Design and optimization of electrochemical microreactors for continuous electrosynthesis
The study focuses on the design and construction, as well as the theoretical and experimental optimization of electrochemical filter press microreactors for the electrosynthesis of molecules with a high added value. The main characteristics of these devices are firstly a high-specific electrochemica...
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| Veröffentlicht in: | Journal of applied electrochemistry 2012-09, Vol.42 (9), p.667-677 |
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| container_title | Journal of applied electrochemistry |
| container_volume | 42 |
| creator | Renault, C. Roche, J. Ciumag, M. R. Tzedakis, T. Colin, S. Serrano, K. Reynes, O. André-Barrès, C. Winterton, P. |
| description | The study focuses on the design and construction, as well as the theoretical and experimental optimization of electrochemical filter press microreactors for the electrosynthesis of molecules with a high added value. The main characteristics of these devices are firstly a high-specific electrochemical area to increase conversion and selectivity, and secondly the shape and size of the microchannels designed for a uniform residence time distribution of the fluid. A heat exchanger is integrated into the microstructured electrode to rapidly remove (or supply) the heat required in exo- or endothermic reactions. The microreactors designed are used to perform-specific electrosynthesis reactions such as thermodynamically unfavorable reactions (continuous NADH regeneration), or reactions with high enthalpy changes. |
| doi_str_mv | 10.1007/s10800-012-0445-x |
| format | Article |
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The microreactors designed are used to perform-specific electrosynthesis reactions such as thermodynamically unfavorable reactions (continuous NADH regeneration), or reactions with high enthalpy changes.</description><identifier>ISSN: 0021-891X</identifier><identifier>EISSN: 1572-8838</identifier><identifier>DOI: 10.1007/s10800-012-0445-x</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Chemical engineering ; Chemical Sciences ; Chemistry ; Chemistry and Materials Science ; Devices ; Electrochemistry ; Electrodes ; Endothermic reactions ; Heat exchangers ; Industrial Chemistry/Chemical Engineering ; Microreactors ; NADH ; Optimization ; Original Paper ; Physical Chemistry ; Residence time distribution</subject><ispartof>Journal of applied electrochemistry, 2012-09, Vol.42 (9), p.667-677</ispartof><rights>Springer Science+Business Media B.V. 2012</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c501t-387c62a2653d62432751ef8aaefb249299b7af34f4ad5d426d45a055bf80d5793</citedby><cites>FETCH-LOGICAL-c501t-387c62a2653d62432751ef8aaefb249299b7af34f4ad5d426d45a055bf80d5793</cites><orcidid>0000-0002-8973-1875 ; 0000-0002-9222-4487 ; 0000-0003-3434-3848 ; 0009-0002-5886-7048</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10800-012-0445-x$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10800-012-0445-x$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>230,314,780,784,885,27924,27925,41488,42557,51319</link.rule.ids><backlink>$$Uhttps://hal.science/hal-00878979$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Renault, C.</creatorcontrib><creatorcontrib>Roche, J.</creatorcontrib><creatorcontrib>Ciumag, M. 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| source | SpringerNature Journals |
| subjects | Chemical engineering Chemical Sciences Chemistry Chemistry and Materials Science Devices Electrochemistry Electrodes Endothermic reactions Heat exchangers Industrial Chemistry/Chemical Engineering Microreactors NADH Optimization Original Paper Physical Chemistry Residence time distribution |
| title | Design and optimization of electrochemical microreactors for continuous electrosynthesis |
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