Inorganics distribution in bio oils and char produced by biomass fast pyrolysis: The key role of aerosols

Fast pyrolysis of biomass is a promising process for the preparation of bio-oil dedicated to energy production. Inorganic species originally present in biomass are known to induce problems such as bio-oil instability or deposits and fouling. However the mechanisms of inorganic species release during...

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Veröffentlicht in:Journal of analytical and applied pyrolysis 2011, Vol.92 (1), p.59-67
Hauptverfasser: Jendoubi, N., Broust, F., Commandre, J.M., Mauviel, G., Sardin, M., Lédé, J.
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container_end_page 67
container_issue 1
container_start_page 59
container_title Journal of analytical and applied pyrolysis
container_volume 92
creator Jendoubi, N.
Broust, F.
Commandre, J.M.
Mauviel, G.
Sardin, M.
Lédé, J.
description Fast pyrolysis of biomass is a promising process for the preparation of bio-oil dedicated to energy production. Inorganic species originally present in biomass are known to induce problems such as bio-oil instability or deposits and fouling. However the mechanisms of inorganic species release during biomass pyrolysis into the raw bio-oils still remain unclear. The present work focuses on the determination of inorganic distribution in the products from wheat straw and beech wood fast pyrolysis performed in a fluidized bed. More specifically, the bio-oils are fractionated by using a series of condensers. The results show that more than 60 wt.% of the inorganic content of the overall bio-oil is contained in the aerosols. Several possible interpretations for this observation are discussed. It is likely that the inorganics are transported within the aerosols droplets and solid particles which are recovered in the bio-oils, either by mechano-chemical processes, or by entrainment of submicron intermediate liquid compound formed in the first steps of biomass fast pyrolysis.
doi_str_mv 10.1016/j.jaap.2011.04.007
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source Elsevier ScienceDirect Journals
subjects Aerosols
Bio-oil
Biomass
Chemical and Process Engineering
Engineering Sciences
Environmental Engineering
Environmental Sciences
Fast pyrolysis
Fluidized bed
Inorganics
title Inorganics distribution in bio oils and char produced by biomass fast pyrolysis: The key role of aerosols
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