Porosity and permeability changes in sedimentary rocks induced by injection of reactive fluid: A simulation model

► Navier Stokes’ equation is simulated using Finite Difference Method. ► Simulation of reaction–diffusion processes. ► Simulation results give good agreement with experimental results. ► Mechanism of dissolution for different concentrations proposed. ► Porosity–permeability shows a power law behaviour when scaled by concentration. Numerical programs for simulating flow and reactive transport in porous media is essential for predicting reservoir properties related to CO2 sequestration performance, subsurface storage and risk assessment. In this paper we solve the Navier Stokes’ equation using finite difference method, on a simulated porous rock structure, to study the velocity distribution of fluid flowing through it under a constant pressure gradient. A reactive solute carried through the fluid is allowed to interact with the minerals in the rock. This chemical reaction dissolves the mineral which changes the rock structure thus affecting its flow properties. These changes of flow properties are studied with variation in reactive solute concentration and pressure field. The different mechanisms of dissolution responsible for the variation of flow properties for the different parameters is predicted. Before the onset of homogeneous dissolution, variation in porosity follows a power-law behaviour with change in permeability when the latter is scaled by the concentration of the reactive species. The simulation results are compared with available experimental data and found to give a reasonable match.