Ligand-Activated Lithium-Mediated Zincation of N-Phenylpyrrole

Metalation of N‐phenylpyrrole by using an in situ mixture of ZnCl2⋅TMEDA (0.5 equiv; TMEDA=N,N,N′,N′‐tetramethylethylenediamine) and LiTMP (1.5 equiv; TMP=2,2,6,6‐tetramethylpiperidino) was optimized. The reaction carried out at room temperature in THF resulted in incomplete metalation (56 % convers...

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Veröffentlicht in:	Chemistry : a European journal 2007-01, Vol.13 (35), p.9982-9989
Hauptverfasser:	Seggio, Anne, Lannou, Marie-Isabelle, Chevallier, Floris, Nobuto, Daisuke, Uchiyama, Masanobu, Golhen, Stéphane, Roisnel, Thierry, Mongin, Florence
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemical Sciences heterocycles ligand effects Ligands lithium Lithium - chemistry metalation Molecular Structure Organic chemistry Pyrroles - chemical synthesis Pyrroles - chemistry Zinc - chemistry Zinc Compounds - chemical synthesis Zinc Compounds - chemistry zincates
Online-Zugang:	Volltext
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