Revisiting the Spectroscopy of the Bi3+ Ion in Oxide Compounds

A model is introduced to predict the energy of metal-to-metal charge-transfer transitions in oxide compounds containing Bi3+ ions and d0 or d10 metals (M n+). The model takes into account the structural characteristics of the host lattices, the anion relaxation resulting from Bi3+ doping, and the el...

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Veröffentlicht in:	Inorganic chemistry 2013-05, Vol.52 (10), p.6028-6038
1. Verfasser:	Boutinaud, Philippe
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Sprache:	eng
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description	A model is introduced to predict the energy of metal-to-metal charge-transfer transitions in oxide compounds containing Bi3+ ions and d0 or d10 metals (M n+). The model takes into account the structural characteristics of the host lattices, the anion relaxation resulting from Bi3+ doping, and the electronegativities and coordination numbers of the Bi3+ and M n+ ions in the compounds. It is shown, through a critical review of the archival literature, that this model provides new insights on the assignment of the luminescence spectra and the related interpretation of the spectroscopic behaviors.
doi_str_mv	10.1021/ic400382k
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title	Revisiting the Spectroscopy of the Bi3+ Ion in Oxide Compounds
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