Experimental Vapor Pressures of Five Saturated Fatty Acid Ethyl Ester (FAEE) Components of Biodiesel

Vapor pressures of five saturated fatty acid ethyl esters (FAEEs), ethyl hexanoate (or ethyl caproate), ethyl octanoate (or ethyl caprylate), ethyl decanoate (or ethyl caprate), ethyl dodecanoate (or ethyl laurate), and ethyl tetradecanoate (or ethyl myristate), were measured at pressures from 1 Pa...

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Veröffentlicht in:Journal of chemical and engineering data 2011-12, Vol.56 (12), p.4736-4740
Hauptverfasser: Benziane, Mokhtar, Khimeche, Kamel, Mokbel, Ilham, Sawaya, Terufat, Dahmani, Abdallah, Jose, Jacques
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container_end_page 4740
container_issue 12
container_start_page 4736
container_title Journal of chemical and engineering data
container_volume 56
creator Benziane, Mokhtar
Khimeche, Kamel
Mokbel, Ilham
Sawaya, Terufat
Dahmani, Abdallah
Jose, Jacques
description Vapor pressures of five saturated fatty acid ethyl esters (FAEEs), ethyl hexanoate (or ethyl caproate), ethyl octanoate (or ethyl caprylate), ethyl decanoate (or ethyl caprate), ethyl dodecanoate (or ethyl laurate), and ethyl tetradecanoate (or ethyl myristate), were measured at pressures from 1 Pa to 180 kPa and temperatures from (253.15 to 463.15) K using a static apparatus. These esters are a light fraction present in biodiesel derived from palmist oil and copra oil (Ballerini and Alazard-Toux, Les biocarburants; IFP Publications: Paris, 2006). The experimental data (P–T) were smoothed using the Antoine equation and compared with the available literature values. The molar enthalpies of vaporization at the mean temperature of the experimental range were derived from the Clausius–Clapeyron equation. From these results the standard enthalpies of vaporization at T = 298.15 K were calculated.
doi_str_mv 10.1021/je200730m
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subjects Analytical chemistry
Biofuel production
Biological and medical sciences
Biotechnology
Chemical engineering
Chemical Sciences
Energy
Fundamental and applied biological sciences. Psychology
Industrial applications and implications. Economical aspects
title Experimental Vapor Pressures of Five Saturated Fatty Acid Ethyl Ester (FAEE) Components of Biodiesel
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