Iron-Catalyzed Hydrosilylation of Esters

Iron-Catalyzed Hydrosilylation of Esters

The first hydrosilylation of esters catalyzed by a well defined iron complex has been developed. Esters are converted to the corresponding alcohols at 100 °C, under solvent‐free conditions and visible light activation.

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Bibliographische Detailangaben
Veröffentlicht in:Advanced synthesis & catalysis 2012-07, Vol.354 (10), p.1879-1884
Hauptverfasser: Bézier, David, Venkanna, Gopaladasu T., Castro, Luis C. Misal, Zheng, Jianxia, Roisnel, Thierry, Sortais, Jean-Baptiste, Darcel, Christophe
Format: Artikel
Sprache:eng
Schlagworte:
Activation
alcohols
Aliphatic compounds
Catalysis
Chemical Sciences
Chemistry
esters
Exact sciences and technology
hydrosilylation
iron catalysis
Organic chemistry
Preparations and properties
reduction
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Beschreibung
Zusammenfassung:The first hydrosilylation of esters catalyzed by a well defined iron complex has been developed. Esters are converted to the corresponding alcohols at 100 °C, under solvent‐free conditions and visible light activation.
ISSN:1615-4150
1615-4169
DOI:10.1002/adsc.201200087