Homologous Critical Behavior in the Molecular Frameworks Zn(CN)2 and Cd(imidazolate)2

Using a combination of single-crystal and powder X-ray diffraction measurements, we study temperature- and pressure-driven structural distortions in zinc(II) cyanide (Zn(CN)2) and cadmium(II) imidazolate (Cd(im)2), two molecular frameworks with the anticuprite topology. Under a hydrostatic pressure...

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Veröffentlicht in:	Journal of the American Chemical Society 2013-05, Vol.135 (20), p.7610-7620
Hauptverfasser:	Collings, Ines E, Cairns, Andrew B, Thompson, Amber L, Parker, Julia E, Tang, Chiu C, Tucker, Matthew G, Catafesta, Jadna, Levelut, Claire, Haines, Julien, Dmitriev, Vladimir, Pattison, Philip, Goodwin, Andrew L
Format:	Artikel
Sprache:	eng
Schlagworte:	Cadmium - chemistry Chemical Sciences Cyanides - chemistry Imidazoles - chemistry Material chemistry Models, Molecular Organometallic Compounds - chemistry Powder Diffraction X-Ray Diffraction Zinc - chemistry
Online-Zugang:	Volltext
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