Excited state absorption: a key phenomenon for the improvement of biphotonic based optical limiting at telecommunication wavelengths
Spectroscopic properties, two-photon absorption (TPA) and excited state absorption (ESA), of two organic cyanine dyes and of a ruthenium based organometallic cyanine are compared in order to rationalize their similar ns-optical power limiting (OPL) efficiency in the telecommunication wavelength rang...
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| Veröffentlicht in: | Physical chemistry chemical physics : PCCP 2012-01, Vol.14 (44), p.15299-15307 |
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| container_title | Physical chemistry chemical physics : PCCP |
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| creator | BELLIER, Quentin MAKAROV, Nikolay S BOUIT, Pierre-Antoine RIGAUT, Stephane KAMADA, Kenji FENEYROU, Patrick BERGINC, Gerard MAURY, Olivier PERRY, Joseph W ANDRAUD, Chantal |
| description | Spectroscopic properties, two-photon absorption (TPA) and excited state absorption (ESA), of two organic cyanine dyes and of a ruthenium based organometallic cyanine are compared in order to rationalize their similar ns-optical power limiting (OPL) efficiency in the telecommunication wavelength range. The TPA contribution to the ns-OPL behavior is higher for both organic cyanines, while the main process is a TPA-induced ESA in the case of the organometallic system, in which the ruthenium induces a broadening of the NIR-ESA band and resulting in a strong spectral overlap between TPA and ESA spectra. |
| doi_str_mv | 10.1039/c2cp40779e |
| format | Article |
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The TPA contribution to the ns-OPL behavior is higher for both organic cyanines, while the main process is a TPA-induced ESA in the case of the organometallic system, in which the ruthenium induces a broadening of the NIR-ESA band and resulting in a strong spectral overlap between TPA and ESA spectra.</description><identifier>ISSN: 1463-9076</identifier><identifier>EISSN: 1463-9084</identifier><identifier>DOI: 10.1039/c2cp40779e</identifier><identifier>PMID: 23051920</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Band spectra ; Carbocyanines - chemistry ; Chemical Sciences ; Chemistry ; Coloring Agents - chemistry ; Constraining ; Exact sciences and technology ; Excitation spectra ; General and physical chemistry ; Metalorganic compounds ; Molecular Structure ; or physical chemistry ; Organometallic Compounds - chemistry ; Ruthenium ; Ruthenium - chemistry ; Spectra ; Spectrophotometry ; Telecommunications ; Theoretical and ; Wavelengths</subject><ispartof>Physical chemistry chemical physics : PCCP, 2012-01, Vol.14 (44), p.15299-15307</ispartof><rights>2015 INIST-CNRS</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c486t-6272b62ba0b27360657099cc09f0a5babf48f5df758a23452b0e5d8430222fb03</citedby><cites>FETCH-LOGICAL-c486t-6272b62ba0b27360657099cc09f0a5babf48f5df758a23452b0e5d8430222fb03</cites><orcidid>0000-0001-7001-9039 ; 0000-0002-4623-3227 ; 0000-0002-4639-643X ; 0000-0002-0538-9276 ; 0000-0002-6718-9624</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,314,780,784,885,27924,27925</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=26576878$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/23051920$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink><backlink>$$Uhttps://hal.science/hal-00833259$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>BELLIER, Quentin</creatorcontrib><creatorcontrib>MAKAROV, Nikolay S</creatorcontrib><creatorcontrib>BOUIT, Pierre-Antoine</creatorcontrib><creatorcontrib>RIGAUT, Stephane</creatorcontrib><creatorcontrib>KAMADA, Kenji</creatorcontrib><creatorcontrib>FENEYROU, Patrick</creatorcontrib><creatorcontrib>BERGINC, Gerard</creatorcontrib><creatorcontrib>MAURY, Olivier</creatorcontrib><creatorcontrib>PERRY, Joseph W</creatorcontrib><creatorcontrib>ANDRAUD, Chantal</creatorcontrib><title>Excited state absorption: a key phenomenon for the improvement of biphotonic based optical limiting at telecommunication wavelengths</title><title>Physical chemistry chemical physics : PCCP</title><addtitle>Phys Chem Chem Phys</addtitle><description>Spectroscopic properties, two-photon absorption (TPA) and excited state absorption (ESA), of two organic cyanine dyes and of a ruthenium based organometallic cyanine are compared in order to rationalize their similar ns-optical power limiting (OPL) efficiency in the telecommunication wavelength range. 