><topic>Zinc sulfides</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Chlique, Christophe</creatorcontrib><creatorcontrib>Merdrignac-Conanec, Odile</creatorcontrib><creatorcontrib>Hakmeh, Noha</creatorcontrib><creatorcontrib>Zhang, Xianghua</creatorcontrib><creatorcontrib>Adam, Jean-Luc</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><collection>Ceramic Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>Journal of the American Ceramic Society</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Chlique, Christophe</au><au>Merdrignac-Conanec, Odile</au><au>Hakmeh, Noha</au><au>Zhang, Xianghua</au><au>Adam, Jean-Luc</au><au>Bhandarkar, S.</au><au>Bhandarkar, S.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Transparent ZnS Ceramics by Sintering of High Purity Monodisperse Nanopowders</atitle><jtitle>Journal of the American Ceramic Society</jtitle><addtitle>J. Am. Ceram. Soc</addtitle><date>2013-10</date><risdate>2013</risdate><volume>96</volume><issue>10</issue><spage>3070</spage><epage>3074</epage><pages>3070-3074</pages><issn>0002-7820</issn><eissn>1551-2916</eissn><coden>JACTAW</coden><abstract>We report an efficient way of preparing transparent ZnS ceramics using the hot‐pressing technique. It has been found that the transparency is highly dependent on the purity and the grain size distribution of the starting ZnS powders. Highly pure and monodisperse ZnS powders have been obtained by posttreatment of the precipitated powders in a H2S/N2 flow for 2 h at 600°C. The obtained ZnS ceramics show fully dense and homogeneous microstructure with average grain size of ~1 μm and smooth grain boundaries, leading to an excellent transmission of around 70% in the mid‐ and far‐ IR regions. 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| subjects | Ceramic sintering Ceramics Chemical Sciences Grain boundaries Grain size Hot pressing Material chemistry Microstructure Nanocomposites Nanomaterials Nanostructure Purity Zinc sulfides |
| title | Transparent ZnS Ceramics by Sintering of High Purity Monodisperse Nanopowders |
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