Experimental Vapor Pressures of Five Saturated Fatty Acid Ethyl Ester (FAEE) Components of Biodiesel
Vapor pressures of five saturated fatty acid ethyl esters (FAEEs), ethyl hexanoate (or ethyl caproate), ethyl octanoate (or ethyl caprylate), ethyl decanoate (or ethyl caprate), ethyl dodecanoate (or ethyl laurate), and ethyl tetradecanoate (or ethyl myristate), were measured at pressures from 1 Pa...
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Veröffentlicht in: | Journal of chemical and engineering data 2011-12, Vol.56 (12), p.4736-4740 |
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creator | Benziane, Mokhtar Khimeche, Kamel Mokbel, Ilham Sawaya, Terufat Dahmani, Abdallah Jose, Jacques |
description | Vapor pressures of five saturated fatty acid ethyl esters (FAEEs), ethyl hexanoate (or ethyl caproate), ethyl octanoate (or ethyl caprylate), ethyl decanoate (or ethyl caprate), ethyl dodecanoate (or ethyl laurate), and ethyl tetradecanoate (or ethyl myristate), were measured at pressures from 1 Pa to 180 kPa and temperatures from (253.15 to 463.15) K using a static apparatus. These esters are a light fraction present in biodiesel derived from palmist oil and copra oil (Ballerini and Alazard-Toux, Les biocarburants; IFP Publications: Paris, 2006). The experimental data (P–T) were smoothed using the Antoine equation and compared with the available literature values. The molar enthalpies of vaporization at the mean temperature of the experimental range were derived from the Clausius–Clapeyron equation. From these results the standard enthalpies of vaporization at T = 298.15 K were calculated. |
doi_str_mv | 10.1021/je200730m |
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These esters are a light fraction present in biodiesel derived from palmist oil and copra oil (Ballerini and Alazard-Toux, Les biocarburants; IFP Publications: Paris, 2006). The experimental data (P–T) were smoothed using the Antoine equation and compared with the available literature values. The molar enthalpies of vaporization at the mean temperature of the experimental range were derived from the Clausius–Clapeyron equation. From these results the standard enthalpies of vaporization at T = 298.15 K were calculated.</description><identifier>ISSN: 0021-9568</identifier><identifier>EISSN: 1520-5134</identifier><identifier>DOI: 10.1021/je200730m</identifier><identifier>CODEN: JCEAAX</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>Analytical chemistry ; Biofuel production ; Biological and medical sciences ; Biotechnology ; Chemical engineering ; Chemical Sciences ; Energy ; Fundamental and applied biological sciences. 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Chem. Eng. Data</addtitle><description>Vapor pressures of five saturated fatty acid ethyl esters (FAEEs), ethyl hexanoate (or ethyl caproate), ethyl octanoate (or ethyl caprylate), ethyl decanoate (or ethyl caprate), ethyl dodecanoate (or ethyl laurate), and ethyl tetradecanoate (or ethyl myristate), were measured at pressures from 1 Pa to 180 kPa and temperatures from (253.15 to 463.15) K using a static apparatus. These esters are a light fraction present in biodiesel derived from palmist oil and copra oil (Ballerini and Alazard-Toux, Les biocarburants; IFP Publications: Paris, 2006). The experimental data (P–T) were smoothed using the Antoine equation and compared with the available literature values. The molar enthalpies of vaporization at the mean temperature of the experimental range were derived from the Clausius–Clapeyron equation. From these results the standard enthalpies of vaporization at T = 298.15 K were calculated.</description><subject>Analytical chemistry</subject><subject>Biofuel production</subject><subject>Biological and medical sciences</subject><subject>Biotechnology</subject><subject>Chemical engineering</subject><subject>Chemical Sciences</subject><subject>Energy</subject><subject>Fundamental and applied biological sciences. Psychology</subject><subject>Industrial applications and implications. 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Psychology</topic><topic>Industrial applications and implications. Economical aspects</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Benziane, Mokhtar</creatorcontrib><creatorcontrib>Khimeche, Kamel</creatorcontrib><creatorcontrib>Mokbel, Ilham</creatorcontrib><creatorcontrib>Sawaya, Terufat</creatorcontrib><creatorcontrib>Dahmani, Abdallah</creatorcontrib><creatorcontrib>Jose, Jacques</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>Journal of chemical and engineering data</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Benziane, Mokhtar</au><au>Khimeche, Kamel</au><au>Mokbel, Ilham</au><au>Sawaya, Terufat</au><au>Dahmani, Abdallah</au><au>Jose, Jacques</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Experimental Vapor Pressures of Five Saturated Fatty Acid Ethyl Ester (FAEE) Components of Biodiesel</atitle><jtitle>Journal of chemical and engineering data</jtitle><addtitle>J. Chem. Eng. Data</addtitle><date>2011-12-08</date><risdate>2011</risdate><volume>56</volume><issue>12</issue><spage>4736</spage><epage>4740</epage><pages>4736-4740</pages><issn>0021-9568</issn><eissn>1520-5134</eissn><coden>JCEAAX</coden><abstract>Vapor pressures of five saturated fatty acid ethyl esters (FAEEs), ethyl hexanoate (or ethyl caproate), ethyl octanoate (or ethyl caprylate), ethyl decanoate (or ethyl caprate), ethyl dodecanoate (or ethyl laurate), and ethyl tetradecanoate (or ethyl myristate), were measured at pressures from 1 Pa to 180 kPa and temperatures from (253.15 to 463.15) K using a static apparatus. These esters are a light fraction present in biodiesel derived from palmist oil and copra oil (Ballerini and Alazard-Toux, Les biocarburants; IFP Publications: Paris, 2006). The experimental data (P–T) were smoothed using the Antoine equation and compared with the available literature values. The molar enthalpies of vaporization at the mean temperature of the experimental range were derived from the Clausius–Clapeyron equation. From these results the standard enthalpies of vaporization at T = 298.15 K were calculated.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><doi>10.1021/je200730m</doi><tpages>5</tpages></addata></record> |
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subjects | Analytical chemistry Biofuel production Biological and medical sciences Biotechnology Chemical engineering Chemical Sciences Energy Fundamental and applied biological sciences. Psychology Industrial applications and implications. Economical aspects |
title | Experimental Vapor Pressures of Five Saturated Fatty Acid Ethyl Ester (FAEE) Components of Biodiesel |
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