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MAKAROV, Nikolay S ; BOUIT, Pierre-Antoine ; RIGAUT, Stephane ; KAMADA, Kenji ; FENEYROU, Patrick ; BERGINC, Gerard ; MAURY, Olivier ; PERRY, Joseph W ; ANDRAUD, Chantal</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c486t-6272b62ba0b27360657099cc09f0a5babf48f5df758a23452b0e5d8430222fb03</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>Band spectra</topic><topic>Carbocyanines - chemistry</topic><topic>Chemical Sciences</topic><topic>Chemistry</topic><topic>Coloring Agents - chemistry</topic><topic>Constraining</topic><topic>Exact sciences and technology</topic><topic>Excitation spectra</topic><topic>General and physical chemistry</topic><topic>Metalorganic compounds</topic><topic>Molecular Structure</topic><topic>or physical chemistry</topic><topic>Organometallic Compounds - chemistry</topic><topic>Ruthenium</topic><topic>Ruthenium - chemistry</topic><topic>Spectra</topic><topic>Spectrophotometry</topic><topic>Telecommunications</topic><topic>Theoretical and</topic><topic>Wavelengths</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>BELLIER, Quentin</creatorcontrib><creatorcontrib>MAKAROV, Nikolay S</creatorcontrib><creatorcontrib>BOUIT, Pierre-Antoine</creatorcontrib><creatorcontrib>RIGAUT, Stephane</creatorcontrib><creatorcontrib>KAMADA, Kenji</creatorcontrib><creatorcontrib>FENEYROU, Patrick</creatorcontrib><creatorcontrib>BERGINC, Gerard</creatorcontrib><creatorcontrib>MAURY, Olivier</creatorcontrib><creatorcontrib>PERRY, Joseph W</creatorcontrib><creatorcontrib>ANDRAUD, Chantal</creatorcontrib><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>Electronics & Communications Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Hyper Article en Ligne (HAL)</collection><collection>Hyper Article en Ligne (HAL) (Open Access)</collection><jtitle>Physical chemistry chemical physics : PCCP</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>BELLIER, Quentin</au><au>MAKAROV, Nikolay S</au><au>BOUIT, Pierre-Antoine</au><au>RIGAUT, Stephane</au><au>KAMADA, Kenji</au><au>FENEYROU, Patrick</au><au>BERGINC, Gerard</au><au>MAURY, Olivier</au><au>PERRY, Joseph W</au><au>ANDRAUD, Chantal</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Excited state absorption: a key phenomenon for the improvement of biphotonic based optical limiting at telecommunication wavelengths</atitle><jtitle>Physical chemistry chemical physics : PCCP</jtitle><addtitle>Phys Chem Chem Phys</addtitle><date>2012-01-01</date><risdate>2012</risdate><volume>14</volume><issue>44</issue><spage>15299</spage><epage>15307</epage><pages>15299-15307</pages><issn>1463-9076</issn><eissn>1463-9084</eissn><abstract>Spectroscopic properties, two-photon absorption (TPA) and excited state absorption (ESA), of two organic cyanine dyes and of a ruthenium based organometallic cyanine are compared in order to rationalize their similar ns-optical power limiting (OPL) efficiency in the telecommunication wavelength range. 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| source | MEDLINE; Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Band spectra Carbocyanines - chemistry Chemical Sciences Chemistry Coloring Agents - chemistry Constraining Exact sciences and technology Excitation spectra General and physical chemistry Metalorganic compounds Molecular Structure or physical chemistry Organometallic Compounds - chemistry Ruthenium Ruthenium - chemistry Spectra Spectrophotometry Telecommunications Theoretical and Wavelengths |
| title | Excited state absorption: a key phenomenon for the improvement of biphotonic based optical limiting at telecommunication wavelengths |
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