Copper Catalyst Activation Driven by Photoinduced Electron Transfer: A Prototype Photolatent Click Catalyst
PET cat. While the copper(II) tren ketoprofenate precatalyst 1 (see picture) is inactive at room temperature in methanol, it is quantitatively and rapidly reduced to its cuprous state upon light irradiation to provide a highly reactive click catalyst. By simply introducing air into the reaction medi...
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| Veröffentlicht in: | Angewandte Chemie International Edition 2012-07, Vol.51 (29), p.7137-7141 |
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| container_issue | 29 |
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| container_title | Angewandte Chemie International Edition |
| container_volume | 51 |
| creator | Harmand, Lydie Cadet, Sarah Kauffmann, Brice Scarpantonio, Luca Batat, Pinar Jonusauskas, Gediminas McClenaghan, Nathan D. Lastécouères, Dominique Vincent, Jean-Marc |
| description | PET cat. While the copper(II) tren ketoprofenate precatalyst 1 (see picture) is inactive at room temperature in methanol, it is quantitatively and rapidly reduced to its cuprous state upon light irradiation to provide a highly reactive click catalyst. By simply introducing air into the reaction medium the catalysis can be switched off and then switched on again by bubbling argon followed by irradiation. |
| doi_str_mv | 10.1002/anie.201203014 |
| format | Article |
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While the copper(II) tren ketoprofenate precatalyst 1 (see picture) is inactive at room temperature in methanol, it is quantitatively and rapidly reduced to its cuprous state upon light irradiation to provide a highly reactive click catalyst. 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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Activation Argon Bubbling Catalysis CATALYSTS Chemical Physics Chemical Sciences click chemistry Coordination chemistry Copper Electron transfer Huisgen cycloaddition IRRADIATION Light irradiation Methyl alcohol photocontrolled catalysts photolatent catalysts Physics |
| title | Copper Catalyst Activation Driven by Photoinduced Electron Transfer: A Prototype Photolatent Click Catalyst |
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