Mechanistic and Preparative Studies of Radical Chain Homolytic Substitution Reactions of N‑Heterocyclic Carbene Boranes and Disulfides

Reactions of 1,3-dimethylimidazol-2-ylidene–borane (diMe-Imd-BH3) and related NHC–boranes with diaryl and diheteroaryl disulfides provide diverse NHC–boryl monosulfides (diMe-Imd-BH2SAr) and NHC–boryl disulfides (diMe-Imd-BH(SAr)2). Heating in the dark with 1 equiv of disulfide favors monosulfide fo...

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Veröffentlicht in:	Journal of the American Chemical Society 2013-07, Vol.135 (28), p.10484-10491
Hauptverfasser:	Pan, Xiangcheng, Vallet, Anne-Laure, Schweizer, Stéphane, Dahbi, Karim, Delpech, Bernard, Blanchard, Nicolas, Graff, Bernadette, Geib, Steven J, Curran, Dennis P, Lalevée, Jacques, Lacôte, Emmanuel
Format:	Artikel
Sprache:	eng
Schlagworte:	Boranes - chemistry Chemical Sciences Disulfides - chemistry Free Radicals - chemical synthesis Free Radicals - chemistry Heterocyclic Compounds - chemical synthesis Heterocyclic Compounds - chemistry Methane - analogs & derivatives Methane - chemical synthesis Methane - chemistry Molecular Structure Organic chemistry
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