Synthesis of Phosphorus(V)-Stabilized Geminal Dianions. The Cases of Mixed PX/P→BH3 (X = S, O) and PS/SiMe3 Derivatives

The monodeprotonation of [CH2(PPh2→BH3)­(PPh2E)] (E = S (6), O (7)) afforded [CH­(PPh2→BH3)­(PPh2E)]− (E = S (6 ‑ ), O (7 – )), whose structures were confirmed by X-ray crystallography. The kinetics of the second deprotonation appeared to be crucial in efficient synthesis of the corresponding dian...

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Veröffentlicht in:	Organometallics 2013-01, Vol.32 (2), p.498-508
Hauptverfasser:	Heuclin, Hadrien, Fustier-Boutignon, Marie, Ho, Samuel Ying-Fu, Le Goff, Xavier-Frédéric, Carenco, Sophie, So, Cheuk-Wai, Mézailles, Nicolas
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemical Sciences Coordination chemistry
Online-Zugang:	Volltext
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