Photoactive Hybrid Gelators Based on a Luminescent Inorganic [Cu4I4] Cluster Core

Photoactive Hybrid Gelators Based on a Luminescent Inorganic [Cu4I4] Cluster Core

Luminescent clustogelator: Hybrid gelators with a [Cu4I4] cluster core functionalized by cholesteryl derivatives allow solvent gelation through the formation of a globular network (see figure). The resulting gels display thermochromic and rigidochromic luminescence properties, the latter being used...

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Veröffentlicht in:Chemistry : a European journal 2013-11, Vol.19 (47), p.15831-15835
Hauptverfasser: Benito, Quentin, Fargues, Alexandre, Garcia, Alain, Maron, Sébastien, Gacoin, Thierry, Boilot, Jean-Pierre, Perruchas, Sandrine, Camerel, Franck
Format: Artikel
Sprache:eng
Schlagworte:
Chemical Sciences
Chemistry
cluster compounds
Clusters
Derivatives
Dynamic mechanical properties
Dynamics
Gelation
gels
Luminescence
Material chemistry
metallogelators
Networks
rigidochromic luminescence
Solvents
thermochromic luminescence
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Zusammenfassung:Luminescent clustogelator: Hybrid gelators with a [Cu4I4] cluster core functionalized by cholesteryl derivatives allow solvent gelation through the formation of a globular network (see figure). The resulting gels display thermochromic and rigidochromic luminescence properties, the latter being used to probe the dynamics of the gelation phenomenon.
ISSN:0947-6539
1521-3765
DOI:10.1002/chem.201303567