Controlled ROP of β-Butyrolactone Simply Mediated by Amidine, Guanidine, and Phosphazene Organocatalysts

Basic organocatalysts of the guanidine (1,5,7‐triazabicyclo[4.4.0]dec‐5‐ene, TBD), amidine (1,8‐diazabicyclo[5.4.0]‐undec‐7‐ene, DBU), and phosphazene (2‐tert‐butylimino‐2‐diethylamino‐1,3‐dimethylperhydro‐1,3,2diazaphosphorine, BEMP) type do effectively polymerize β‐butyrolactone (BL). Poly(3‐hydro...

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Veröffentlicht in:	Macromolecular rapid communications. 2012-11, Vol.33 (22), p.1938-1944
Hauptverfasser:	Jaffredo, Cédric G., Carpentier, Jean-François, Guillaume, Sophie M.
Format:	Artikel
Sprache:	eng
Schlagworte:	4-Butyrolactone - analogs & derivatives 4-Butyrolactone - chemistry Applied sciences Azabicyclo Compounds - chemistry beta-lactone Bridged Bicyclo Compounds, Heterocyclic - chemistry Catalysis Chemical Sciences Exact sciences and technology Heterocyclic Compounds, 1-Ring - chemistry Hydroxybutyrates - chemistry Organic polymers organocatalysis Organophosphorus Compounds - chemistry Physicochemistry of polymers poly(3-hydroxybutyrate) Polyesters - chemistry Polymerization Preparation, kinetics, thermodynamics, mechanism and catalysts ring-opening polymerization Spectrometry, Mass, Matrix-Assisted Laser Desorption-Ionization
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